Pentlandite

Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in nickel to iron ratios (Ni:Fe), but it is usually described as 1:1. In some cases, this ratio is skewed by the presence of pyrrhotite inclusions. It also contains minor cobalt, usually at low levels as a fraction of weight.

Pentlandite
Pentlandite, Pyrrhotite-540342
3.1 x 2.6 cm mass of Pentlandite with some Pyrrhotite
General
CategorySulfide mineral
Formula
(repeating unit)		iron nickel sulfide: (Fe,Ni)9S8
IMA symbolPn[1]
Strunz classification2.BB.15a
Dana classification2.7.1.1
Crystal systemIsometric
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupFm3m
Unit cella = 9.928 Å, Z = 4
Identification
Formula mass771.94 g/mol
ColorYellowish bronze
Crystal habitHexoctahedral rare; massive to granular
CleavageAbsent – octahedral parting on {111}
FractureConchoidal
TenacityBrittle
Mohs scale hardness3.5–4
LusterMetallic
StreakLight bronze-brown[2][3][4][5]
Greenish black[6][7][8]
DiaphaneityOpaque
Specific gravity4.6–5.0
Density4.6–5 g/cm3
Fusibility1.5–2
Other characteristicsBecomes magnetic upon heating
References[9][2][3][4][5][6][7][8]
Pentlandite in pyrrhotite, ore specimen from the Sudbury Basin (field of view 3.4 cm)

Pentlandite forms isometric crystals, but it is normally found in massive granular aggregates. It is brittle with a hardness of 3.5–4 and specific gravity of 4.6–5.0 and is non-magnetic. It has a yellowish bronze color and a metallic luster.[10]

Pentlandite is found in abundance within ultramafic rocks, making it one of the most important sources of mined nickel.[11] It also occasionally occurs within mantle xenoliths and "black smoker" hydrothermal vents.[12]

Etymology

It is named after Irish scientist Joseph Barclay Pentland (1797–1873), who first noted the mineral at Sudbury, Ontario.

Copper Cliff mine, Sudbury, Ontario (1913)

Identification

Physical & Optical Properties

In the field, pentlandite is often confused with other sulfide minerals, as they are all brassy yellowish in color and have a metallic luster. For this reason, the best way to discern pentlandite is by its paler color, lack of magnetism, and light brownish bronze streak.[12] In contrast, pyrite, pyrrhotite and chalcopyrite will all display much darker streaks: brownish black,[13] greyish black,[14] greenish black[15] respectively. When looked at using reflected light ore microscopy, it possesses key diagnostic properties such as octahedral cleavage, and its alteration to bravoite, a pinkish to brownish violet sulfide mineral that occurs in euhedral to octahedral crystals. Pentlandite usually develops as granular inclusions within other sulfide minerals (mainly pyrrhotite), often taking the shape of thin veins or "flames." Although pentlandite is an opaque mineral, it exhibits a strong light creamy reflectance.[16]

Photomicrograph showing flame-like pentlandite intergrowth in plane polarized light (PPL) (a) and cross polarized light (XPL) (b) (5x magnification, FOV = 4 mm)

Mineral Associations

Pentlandite occurs alongside sulfide minerals such as bravoite, chalcopyrite, cubanite, millerite, pyrrhotite, valleriite, as well as other minerals like chromite, ilmenite, magnetite, and sperrylite. It is chemically similar to mackinawite, godlevskite and horomanite.[17][18]

Pentlandite is synonymous with folgerite, horbachite, lillhammerite, and nicopyrite.[18]

Pentlandite Group

The pentlandite group is a subdivision of rare minerals that share similar chemical and structural properties with pentlandite, hence the name. Their chemical formula can be written as XY8(S, Se)8 in which X is usually replaced by silver, manganese, cadmium, and lead, while copper takes the place of Y. Iron, nickel, and cobalt have the ability to occupy both X or Y positions. These minerals are:[19]

