Kačák Event

The Kačák Event (Czech pronunciation: [ˈkatʃaːk]), also known as the Kačák-otomari Event, is a widely recognised bioevent or series of events that occurred close to the end of the Eifelian Age of the Middle Devonian Epoch. It involved a global eustatic rise in sea level and ecological turnover.[1][2] It was named for the Kačák Member of the Srbsko Formation in Bohemia, where it is represented by a black shale interval within a sequence of limestone. In marine environments, this appears as an anoxic event, often forming potential hydrocarbon source rocks such as the Marcellus Shale. Within the Old Red Sandstone continent, it is represented by the Achanarras lake, the deepest and most widespread lake that developed within the Orcadian Basin. The event is associated with significant extinctions, particularly amongst the Ammonoidea.

Age and duration

The event occurred towards the end of the Eifelian, extending into the earliest part of the Givetian, in the mid-Devonian period. The duration of the event has been estimated as 700,000 years from the seven cycles involved in the Achanarras interval (each cycle interpreted to represent 100,000 years),[3] but only 200,000 years using geochemical and magnetic resonance data from the Eifelian-Givetian boundary in Morocco.[4]

Occurrence

The Kačák interval was first named from its occurrence in Bohemia as a black shale unit, known as the Kačák Member. This organic rich shale is found within a sequence of shallow water limestones forming the Srbsko Formation of the Prague Basin.[5] The event has also been recognised at Eifel in Germany, Gorodenka (near Omsk, Russia) and in Ontario and New York State in eastern North America, all localities lying on the then continental shelf around the Old Red continent. Further afield at the time of the event, on the continental shelf on the other side of the Rheic Ocean, it has been recognised in Morocco, Cantabria in northern Spain, the Carnic Alps and Graz Paleozoic in Italy and Austria, the Montagne Noire in France and in the Barrandian area of the Czech Republic. The Orcadian Basin of Scotland is the only locality within the continent itself that the event is recognised.[3][6] Similar events have also been correlated with the Kačák Event in China and Australia.[5] In Brazil, the event was registered in the Paraná Basin.[7] In the Horn River Group of Canada, the Kačák interval corresponds to an appearance of anoxic sedimentation and a termination of carbonate platform deposition.[8]

Geochemistry

At the level of the Kačák Event there is a marked negative excursion in the δ13C level, interpreted to be a result of the anoxic event.[6] This reduction matches closely to an increase in both total organic carbon and a change in the fractionation of carbon between carbonates and organic 'reservoirs'.[9]

Cause

The cause of this event is interpreted to be a period of high temperatures resulting from high insolation levels. This explains both the transgressive event recognised at the margins of the Old Red continent, caused by thermal expansion of the oceans, and the formation of the Achanarras lake within the continent due to the increased intensity of monsoon conditions.[3]

Extinctions

The Kačák Event was a period of significant extinctions, although not as marked as those of the subsequent Late Devonian extinctions. Pelagic or nektonic animals (which inhabited open ocean basins) were the most strongly affected. The ancestral ammonoid group, the agoniatitids, suffered heavy losses, while their descendants in the group Tornoceratina diversified at the same time.[10][5] Conodonts also experienced a turnover, and the Kačák Event is equivalent to the Polygnathus ensensis conodont zone. The first part of the extinction is sometimes known as the otomari event, named after Nowakia otomari, a widespread species of dacryconarid which appeared during the event while other dacryconarids died out.[11][12]

Economic importance

Organic-rich black shales that formed during this anoxic event occur in several countries. In the eastern United States the Marcellus shale is in the early stages of being exploited for shale gas, with large recoverable reserves predicted. An initial USGS assessment from 2002 suggested about 2 TCF of recoverable gas,[13] while in 2009, a study by the United States Department of Energy gave an estimate of 262 TCF.[14]

