Francis S. Mair

Francis S. Mair is a British chemist and a Senior Lecturer in the Department of Chemistry at The University of Manchester.[1][2] His research is based on synthetic chemistry, inorganic chemistry, catalysis and polymer chemistry.[3]

Frank Mair
Born
Francis S. Mair

Scotland
Alma materUniversity of Strathclyde[1] (BSc., PhD)
Known forLigand Design
Inorganic synthesis
Polymerization catalysis
Awards
  • Ritchie Prize (1991) [2]
Scientific career
FieldsSynthetic Chemistry
Inorganic Chemistry
Catalysis
Polymer Chemistry
InstitutionsThe University of Manchester
ThesisSynthesis and Bonding Studies on Icosahedral Borane and Carborane Anions for Neutron Capture Therapy &quot (1991)

Education

Mair completed his Bachelor of Science degree in applied chemistry in 1988 at University of Strathclyde, where he investigated on borane cluster synthesis for his undergraduate research project. He continued to read for his Doctor of Philosophy degree at University of Strathclyde on Synthesis and Bonding Studies on Icosahedral Borane and Carborane Anions for Neutron Capture Therapy &quot and successfully completed it in 1991.[2][3]

Research and career

Mair worked as a research fellow at Queens from 1992 - 1993 where he worked on s-block coordination chemistry. He then moved to Trinity College Dublin as a lecturer where he worked on β-diketiminate ligands and s-block chemistry and in 1996 joined the Department of Chemistry at the University of Manchester as a lecturer in inorganic chemistry and later on was promoted to the position of senior lecturer.[2][4]

Mair's research is based on synthetic chemistry, inorganic chemistry, catalysis and polymer chemistry, specifically in the area of ligand Design, inorganic synthesis and polymerization catalysis.[1]

Apart from research and lecturing, Mair has also worked at the RSC, Manchester as the District Local Section Science Chair in 2017.[5][6] He also works in many chemistry based outreach activities, including the flash-bang show as well as in the Salters festival.[1][7][8][9][10]

Notable work

In 2015, Dr. Mair led a research to investigate the behaviour of β-triketimine cobalt complexes in the polymerization of isoprene,[11] and upon confirmation of the capability to use such complexes in polymerization, led a further research in 2016 on the use of enamine–diimine cobalt complexes in isoprene polymerization.[12] Both these researches indicated the potential to replace the use of more expensive neodymium complexes as a catalyst in the rubber industry, and also confirmed that the use of the cobalt complexes enhanced the polymerization rate of isoprene by 10 times, however also indicated issues including chances of cross-linking leading to gelation.[13] In general, the capability to replace the highly demanded Neodymium based catalysts was observed in this research, and it also confirmed the potential to replace it with cobalt and even more cheaper and abundant iron which may eventually help to reduce the cost of rubber production in the future.

In 1999, Dr. Mair led a research on a new supramolecular packing motif where he showed how the structure of N,N′,N″-tris(2-methoxyethyl)benzene-1,3,5-tricarboxamide consists of aryl rings self-assembled using a organized π-stack surrounded by a triple helical network of hydrogen bonds confirming a new mode of organization for columnar liquid crystals.[14]

In 1998, Dr. Mair also reported the first synthesis and use of the ligand, Dipp-NacNac as a N,N - bidentate anionic ligand, which is now currently one of the major alternatives that is available instead of common bulky ligands, including Cp*, and [RC(NR‘)2]− (R = Me, Ph; R‘ = Me3Si).[15][16]

Awards and nominations
  • Ritchie Prize (1991) [2]

