Ferrario–Ackermann reaction

In organic chemistry, the Ferrario–Ackermann reaction or simply the Ferrario reaction is a name reaction that allow for the generation of phenoxanthiine from diphenyl ether and sulfur in the presence of aluminum chloride catalyst.[1][2][3][4][5][6]

Ferrario reaction
Ferrario–Ackermann reaction
Named after M. E. Ferrario
Fritz Ackermann
Reaction type Ring forming reaction

References
  1. Ferrario, E. (January 1911). "Preparation of phenoxathiin from diphenyl ether and sulfur". Bulletin de la Société Chimique de France. 9 (4): 536–537.
  2. Germany 234743, Fritz Ackermann, "Verfahren zur Darstellung von Phenoxthin und dessen Derivaten", published 20 May 1911
  3. Deasy, Clara L. (1 April 1943). "The Chemistry of Phenoxathiin and its Derivatives". Chemical Reviews. 32 (2): 173–194. doi:10.1021/cr60102a001.
  4. Suter, C. M.; Maxwell, Charles E. "Phenoxthin [Phenoxathiin]". Organic Syntheses. 18: 64. doi:10.15227/orgsyn.018.0064.; Collective Volume, vol. 2, p. 485
  5. Al-Araji, Suad M.; Mohamad, Ayad Ahmed (2 June 201). "Synthesis of New Pyrazoline - Phenoxathiin Derivatives". Baghdad Science Journal. 10 (2): 405–419. doi:10.21123/bsj.2013.10.2.405-419 (inactive 1 August 2023).{{cite journal}}: CS1 maint: DOI inactive as of August 2023 (link)
  6. Suter, C. M.; Green, Frank O. (1 December 1937). "Phenoxthin. II. Extension of the Ferrario Reaction". Journal of the American Chemical Society. 59 (12): 2578–2580. doi:10.1021/ja01291a030.



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