Allyl methyl sulfide

Allyl methyl sulfide
Names
	Preferred IUPAC name 3-(Methylsulfanyl)prop-1-ene
	Other names Methyl propenyl sulfide; 3-Methylthio-1-propene
Identifiers
CAS Number	10152-76-8 ;
3D model (JSmol)	Interactive image;
ChemSpider	21159856 ;
ECHA InfoCard	100.030.371
EC Number	233-422-0;
MeSH	allyl+methyl+sulfide
PubChem CID	66282;
RTECS number	UD1015000;
UNII	V7QI1R316C ;
UN number	1993
CompTox Dashboard (EPA)	DTXSID9064976 ;
	InChI InChI=1S/C4H8S/c1-3-4-5-2/h3H,1,4H2,2H3 Key: NVLPQIPTCCLBEU-UHFFFAOYSA-N ; InChI=1/C4H8S/c1-3-4-5-2/h3H,1,4H2,2H3 Key: NVLPQIPTCCLBEU-UHFFFAOYAX;
	SMILES CSCC=C;
Properties
Chemical formula	C4H8S
Molar mass	88.17 g·mol−1
Odor	Garlic
Density	0.803 g cm−3
Boiling point	92 °C; 197 °F; 365 K
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H225
Precautionary statements	P210
Flash point	18.0 °C (64.4 °F; 291.1 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Allyl methyl sulfide is an organosulfur compound with the chemical formula CH₂=CHCH₂SCH₃. The molecule features two functional groups, an allyl (CH₂=CHCH₂) and a sulfide. It is a colourless liquid with a strong odor characteristic of alkyl sulfides. It is a metabolite of garlic, and "garlic breath" is attributed to its presence.[1]

It is prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol.

CH₂=CHCH₂Cl + NaOH (aq) + CH₃SH → CH₂=CHCH₂SCH₃ + NaCl + H₂O

References

Eric Block (2010-01-04). Garlic and Other Alliums: The Lore and the Science. Royal Society of Chemistry. ISBN 978-0-85404-190-9.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.