Bis(acetonitrile)palladium dichloride

Bis(acetonitrile)palladium dichloride
Names
	Other names palladium dichloride bis(acetonitrile), bis(acetonitrile)dichloropalladium
Identifiers
CAS Number	14592-56-4 ;
3D model (JSmol)	ionic form: Interactive image; coordination form: Interactive image;
EC Number	238-637-3;
PubChem CID	6093782;
	InChI InChI=1S/2C2H3N.2ClH.Pd/c21-2-3;;;/h21H3;2*1H;/q;;;;+2/p-2 Key: RBYGDVHOECIAFC-UHFFFAOYSA-L;
	SMILES ionic form: CC#N.CC#N.Cl[Pd]Cl; coordination form: Cl[Pd-2](Cl)([N+]#CC)[N+]#CC;
Properties
Chemical formula	C4H6Cl2N2Pd
Molar mass	259.43 g·mol−1
Appearance	yellow-brown
Melting point	129–131 °C (264–268 °F; 402–404 K)
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H301, H311, H330
Precautionary statements	P260, P261, P264, P270, P271, P273, P280, P284, P301+P310, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, P501
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Bis(acetonitrile)palladium dichloride is the coordination complex with the formula PdCl₂(NCCH₃)₂. It is the adduct of two acetonitrile ligands with palladium(II) chloride. It is a yellow-brown solid that is soluble in organic solvents. The compound is a reagent and a catalyst for reactions that require soluble Pd(II).[1] The compound is similar to bis(benzonitrile)palladium dichloride. It reacts with 1,5-cyclooctadiene to give dichloro(1,5‐cyclooctadiene)palladium.

References

Carretero, Juan Carlos; Arrayas, Ramon Gomez (2008). "Dichloro bis(acetonitrile) palladium". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn00908. ISBN 978-0471936237.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.