Diethylhydroxylamine

Diethylhydroxylamine (DEHA) is an organic compound with the formula (C₂H₅)₂NOH. Strictly, this is N,N-diethylhydroxylamine. It has an isomer, N,O-diethylhydroxylamine with the formula EtNHOEt. N,N-diethylhydroxylamine is a colorless liquid, although it is usually encountered as a solution. It is mainly used as an oxygen scavenger in water treatment.

Diethylhydroxylamine

Names
Preferred IUPAC name N-Ethyl-N-hydroxyethanamine
Identifiers
CAS Number	3710-84-7 Y
3D model (JSmol)	Interactive image
Beilstein Reference	1731349
ChemSpider	18340 Y
ECHA InfoCard	100.020.960
EC Number	223-055-4
MeSH	N,N-diethylhydroxylamine
PubChem CID	19463
RTECS number	NC3500000
UNII	314I05EDVH Y
UN number	1993
CompTox Dashboard (EPA)	DTXSID2027543
InChI InChI=1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3 Y Key: FVCOIAYSJZGECG-UHFFFAOYSA-N Y
SMILES CCN(O)CC
Properties
Chemical formula	C4H11NO
Molar mass	89.138 g·mol−1
Appearance	Colorless liquid
Odor	Ammoniacal
Density	867 mg mL−1
Melting point	−26 to −25 °C (−15 to −13 °F; 247 to 248 K)
Boiling point	127.6 °C; 261.6 °F; 400.7 K
Solubility in water	Miscible
Vapor pressure	500 Pa (at 0 °C)
Acidity (pKa)	5.67 (est) [1]
Thermochemistry
Heat capacity (C)	370.8 J K−1 mol−1
Std enthalpy of formation (ΔfH⦵298)	−175.47–−174.03 kJ mol−1
Std enthalpy of combustion (ΔcH⦵298)	−2.97201–−2.97069 MJ mol−1
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H226, H312, H315, H319, H332
Precautionary statements	P280, P305+P351+P338
Explosive limits	1.9–10%
Lethal dose or concentration (LD, LC):
LD50 (median dose)	1.3 g kg−1 (dermal, rabbit) 2.19 g kg−1 (oral, rat)
Related compounds
Related alkanols	N-Methylethanolamine Dimethylethanolamine Diethylethanolamine Diethanolamine N,N-Diisopropylaminoethanol Methyl diethanolamine Triethanolamine Bis-tris methane Meglumine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Y verify (what is YN ?) Infobox references

It is a volatile oxygen scavenger[2][3] and reacts in a ratio of 2.8/1 DEHA/O2. It is employed in high pressure (>70 bar) boiler systems due to a very low rate of reaction at low temperatures and pressures. Due to its volatility, it acts as an oxygen scavenger throughout the entire boiler system due to steam carryover. DEHA also reacts with ferrous metals to form a passivized film of magnetite throughout the boiler system.

It has these other uses:

1. Polymerisation inhibitor
2. Color stabilizer (photographics)
3. Corrosion inhibitor
4. Discoloration inhibitor (phenolics)
5. Antiozonant
6. Radical scavenger[4]