Isotopes of boron

Boron (5B) naturally occurs as isotopes 10
B
and 11
B
, the latter of which makes up about 80% of natural boron. There are 13 radioisotopes that have been discovered, with mass numbers from 7 to 21, all with short half-lives, the longest being that of 8
B
, with a half-life of only 771.9(9) ms and 12
B
with a half-life of 20.20(2) ms. All other isotopes have half-lives shorter than 17.35 ms. Those isotopes with mass below 10 decay into helium (via short-lived isotopes of beryllium for 7
B
and 9
B
) while those with mass above 11 mostly become carbon.

A chart showing the abundances of the naturally occurring isotopes of boron.
Isotopes of boron (5B)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
10B 19.65% stable
11B 80.35% stable
Standard atomic weight Ar°(B)
  • [10.806, 10.821]
  • 10.81±0.02 (abridged)[1][2]

List of isotopes

Nuclide[3]
[n 1]
Z N Isotopic mass (Da)[4]
[n 2][n 3]
Half-life

[resonance width]
Decay
mode

[n 4]
Daughter
isotope

[n 5]
Spin and
parity
[n 6][n 7]
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
6
B
?[n 8]
5 1 6.050800(2150) p-unstable 2p? 6
Li
?
2−#
7
B
5 2 7.029712(27) 570(14) ys
[801(20) keV]
p 6
Be
[n 9]
(3/2−)
8
B
[n 10][n 11]
5 3 8.0246073(11) 771.9(9) ms β+α 4
He
2+
8m
B
10624(8) keV 0+
9
B
5 4 9.0133296(10) 800(300) zs p 8
Be
[n 12]
3/2−
10
B
[n 13]
5 5 10.012936862(16) Stable 3+ [0.189, 0.204][5]
11
B
5 6 11.009305167(13) Stable 3/2− [0.796, 0.811][5]
11m
B
12560(9) keV 1/2+, (3/2+)
12
B
5 7 12.0143526(14) 20.20(2) ms β (99.40(2)%) 12
C
1+
βα (0.60(2)%) 8
Be
[n 14]
13
B
5 8 13.0177800(11) 17.16(18) ms β (99.734(36)%) 13
C
3/2−
βn (0.266(36)%) 12
C
14
B
5 9 14.025404(23) 12.36(29) ms β (93.96(23)%) 14
C
2−
βn (6.04(23)%) 13
C
β2n ?[n 15] 12
C
 ?
14m
B
17065(29) keV 4.15(1.90) zs IT ?[n 15] 0+
15
B
5 10 15.031087(23) 10.18(35) ms βn (98.7(1.0)%) 14
C
3/2−
β (< 1.3%) 15
C
β2n (< 1.5%) 13
C
16
B
5 11 16.039841(26) > 4.6 zs n ?[n 15] 15
B
 ?
0−
17
B
[n 16]
5 12 17.04693(22) 5.08(5) ms βn (63(1)%) 16
C
(3/2−)
β (21.1(2.4)%) 17
C
β2n (12(2)%) 15
C
β3n (3.5(7)%) 14
C
β4n (0.4(3)%) 13
C
18
B
5 13 18.05560(22) < 26 ns n 17
B
(2−)
19
B
[n 16]
5 14 19.06417(56) 2.92(13) ms βn (71(9)%) 18
C
(3/2−)
β2n (17(5)%) 17
C
β3n (< 9.1%) 16
C
β (> 2.9%) 19
C
20
B
[6]
5 15 20.07451(59) > 912.4 ys n 19
B
(1−, 2−)
21
B
[6]
5 16 21.08415(60) > 760 ys 2n 19
B
(3/2−)
This table header & footer:
  1. mB  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Modes of decay:
    n:Neutron emission
    p:Proton emission
  5. Bold symbol as daughter  Daughter product is stable.
  6. () spin value  Indicates spin with weak assignment arguments.
  7. #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  8. This isotope has not yet been observed; given data is inferred or estimated from periodic trends.
  9. Subsequently decays by double proton emission to 4
    He
    for a net reaction of 7
    B
    4
    He
    + 31
    H
  10. Has 1 halo proton
  11. Intermediate product of a branch of proton-proton chain in stellar nucleosynthesis as part of the process converting hydrogen to helium
  12. Immediately decays into two α particles, for a net reaction of 9
    B
    → 24
    He
    + 1
    H
  13. One of the few stable odd-odd nuclei
  14. Immediately decays into two α particles, for a net reaction of 12
    B
    → 34
    He
    + e
  15. Decay mode shown is energetically allowed, but has not been experimentally observed to occur in this nuclide.
  16. Has 2 halo neutrons
  • Neutrinos from boron-8 beta decays within the Sun are an important background to dark matter direct detection experiments.[7] They are the first component of the neutrino floor that dark matter direct detection experiments are expected to eventually encounter.

Applications

Boron-10

Boron-10 is used in boron neutron capture therapy as an experimental treatment of some brain cancers.

References

  1. "Standard Atomic Weights: Boron". CIAAW. 2009.
  2. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; et al. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. Half-life, decay mode, nuclear spin, and isotopic composition is sourced in:
    Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  4. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  5. "Atomic Weight of Boron". CIAAW.
  6. Leblond, S.; et al. (2018). "First observation of 20B and 21B". Physical Review Letters. 121 (26): 262502–1–262502–6. arXiv:1901.00455. doi:10.1103/PhysRevLett.121.262502. PMID 30636115. S2CID 58602601.
  7. Cerdeno, David G.; Fairbairn, Malcolm; Jubb, Thomas; Machado, Pedro; Vincent, Aaron C.; Boehm, Celine (2016). "Physics from solar neutrinos in dark matter direct detection experiments". JHEP. 2016 (5): 118. arXiv:1604.01025. Bibcode:2016JHEP...05..118C. doi:10.1007/JHEP05(2016)118. S2CID 55112052.


https://borates.today/isotopes-a-comprehensive-guide/#:~:text=Boron%20isotope%20elements%20with%20masses,11%20mostly%20decay%20into%20carbon.

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