References
  1. Königshof, P.; Silva, A. C. Da; Suttner, T. J.; Kido, E.; Waters, J.; Carmichael, S. K.; Jansen, U.; Pas, D.; Spassov, S. (2016-01-01). "Shallow-water facies setting around the Kačák Event: a multidisciplinary approach". Geological Society, London, Special Publications. 423 (1): 171–199. doi:10.1144/SP423.4. ISSN 0305-8719. S2CID 131042746.
  2. DeSantis, M. K.; Brett, C. E.; Straeten, C. A. Ver (2007-01-01). "Persistent depositional sequences and bioevents in the Eifelian (early Middle Devonian) of eastern Laurentia: North American evidence of the Kačák Events?". Geological Society, London, Special Publications. 278 (1): 83–104. doi:10.1144/SP278.4. ISSN 0305-8719. S2CID 129585313.
  3. Marshall, J.A.E.; Astin, T.R.; Brown, J.F.; Mark-Kurik E.; Lazauskiene J. (2007). "Recognizing the Kačák Event in the Devonian terrestrial environment and its implications for understanding land–sea interactions". In Becker R.T. & Kirchgasser W.T. (ed.). Devonian events and correlations. Special Publications. Vol. 278. London: Geological Society. pp. 133–155. ISBN 9781862392229. Retrieved 3 March 2012.
  4. Ellwood, B.B.; Algeo T.J.; El Hassani A.; Tomkin J.H.; Rowe H.D. (2011). "Defining the timing and duration of the Kačák Interval within the Eifelian/Givetian boundary GSSP, Mech Irdane, Morocco, using geochemical and magnetic susceptibility patterns". Palaeogeography, Palaeoclimatology, Palaeoecology. Elsevier. 304 (1–2): 74–84. doi:10.1016/j.palaeo.2010.10.012.
  5. House, M.R. (1996). "The Middle Devonian Kačák Event" (PDF). Proceedings of the Ussher Society. 9: 79–84. Retrieved 3 March 2012.
  6. Kido, E.; Suttner T.J. (2011). "A new project has been launched: FWF P23775-B17 "Late Eifelian climate perturbations: effects on tropical coral communities"" (PDF). Jahrbuch der Geologischen Bundesanstalt. 151 (3–4): 407–416. ISSN 0016-7800. Retrieved 3 March 2012.
  7. Horodyski, R.S.; Holz, M.; Grahn, C.Y.; Bosetti, E.P. (2014). Remarks on the sequence stratigraphy and taphonomy of the relictual Malvinokaffric fauna during the Kačák event in the Paraná Basin, Brazil. International Journal of Earth Sciences, 103:367-380.
  8. Kabanov, Pavel; Hauck; Gouwy, Sofie A.; Grasby, Stephen E.; Van der Boon, Annique (10 April 2023). "Oceanic anoxic events, marine photic-zone euxinia, and controversy of sea-level fluctuations during the Middle-Late Devonian". Earth-Science Reviews. doi:10.1016/j.earscirev.2023.104415. Retrieved 19 April 2023.
  9. van Hengstum, P.J.; Gröcke D.R. (2008). "Stable isotope record of the Eifelian-Givetian boundary Kačák-otomari Event (Middle Devonian) from Hungry Hollow, Ontario, Canada" (PDF). Canadian Journal of Earth Sciences. 45 (3): 353–366. Bibcode:2008CaJES..45..353V. doi:10.1139/E08-005. Retrieved 4 March 2012.
  10. House, Michael R. (1985). "Correlation of mid-Palaeozoic ammonoid evolutionary events with global sedimentary perturbations". Nature. 313 (5997): 17–22. doi:10.1038/313017a0. ISSN 1476-4687. S2CID 34273115.
  11. DeSantis, M.K.; Brett C.E. (2011). "Late Eifelian (Middle Devonian) biocrises: Timing and signature of the pre-Kačák Bakoven and Stony Hollow Events in eastern North America". Palaeogeography, Palaeoclimatology, Palaeoecology. Elsevier. 304 (1–2): 113–135. doi:10.1016/j.palaeo.2010.10.013.
  12. Jamart, V.; Denayer, J. (2020). "The Kačák event (late Eifelian, Middle Devonian) on the Belgian shelf and its effects on rugose coral palaeobiodiversity" (PDF). Bulletin of Geosciences. 95 (3): 279–311. doi:10.3140/bull.geosci.1788. S2CID 225423367.
  13. Milici, R.; Swezey C.S. (2006). "Assessment of Appalachian Basin Oil and Gas Resources: Devonian Shale–Middle and Upper Paleozoic Total Petroleum System" (PDF). Open-File Report Series 2006-1237. United States Geological Survey. p. 39. Retrieved 7 March 2012.
  14. US Department of Energy (April 2009): Modern shale gas development in the United States: a primer Archived 2013-12-10 at the Wayback Machine, p.17, PDF file, downloaded 7 March 2012.
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