Major publications
  • Mair, Frank S.; Alnajrani, Mohammed N. (2015). "The behaviour of β-triketimine cobalt complexes in the polymerization of isoprene". RSC Adv. 5 (57): 46372–46385. Bibcode:2015RSCAd...546372A. doi:10.1039/C5RA06792H. PMID 11670390. Retrieved 10 June 2020.
  • Mair, Frank S.; Alnajrani, Mohammed N. (2016). "Bidentate forms of β-triketimines: syntheses, characterization and outstanding performance of enamine–diimine cobalt complexes in isoprene polymerization". Dalton Trans. 45 (25): 10435–10446. Bibcode:2015RSCAd...546372A. doi:10.1039/C5RA06792H. PMID 27264840.
  • Pritchard, Robin G.; Warren, John E.; Lightfoot, Matthew P.; Mair, Frank S. (1999). "New supramolecular packing motifs: π-stacked rods encased in triply-helical hydrogen bonded amide strands". Chem. Commun. (19): 1945–1946. doi:10.1039/A905245C. Retrieved 10 June 2020.
  • Alnajran, Mohammed N.; Mair, Francis S. (2014). "Synthesis and characterization of β-triketimine cobalt complexes and their behaviour in the polymerization of 1,3-butadiene". Dalton Trans. 43 (42): 15727–15736. doi:10.1039/C4DT02196G. PMID 25211486.
  • McDouall, Joseph J. W.; Weston, Laura; Pownall, Barnaby T.; Mair, Francis S. (2016). "Thallophilic Tl(i)–Tl(i) contacts mediated by Tl–aryl interactions. A computational study". Dalton Trans. 45 (20): 8433–8439. doi:10.1039/C6DT01035K. PMID 27108889. S2CID 26526570.
  • Mair, Frank S.; Cope, Elaine K.; Clegg, William; Edwards, Andrew J. (1998). "Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex". Inorg. Chem. 37 (9): 2317–2319. doi:10.1021/ic970956j. PMID 11670390.

References
  1. University of Manchester. "Dr Francis Mair". Retrieved 10 June 2020.
  2. "Dr. Francis Mair (Linkedin)". Retrieved 10 June 2020.
  3. Mair, Frank (1991). Synthesis and Bonding Studies on Icosahedral Borane and Carborane Anions for Neutron Capture Therapy &quot (PhD thesis). (subscription required)
  4. "Academic and research staff (A-Z), Department of Chemistry". Retrieved 10 June 2020.
  5. "A Quantum Of Science". Retrieved 10 June 2020.
  6. "News: Manchester Literary and Philosophical Society". 29 March 2017. Retrieved 10 June 2020.
  7. "WELLACRE - Flash Bang Show, Transition event". Retrieved 10 June 2020.
  8. "Information for secondary schools". Retrieved 10 June 2020.
  9. Keeling, Neal (12 April 2017). "A blue plaque has been put up for John Dalton...but do you know who he is?". Manchester Evening News. Manchester. Retrieved 18 June 2020.
  10. Roberts, Alana (17 July 2019). "Sheffield sixth form students win regional final of school's chemistry competition". The Star. Sheffield. Retrieved 18 June 2020.
  11. Mair, Frank S.; Alnajrani, Mohammed N. (2015). "The behaviour of β-triketimine cobalt complexes in the polymerization of isoprene". RSC Adv. 5 (57): 46372–46385. Bibcode:2015RSCAd...546372A. doi:10.1039/C5RA06792H. Retrieved 10 June 2020.
  12. Mair, Frank S.; Alnajrani, Mohammed N. (2016). "Bidentate forms of β-triketimines: syntheses, characterization and outstanding performance of enamine–diimine cobalt complexes in isoprene polymerization". Dalton Trans. 45 (25): 10435–10446. Bibcode:2015RSCAd...546372A. doi:10.1039/C5RA06792H. PMID 27264840.
  13. Anastas, Paul; Warner, John (23 March 2000). Green Chemistry: Theory and Practice. UK: Oxford University Press. ISBN 9780198506980.
  14. Mair, Frank S.; Warren, John E.; Pritchard, Robin G.; Lightfoot, Matthew P. (1999). "New supramolecular packing motifs: π-stacked rods encased in triply-helical hydrogen bonded amide strands". Chem. Commun. (45): 1945–1946. doi:10.1039/A905245C.
  15. Mair, Frank S.; Cope, Elaine K.; Clegg, William; Edwards, Andrew J. (1998). "Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3]∞: A Heavy Alkali Metal Diazapentadienyl Complex". Inorg. Chem. 37 (9): 2317–2319. doi:10.1021/ic970956j. PMID 11670390.
  16. Bourget-Merle, Laurence; Lappert, Michael F.; Severn, John R. (2002). "The Chemistry of β-Diketiminatometal Complexes". Chem. Rev. 102 (9): 3031–3066. doi:10.1021/cr010424r. PMID 12222981.
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