Intermetallic particle

Intermetallic particles form during solidification of metallic alloys.

Aluminium alloys

Al-Si-Cu-Mg alloys

For example, Al-Si-Cu-Mg alloys form Al5FeSi- plate like intermetallic phase, Chinese script like -Al8Fe2Si, Al2Cu, etc. The size and morphology of these intermetallic phases in these alloys control the mechanical properties of these alloys especially strength and ductility.[1] The size of these phases depends on the secondary dendrite arm spacing,[2] as well as the Si content of the alloy,[3][4][5][6][7] of the primary phase in the micro structure.

Phases and crystal structures
PhaseStructureSpace Groupabcαβγ..
α-Al8Fe2Si[8]hexagonalp63/mmc(194)12.40412.40426.2349090120..
β-Al5FeSi[9]monoclinic2/m6.167606.166120.8093....91..
Al2Cu..................

Magnesium alloys

WE 43

In-situ synchrotron diffraction experiment[10] on Electron alloy-WE 43 (Mg4Y3Nd) shows that this alloy form the following intermetallic phases ;Mg12Nd, Mg14Y4Nd, and Mg24Y5.

Phases and crystal structures
PhaseStructureSpace Groupabcαβγ..
Mg41Nd5..................
β-Mg14Nd2Y[11]face centered cubic2.2 nm......
Mg24Y5[11]body centered cubic..1.12 nm............

References
  1. Caceres, C. H. Svensson, I. L. Taylor, J. A. "Strength-ductility behaviour of Al-Si-Cu-Mg casting alloys in T6 temper" (5). {{cite journal}}: Cite journal requires |journal= (help)CS1 maint: multiple names: authors list (link)
  2. Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (9 May 2013). "Alloy Composition and Dendrite Arm Spacing in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 44 (9): 4071–4080. Bibcode:2013MMTA...44.4071S. doi:10.1007/s11661-013-1768-x. S2CID 135926219.
  3. Sivarupan, Tharmalingam; Caceres, Carlos H.; Taylor, John A. (July 2013). "Effect of Si Content on the Size of Fe-Rich Intermetallic Particles in Al-xSi-0.8Fe Alloys". Materials Science Forum. 765: 107–111. CiteSeerX 10.1.1.1001.8916. doi:10.4028/www.scientific.net/MSF.765.107. S2CID 136622162.
  4. Sivarupan, T.; Taylor, J. A.; Cáceres, C. H. (2014). Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys. pp. 137–143. doi:10.1002/9781118888100.ch17. ISBN 9781118888100. {{cite book}}: |journal= ignored (help)
  5. Sivarupan, T.; Taylor, J. A.; Cáceres, C. H. (2014). Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys. pp. 137–143. doi:10.1002/9781118888100.ch17. ISBN 9781118888100. {{cite book}}: |journal= ignored (help)
  6. Sivarupan, Tharmalingam (2014). "Ductility and solidification issues in Al-Si-Cu-Mg alloys" (PDF). doi:10.14264/uql.2015.91. {{cite journal}}: Cite journal requires |journal= (help)
  7. Sivarupan, Tharmalingam; Taylor, John Andrew; Cáceres, Carlos Horacio (25 February 2015). "SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys". Metallurgical and Materials Transactions A. 46 (5): 2082–2107. Bibcode:2015MMTA...46.2082S. doi:10.1007/s11661-015-2808-5. S2CID 136803392.
  8. R.N. Corby and P.J. Black: Acta Crystallogr. Sect. B, 1977, vol. 33, pp. 3468–75.
  9. V. Hansen, B. Hauback, M. Sundberg, C. Romming, and J. Gjonnes: Acta Crystallogr. Sect. B, 1998, vol. 54, pp. 351–57.
  10. Tolnai, D.; Mendis, C.L.; Stark, A.; Szakács, G.; Wiese, B.; Kainer, K.U.; Hort, N. (July 2013). "In situ synchrotron diffraction of the solidification of Mg4Y3Nd" (PDF). Materials Letters. 102–103: 62–64. doi:10.1016/j.matlet.2013.03.110.
  11. "Archived copy" (PDF). Archived from the original (PDF) on 2014-07-15. Retrieved 2015-04-27.{{cite web}}: CS1 maint: archived copy as title (link)


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