3-Aminobiphenyl

3-Aminobiphenyl is an organic compound with the formula C6H5C6H4NH2. It is one of three monoamine derivatives of biphenyl. It is a colorless solid, although aged samples can appear colored. It is obtained from 3-bromoaniline and phenylboronic acid by Suzuki coupling.[1]

3-Aminobiphenyl
Names
Preferred IUPAC name
[1,1′-Biphenyl]-3-amine
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.200.942
UNII
  • InChI=1S/C12H11N/c13-12-8-4-7-11(9-12)10-5-2-1-3-6-10/h1-9H,13H2
    Key: MUNOBADFTHUUFG-UHFFFAOYSA-N
  • C1=CC=C(C=C1)C2=CC(=CC=C2)N
Properties
C12H11N
Molar mass 169.227 g·mol−1
Appearance white solid
Density 1.077 g/cm3
Melting point 31–31.5 °C (87.8–88.7 °F; 304.1–304.6 K)
Boiling point 177–8 °C (351–46 °F; 450–281 K)
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H302, H315, H319, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

See also

References
  1. Bin Tao, David W. Boykin (2004). "Simple Amine/Pd(OAc)2-Catalyzed Suzuki Coupling Reactions of Aryl Bromides under Mild Aerobic Conditions". J. Org. Chem. 69: 4330-4335. doi:10.1021/jo040147z.
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