Aniline (data page)

This page provides supplementary chemical data on aniline.

Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommend that you seek the Material Safety Datasheet (MSDS) for this chemical from a reliable source and follow its directions.

Structure and properties

Structure and properties
Index of refraction, nD 1.5863 at 20 °C
Abbe number ?
Dielectric constant,[1] εr 6.89 ε0 at 20 °C
Bond strength  ?
Bond length  ?
Bond angle  ?
Magnetic susceptibility  ?
Surface tension[2] 44.0 dyn/cm at 10 °C
42.9 dyn/cm at 20 °C
24.4 dyn/cm at 180 °C
Viscosity[3] 6.023 mPa·s at 12 °C
4.467 mPa·s at 20 °C
2.92 mPa·s   at 22 °C
1.555 mPa·s at 60 °C

Thermodynamic properties

Phase behavior
Triple point 267.13 K (–6.02 °C), ? Pa
Critical point 698.8 K (425.7 °C), 4890 kPa
Std enthalpy change
of fusion
, ΔfusHo
10.54 kJ/mol
Std entropy change
of fusion
, ΔfusSo
39.57 J/(mol·K) at –6.3 °C
Std enthalpy change
of vaporization
, ΔvapHo
55.83 kJ/mol at 25 °C
42.44 kJ/mol at 184.1 °C
Std entropy change
of vaporization
, ΔvapSo
 ? J/(mol·K)
Solid properties
Std enthalpy change
of formation
, ΔfHosolid
 ? kJ/mol
Standard molar entropy,
Sosolid
 ? J/(mol K)
Heat capacity, cp  ? J/(mol K)
Liquid properties
Std enthalpy change
of formation
, ΔfHoliquid
31 kJ/mol
Standard molar entropy,
Soliquid
191. J/(mol K)
Enthalpy of combustion, ΔcHoliquid –3393 kJ/mol
Heat capacity, cp 193.7 J/(mol K) at 25 °C
Gas properties
Std enthalpy change
of formation
, ΔfHogas
87 kJ/mol
Standard molar entropy,
Sogas
 ? J/(mol K)
Heat capacity,[4] cp 148.7 J/(mol K) at 25 °C
van der Waals' constants[5] a = 2685 L2 kPa/mol2
b = 0.1369 liter per mole

Vapor pressure of liquid

P in mm Hg11040100400760152038007600152003040045600
T in °C34.869.496.7119.9161.9184.4212.8254.8292.7342.0400.0 

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.

log10 of Aniline vapor pressure. Uses formula: obtained from CHERIC[4]

Distillation data

See also:

Vapor-liquid Equilibrium
for Aniline/Water
[6]
P = 745 mm Hg
BP
Temp.
°C
 % by mole water
liquidvapor
98.596.5
10124.794.8
10520.094.3
109.815.392.4
115.811.789.3
1219.386.2
1267.681.6
1315.975.9
1404.2570.8
1522.5060.5
1601.7048.7
1681.0534.1
   
Vapor-liquid Equilibrium
for Aniline/n-hexane
[6]
P = 101.325 kPa
BP
Temp.
°C
 % by mole hexane
liquidvapor
150.21.5062.50
136.42.5076.00
116.05.3088.70
90.011.0096.00
79.516.8597.66
75.720.9998.07
74.127.3598.31
73.2537.9098.42
73.2052.0098.62
73.1571.4698.78
72.1581.2698.93
71.5086.5099.06
70.7090.9399.16
69.8095.3299.36
69.1097.8699.61

Spectral data

UV-Vis
Ionization potential 7.72(62281)   eV(cm−1)
λmax 230 nm (E2-band)[7]
280 nm (B-band)[7]
Extinction coefficient, ε 8 600 (E2-band)[7]
1 430 (B-band)[7]
IR
Major absorption bands[8]
(liquid film)
Wave numbertransmittance
3663 cm177%
3429 cm132%
3354 cm120%
3214 cm144%
3088 cm162%
3072 cm155%
3037 cm138%
3010 cm167%
2930 cm181%
2904 cm179%
2640 cm179%
2627 cm181%
1929 cm177%
1839 cm179%
1705 cm177%
1621 cm17%
1601 cm15%
1557 cm170%
1525 cm166%
1496 cm14%
1467 cm134%
1332 cm174%
1312 cm157%
1277 cm125%
1176 cm132%
1154 cm168%
1053 cm177%
1028 cm164%
996 cm160%
881 cm153%
754 cm18%
693 cm110%
620 cm147%
529 cm150%
504 cm118%
NMR
Proton NMR  
Carbon-13 NMR  
Other NMR data  
MS
Masses of
main fragments
 

UV Absorbance Spectroscopy of Aniline

Aniline is a benzenoid compound. The NH2 group attached to the benzene ring means that there is a lone pair of electrons that can enter into conjugation with the benzene ring resulting in delocalization in the aniline.

Aniline absorbs in the K (220 - 250 nm) and the B (250 - 290 nm) bands exhibited by benzenoid compounds. The K and B bands arise from π to π* transitions as a result of the a group containing multiple bond being attached to the benzene ring. When dissolved in ethanol, λmax for aniline is 230 nm, but in dilute aqueous acid λmax is 203 nm. In the latter case the anilinium cation is formed and the lone pair is no longer available for conjugation with the benzene ring. Consequently, the absorption of the molecule shifts to the lower λmax value and behaves like benzene.

Regulatory data

Regulatory data
Flash point 70 °C
RTECS  ?
Autoignition temperature 615 °C

References

  1. Lange's Handbook of Chemistry, 10th ed. pp. 1234–1237
  2. Lange's Handbook of Chemistry, 10th ed. pp. 1661–1663
  3. Lange's Handbook of Chemistry, 10th ed. pp. 1669–1674
  4. "Pure Component Properties" (Queriable database). Chemical Engineering Research Information Center. Archived from the original on 3 June 2007. Retrieved 28 May 2007.
  5. Lange's Handbook of Chemistry, 10th ed, pp. 1522–1524
  6. "Binary Vapor-Liquid Equilibrium Data" (Queriable database). Chemical Engineering Research Information Center. Retrieved 6 June 2007.
  7. Kaur, H. Spectroscopy. Global Media: Meerut, India, 2009; p. 304
  8. "Spectral Database for Organic Compounds". Advanced Industrial Science and Technology. Archived from the original (Queriable database) on 5 May 2006. Retrieved 9 June 2007.
  • Linstrom, Peter (1997). "NIST Standard Reference Database". National Institute of Standards and Technology. doi:10.18434/T4D303. {{cite journal}}: Cite journal requires |journal= (help)
  • Finar, I.L. (1974); Organic Chemistry Vol.2 – Stereochemistry and the chemistry of natural products 5th. Ed. Longman
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