ANFO

ANFO (/ˈænfoʊ/ AN-foh)[1] (or AN/FO, for ammonium nitrate/fuel oil) is a widely used bulk industrial explosive. It consists of 94% porous prilled ammonium nitrate (NH4NO3) (AN), which acts as the oxidizing agent and absorbent for the fuel, and 6% number 2 fuel oil (FO).[2] The use of ANFO originated in the 1950s.[3]

Ammonium nitrate prills used in ANFO at a potash mine.
25 kg (55 lb) sacks containing ANFO

ANFO accounts for an estimated 90% of the 2.7 million tonnes (6 billion pounds) of explosives used annually in North America.[4] It has found wide use in coal mining, quarrying, metal ore mining, and civil construction in applications where its low cost and ease of use may outweigh the benefits of other explosives, such as water resistance, oxygen balance, higher detonation velocity, or performance in small-diameter columns. ANFO is also widely used in avalanche hazard mitigation.[5]

Chemistry

The chemistry of ANFO detonation is the reaction of ammonium nitrate with a long-chain alkane (CnH2n+2) to form nitrogen, carbon dioxide, and water. In an ideal stoichiometrically balanced reaction, ANFO is composed of about 94.5% AN and 5.5% FO by weight. In practice, a slight excess of fuel oil is added, as underdosing results in reduced performance while overdosing merely results in more post-blast fumes.[6] When detonation conditions are optimal, the aforementioned gases are the only products. In practical use, such conditions are impossible to attain, and blasts produce moderate amounts of toxic gases such as carbon monoxide and nitrogen oxides (NOx).

The fuel component of ANFO is typically diesel, but kerosene, coal dust, racing fuel, or even molasses have been used instead. Finely powdered aluminium in the mixture will sensitise it to detonate more readily.[7]

Explosive properties

ANFO is highly insensitive, making it a tertiary explosive (or a "blasting agent"). Without a sensitizer, it cannot be detonated by a typical (such as No. 8) blasting cap with the small amount of primary explosives within. A larger quantity of secondary explosive, known as a primer or a booster, must be used.[8] One or two sticks of dynamite were historically used; current practice is to use Tovex or cast boosters of pentolite (TNT/PETN or similar compositions).[9]

ANFO is technically a high explosive in that it decomposes through detonation rather than deflagration at a velocity higher than the speed of sound in the material, but the low sensitivity means that it is not generally regulated as such. ANFO has a moderate velocity compared to other industrial explosives, measuring 3,200 m/s in 130 mm (5 in) diameter, unconfined, at ambient temperature.[8] It is described as a non-ideal high explosive, as its explosive velocity is far from the thermodynamic ideal due to its porosity and the phase separation of its two components.[10]

Industrial use
Charging a hole with ANFO for rock blasting

In the mining industry, the term ANFO specifically describes a mixture of solid ammonium nitrate prills and diesel fuel. Other explosives based on the ANFO chemistry exist; the most commonly used are emulsions. They differ from ANFO in the physical form the reactants take. The most notable properties of emulsions are water resistance and higher bulk density.

While the density of pure crystalline ammonium nitrate is 1700 kg/m3, individual prills of explosive-grade AN measure approximately 1300 kg/m3. Their lower density is due to the presence of a small spherical air pocket within each prill: this is the primary difference between AN sold for blasting and that sold for agricultural use. These voids are necessary to sensitize ANFO: they create so-called "hot spots".[lower-alpha 1] Finely powdered aluminium can be added to ANFO to increase both sensitivity and energy;[10] in commercial usages however, this has fallen out of favor due to cost.

ANFO has a bulk density of about 840 kg/m3. In surface mining applications, it is typically loaded into boreholes by dedicated trucks that mix the AN and FO components immediately before the product is dispensed. In underground mining applications, ANFO is typically blow-loaded.

AN is highly hygroscopic, readily absorbing water from air. In humid environments, absorbed water interferes with its explosive function. AN is fully water-soluble; as such, it cannot be loaded into boreholes that contain standing water. When used in wet mining conditions, considerable effort must be taken to remove standing water and install a liner in the borehole; it is generally more productive to instead use a water-resistant explosive such as emulsion.