  • Argentopentlandite Ag(Fe,Ni)8S8
  • Cobalt pentlandite Co9S8
  • Geffroyite (Ag,Cu,Fe)9(Se,S)8
  • Manganese-shadlunite (Mn,Pb)(Cu,Fe)8S8
  • Shadlunite (Pb,Cd)(Fe,Cu)8S8
  • Oberthürite Rh3Ni32S32
  • Sugakiite Cu(Fe,Ni)8S8

Paragenesis

Pentlandite is the most common terrestrial nickel sulfide. It typically forms during cooling of a sulfide melt. These sulfide melts, in turn, are typically formed during the evolution of a silicate melt. Because nickel is a chalcophile element, it has preference for (i.e. it "partitions into") sulfide phases.[20] In sulfide undersaturated melts, nickel substitutes for other transition metals within ferromagnesian minerals, the most common being olivine, as well as nickeliferous varieties of amphibole, biotite, pyroxene and spinel. Nickel substitutes most readily for Fe2+ and Co2+ because or their similarity in size and charge.[21]

In sulfide saturated melts, nickel behaves as a chalcophile element and partitions strongly into the sulfide phase. Because most nickel behaves as a compatible element in igneous differentiation processes, the formation of nickel-bearing sulfides is essentially restricted to sulfide saturated mafic and ultramafic melts. Minor amounts of nickel sulfides are found in mantle peridotites.[20]

The behaviour of sulfide melts is complex and is affected by copper, nickel, iron, and sulfur ratios. Typically, above 1100 °C, only one sulfide melt exists. Upon cooling to 1000 °C, a solid containing mostly Fe and minor amounts of Ni and Cu is formed. This phase is called monosulfide solid solution (MSS), and is unstable at low temperatures decomposing to mixtures of pentlandite and pyrrhotite, and (rarely) pyrite. It is only upon cooling past ~550 °C (1,022 °F) (dependent on composition) that the MSS undergoes exsolution. A separate phase, usually a copper-rich sulfide liquid may also form, giving rise to chalcopyrite upon cooling.[22]

These phases typically form aphanitic equigranular massive sulfides, or are present as disseminated sulfides within rocks composed mostly of silicates. Pristine magmatic massive sulfide are rarely preserved as most deposits of nickeliferous sulfide have been metamorphosed.

Metamorphism at a grade equal to, or higher than, greenschist facies will cause solid massive sulfides to deform in a ductile fashion and to travel some distance into the country rock and along structures.[23] Upon cessation of metamorphism, the sulfides may inherit a foliated or sheared texture, and typically develop bright, equigranular to globular aggregates of porphyroblastic pentlandite crystals known colloquially as "fish scales".[24]

Metamorphism may also alter the concentration of nickel and the Ni:Fe ratio and Ni:S ratio of the sulfides. In this case, pentlandite may be replaced by millerite, and rarely heazlewoodite. Metamorphism may also be associated with metasomatism, and it is particularly common for arsenic to react with pre-existing sulfides, producing nickeline, gersdorffite and other Ni–Co arsenides.[25]

Occurrence

Pentlandite is found within the lower margins of mineralized layered intrusions, the best examples being the Bushveld igneous complex, South Africa, the Voisey's Bay troctolite intrusive complex in Canada, the Duluth gabbro, in North America, and various other localities throughout the world. In these locations, pentlandite is considered an important nickel ore.

Pentlandite is also the dominant ore mineral occurring in Kambalda type komatiitic nickel ore deposits, the prime example of which can be found in the Yilgarn Craton of Western Australia. Similar deposits exist at Nkomati, Namibia, in the Thompson Belt, Canada, and a few examples from Brazil.

Pentlandite, but primarily chalcopyrite and PGEs, are also obtained from the supergiant Norilsk nickel deposit, in trans-Siberian Russia.

The Sudbury Basin in Ontario, Canada, is associated with a large meteorite impact crater. The pentlandite-chalcopyrite-pyrrhotite ore around the Sudbury Structure formed from sulfide melts that segregated from the melt sheet produced by the impact.

