Di-tert-butoxyacetylene

Di-tert-butoxyacetylene is the organic compound with the formula (CH3)3COC≡COC(CH3)3. It is a pale yellow liquid. It is one of the more common dialkoxyacetylenes; most other dialkoxyacetylenes are very labile, for example, dimethoxyacetylene polymerizes within seconds at 0 °C. Di-tert-butoxyacetylene can be prepared from 1,4-dioxane in a multistep procedure.[1]

Di-tert-butoxyacetylene
Names
Other names
Di-tert-butoxyethyne
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C10H18O2/c1-9(2,3)11-7-8-12-10(4,5)6/h1-6H3
    Key: PPVDJWLEHWYMCQ-UHFFFAOYSA-N
  • CC(C)(C)OC#COC(C)(C)C
Properties
C10H18O2
Molar mass 170.252 g·mol−1
Appearance pale yellow oil
Melting point 8.5 °C (47.3 °F; 281.6 K)
Boiling point 30 °C (86 °F; 303 K) 0.05 mm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References

  1. Bou, Anna; Pericàs, Miquel A.; Riera, Antoni; Serratosa, Fèlix (1987). "Dialkoxyacetylenes: Di-tert-butoxyethyne, A Valuable Synthetic Intermediate". Organic Syntheses. 65: 68. doi:10.15227/orgsyn.065.0068.
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