Regulation

In most jurisdictions, ammonium nitrate need not be classified as an explosive for transport purposes; it is merely an oxidizer. Mines typically prepare ANFO on-site using the same diesel fuel that powers their vehicles. While many fuels can theoretically be used, the low volatility and cost of diesel make it ideal.

ANFO under most conditions is detonator–insensitive, so it is legally classified as a blasting agent (tertiary explosive)[11] and not a high explosive.[12]

Ammonium nitrate is widely used as a fertilizer in the agricultural industry. It is also found in instant cold packs. In many countries, its purchase and use are restricted to buyers who have obtained the proper license.

Disasters
Main article: List of ammonium nitrate disasters

Unmixed ammonium nitrate can decompose explosively, and has been responsible for several industrial disasters, including the following:

Environmental hazards include eutrophication in confined waters and nitrate/gas oil contamination of ground or surface water.[13]

Paramilitary use

ANFO was used in 1970 when protests by students became violent at the University of Wisconsin–Madison, who learned how to make and use ANFO from a Wisconsin Conservation Department booklet entitled Pothole Blasting for Wildlife,[6][14] resulting in the Sterling Hall bombing.

ANFO used to be widely used by the FLNC (National Liberation Front of Corsica), along with f15 explosive. Five containers of 500 kilograms (1,100 pounds) each were used to blow up the Tax Office building in Bastia on 28 February 1987.

The ANFO car bomb was adopted by the Provisional IRA in 1972 and, by 1973, the Troubles were consuming 21,000 kilograms (47,000 pounds) of ammonium nitrate for the majority of bombs.[15] The Ulster Volunteer Force (UVF) also made use of ANFO bombs, often mixing in gelignite as a booster, in the Dublin and Monaghan bombings of May 1974 which killed 34 people & injured almost 300, ANFO car bombs were used in Dublin.[16] It has also seen use by groups such as the Revolutionary Armed Forces of Colombia and ETA. In 1992, Shining Path perpetrated the Tarata bombing in Lima, Peru, using two ANFO truck bombs.

A more sophisticated variant of ANFO (ammonium nitrate with nitromethane as the fuel, called ANNM) was used in the 1995 Oklahoma City bombing.

The Shijiazhuang bombings (Chinese: 靳如超爆炸案 or 石家庄"3·16"特大爆炸案) rocked the city of Shijiazhuang, China, on 16 March 2001. A total of 108 people were killed, and 38 others injured when, within a short time, several ANFO bombs exploded near four apartment buildings.[17]

In November 2009, the government of the North West Frontier Province (NWFP) of Pakistan imposed a ban on ammonium sulfate, ammonium nitrate, and calcium ammonium nitrate fertilizers in the Upper Dir, Lower Dir, Swat, Chitral and Malakand districts (the former Malakand Division) following reports that those chemicals were used by militants to make explosives.

In April 2010, police in Greece confiscated 180 kg of ANFO and other related material stashed in a hideaway in the Athens suburb of Kareas. The material was believed to be linked to attacks previously carried out by the "Revolutionary Struggle" terrorist group.

In January 2010, President Hamid Karzai of Afghanistan also issued a decree banning the use, production, storage, purchase, or sale of ammonium nitrate, after an investigation showed militants in the Taliban insurgency had used the substance in bomb attacks.[18][19][20]

On 22 July 2011, an aluminium powder-enriched ANNM explosive, with total size of 950 kg (150 kg of aluminium powder), increasing demolition power by 10–30% over plain ANFO, was used in the Oslo bombing.[21][22]

On 13 April 2016, two suspected IRA members were stopped in Dublin with 67 kg of ANFO.[23]

On 6 March 2018, 8 members of the extreme right neo-Nazi group Combat 18 were arrested in Athens, Greece, accused of multiple attacks on immigrants and activists. They had 50 kg of ANFO in their possession.[24]