See also

References
  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. Handbook of Mineralogy
  3. Mindat.org
  4. Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, p. 280-281 ISBN 0-471-80580-7
  5. Mindat.org - Forum
  6. Webmineral.com
  7. "Pentlandit" (in German).
  8. Schumann, Walter (1991). Mineralien aus aller Welt (in German) (2nd ed.). BLV. p. 224. ISBN 978-3-405-14003-8.
  9. Mineralienatlas
  10. "Pentlandite". www.mindat.org. Retrieved 2023-02-20.
  11. Kerfoot, Derek G. E. (2005). "Nickel". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_157.
  12. "Pentlandite" (PDF). Handbook of Mineralogy.
  13. "Pyrite" (PDF). Handbook of Mineralogy.
  14. "Pyrrhotite" (PDF). Handbook of Mineralogy.
  15. "Chalcopyrite" (PDF). Handbook of Mineralogy.
  16. Spry, Paul G.; Gedlinske, Brian L. (1987-01-01). Skinner, Brian J. (ed.). Noncolored Minerals. doi:10.5382/EGTables. ISBN 9781887483025.
  17. (Finland), Geologian tutkimuskeskus (1986), Mineral resource assessment map, northern Fennoscandia : regions and locations highly favourable for mineral deposits, Geological Surveys of Finland, Norway and Sweden, OCLC 18336974, retrieved 2023-04-13
  18. Pracejus, Bernhard (2008). The ore minerals under the microscope : an optical guide. Elsevier. ISBN 978-0-444-52863-6. OCLC 637267707.
  19. "Pentlandite Group". www.mindat.org. Retrieved 2023-02-20.
  20. Mansur, Eduardo T.; Barnes, Sarah-Jane; Duran, Charley J. (2021-01-01). "An overview of chalcophile element contents of pyrrhotite, pentlandite, chalcopyrite, and pyrite from magmatic Ni-Cu-PGE sulfide deposits". Mineralium Deposita. 56 (1): 179–204. Bibcode:2021MinDe..56..179M. doi:10.1007/s00126-020-01014-3. ISSN 1432-1866. S2CID 221674533.
  21. Rajamani, V.; Naldrett, A. J. (1978-02-01). "Partitioning of Fe, Co, Ni, and Cu between sulfide liquid and basaltic melts and the composition of Ni-Cu sulfide deposits". Economic Geology. 73 (1): 82–93. Bibcode:1978EcGeo..73...82R. doi:10.2113/gsecongeo.73.1.82. ISSN 1554-0774.
  22. Shewman, R. W.; Clark, L. A. (1970-02-01). "Pentlandite phase relations in the Fe–Ni–S system and notes on the monosulfide solid solution". Canadian Journal of Earth Sciences. 7 (1): 67–85. Bibcode:1970CaJES...7...67S. doi:10.1139/e70-005. ISSN 0008-4077.
  23. Frost, B. R.; Mavrogenes, J. A.; Tomkins, A. G. (2002-02-01). "Partial Melting of Sulfide Ore Deposits During Medium- and High-Grade Metamorphism". The Canadian Mineralogist. 40 (1): 1–18. doi:10.2113/gscanmin.40.1.1. ISSN 0008-4476.
  24. McQueen, K. G. (1987-05-01). "Deformation and remobilization in some Western Australian nickel ores". Ore Geology Reviews. 2 (1): 269–286. Bibcode:1987OGRv....2..269M. doi:10.1016/0169-1368(87)90032-1. ISSN 0169-1368.
  25. Piña, R.; Gervilla, F.; Barnes, S.-J.; Ortega, L.; Lunar, R. (2015-03-01). "Liquid immiscibility between arsenide and sulfide melts: evidence from a LA-ICP-MS study in magmatic deposits at Serranía de Ronda (Spain)". Mineralium Deposita. 50 (3): 265–279. Bibcode:2015MinDe..50..265P. doi:10.1007/s00126-014-0534-3. ISSN 1432-1866. S2CID 140179760.

Further reading
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