C. Frederick Koelsch

Charles Frederick Koelsch (31 January 1907 - 24 December 1999) was an American organic chemist who spent his faculty career at the University of Minnesota.[1][2][3]

Charles Frederick Koelsch
Born(1907-01-31)January 31, 1907
DiedDecember 24, 1999(1999-12-24) (aged 92)
Scientific career
FieldsOrganic chemistry, synthetic chemistry
InstitutionsUniversity of Minnesota
Doctoral advisorSamuel M. McElvain
Notable studentsVirgil Boekelheide

Education and academic career

Koelsch was born in Boise, Idaho in 1907 in a family of German descent.[3] He attended the University of Wisconsin and earned his bachelor's degree in 1928 and his Ph.D. from the same institution in 1931, working under the supervision of Samuel M. McElvain.[2][3] After a postdoctoral fellowship at Harvard University with Elmer Peter Kohler, Koelsch was recommended for a position at the University of Minnesota by Lee Irvin Smith.[3] He joined the faculty there as an instructor in 1932 and became an assistant professor in 1934. Koelsch was awarded the ACS Award in Pure Chemistry in 1934.[3][2] He advanced to associate professor in 1937 and full professor in 1946.[1] He remained at the University of Minnesota until his retirement, assuming professor emeritus status, in 1973.[1][3] Through much of his academic career, Koelsch also served as an industry consultant, working first with Smith, Kline & French and later with Sterling Drug and Union Carbide.[3]

Chemical structure of the Koelsch radical

During his work at Harvard, Koelsch attempted to publish a paper describing an unusually stable radical compound, but it was rejected at the time on the grounds that the compound's properties were unlikely to describe a radical. Subsequent experimental evidence and quantum mechanics calculations suggested his interpretation of the original experiment was correct, resulting in the publication of the paper nearly 25 years after the original experiments.[3][4] The compound - 1,3‐bisdiphenylene‐2‐phenylallyl (BDPA) - is now often referred to as the "Koelsch radical".[5][6]

Personal life

Koelsch married his wife Helen in 1938 and the couple had three children. He was a ham radio enthusiast.[2][3] He died in Rochester, Minnesota in 1999.[2]

References

  1. "Biographical Sketch of Charles Frederick Koelsch (1907-1999)". Charles Frederick Koelsch papers. University of Minnesota Libraries. Retrieved 29 December 2020.
  2. "In Memoriam". Badger Chemist: The Newsletter of the University of Wisconsin-Madison Chemistry Department. 44: 27. 2000. Retrieved 29 December 2020.
  3. Noland, Wayland E. (November 1975). "The Life and Times of Professor Emeritus C. Frederick Koelsch". The Minnesota Chemist. 27 (7): 7–8, 15–17. Retrieved 29 December 2020.
  4. Koelsch, C. F. (August 1957). "Syntheses with Triarylvinylmagnesium Bromides. α,γ-Bisdiphenylene-β-phenylallyl, a Stable Free Radical". Journal of the American Chemical Society. 79 (16): 4439–4441. doi:10.1021/ja01573a053.
  5. Zard, Samir Z. (2003). Radical reactions in organic synthesis. Oxford: Oxford University Press. p. 3. ISBN 9780198502401.
  6. Matsui, Yasunori; Shigemori, Minoru; Endo, Toshiyuki; Ogaki, Takuya; Ohta, Eisuke; Mizuno, Kazuhiko; Naito, Hiroyoshi; Ikeda, Hiroshi (August 2018). "Spectroscopic and electrical characterization of α,γ-bisdiphenylene-β-phenylallyl radical as an organic semiconductor". Research on Chemical Intermediates. 44 (8): 4765–4774. doi:10.1007/s11164-018-3282-7. S2CID 102644089.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.