References
  1. It was found by the IRA, in response to using low-brisance AN fertilizers, that "hot spots" can be created by blending powdered sugar into the ANFO mixture, effectively sensitizing the mixture to mining-standard prilled ammonium nitrate effectiveness in which the interaction of the detonation front with a spherical void concentrates energy. Blasting-grade AN prills are typically between 0.9 and 3.0 mm in diameter.
  1. "ANFO | explosive". Encyclopedia Britannica. Retrieved 4 May 2019.
  2. Cook, Melvin A. (1974). The Science of Industrial Explosives. IRECO Chemicals. p. 1. ASIN B0000EGDJT.
  3. Encyclopædia Britannica
  4. Edward M. Green (June 2006). "Explosives regulation in the USA" (PDF). Industrial Materials (465): 78. Archived from the original (PDF) on 11 October 2022. Retrieved 3 March 2013.
  5. Cook, Melvin A. (1974). The Science of Industrial Explosives. IRECO Chemicals. p. 2. ASIN B0000EGDJT.
  6. Mathiak, Harold A. (1965). Pothole Blasting for Wildlife. Wisconsin Conservation Department, Madison, Wisconsin 53701. p. 11.
  7. Singh, R. D. (2005). Principles and Practices of Modern Coal Mining. New Age International. p. 532. ISBN 9788122409741.
  8. Blasters' Handbook (15th ed.). E. I. du Pont de Nemours & Company. 1969. pp. 64–68. ASIN B000JM3SD0.
  9. "Explosives – ANFO (Ammonium Nitrate – Fuel Oil)". GlobalSecurity.org. Retrieved 3 March 2013.
  10. Fabin, M; Jarosz, T (1 October 2021). "Improving ANFO: Effect of Additives and Ammonium Nitrate Morphology on Detonation Parameters". Materials. 14 (19). doi:10.3390/ma14195745. PMID 34640139.
  11. Cook, Melvin A. (1974). The Science of Industrial Explosives. IRECO Chemicals. p. 16. ASIN B0000EGDJT.
  12. "Explosives and blasting agents". Occupation Safety & Health Administration. Retrieved 3 March 2013.
  13. P. Cosgrove. Ammogex Material Safety Data Sheet, Document No: HS-MSDS-03, Irish Industrial Explosives Ltd
  14. Mike Davis (2007). Buda's Wagon: A Brief History of the Car Bomb. New York: Verso. p. 53. ISBN 978-1844671328. LCCN 2007274127..
  15. Henry Stanhope (8 November 1974). "The will to blow the lid off Ulster still remains strong". The Times. London.
  16. "Bombs".
  17. "石家庄九名制贩爆炸物的嫌犯被刑事拘留" [Shijiazhuang nine suspects of the sale of explosives were detained in criminal detention] (in Chinese). Beijing. 3 April 2001. Retrieved 12 August 2017.
  18. "Afghanistan bans chemical used to make bombs; protesters denounce killings". Times Union. Albany, N.Y. Archived from the original on 7 June 2010.
  19. "Afghanistan bans chemical used to make bombs". The Guardian. AP Foreign. 22 January 2010. Retrieved 3 March 2013.
  20. Dexter Filkins (11 November 2009). "Bomb Material Cache Uncovered in Afghanistan". The New York Times. Retrieved 3 March 2013.
  21. Stina Åshildsdatter Grolid; Unni Eikeseth (25 July 2011). "Slik virket trykkbølgen etter bomben" [Such seemed the shock wave after the bomb] (in Norwegian). NRK. Retrieved 28 July 2011.
  22. Stigset, Marianne; Kremer, Josiane; Treloar, Stephen (27 July 2011). "Police in Norway Extend Terror Probe Across Europe After Breivik Attacks". Bloomberg.
  23. Daniel Hickey (13 April 2016). "Two men appear in court charged with possession of 150 kg of homemade explosives". Irish Independent. Dublin. Retrieved 16 April 2016.
  24. "Ο 'Τσαμπ' της 'Combat 18' και ο 'Λύκος' της Χρυσής Αυγής επιβεβαιώνουν τη λογική των 'συγκοινωνούντων δοχείων'".
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