Magnesium ozonide

Magnesium ozonide
Identifiers
CAS Number	63172-13-4 (MgO3) ; 1252008-65-3 (Mg(O3)2) ;
3D model (JSmol)	Interactive image;
	InChI InChI=1S/Mg.HO3/c;1-3-2/h;1H/q+1;/p-1 Key: RBFCWJLHCQDAGO-UHFFFAOYSA-M;
	SMILES [Mg+].[O-]O[O];
Properties
Chemical formula	MgO3
Molar mass	72.302 g·mol−1
Appearance	White solid
Related compounds
Other cations	Potassium ozonide, Ammonium ozonide
Related compounds	Magnesium oxide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Magnesium ozonide is a compound with the formula Mg O₃. Much like other ozonides, it is only stable at low temperatures.[1] Unlike other ozonide compounds, magnesium ozonide is white rather than the typical red colour.[2]

Preparation

Magnesium ozonide can be made by passing a dilute mixture of ozone in liquid nitrogen and over magnesium at -259 °C.[1]

${\ce {O3 + Mg -> MgO3}}$

Magnesium bisonozide

Magnesium is also known to form bisozonide complexes, containing Mg(O₃)₂ complexed with argon or carbon monoxide, in an argon matrix.[3]

References

Andrews, Lester; Prochaska, Eleanor S.; Ault, Bruce S. (1978-07-15). "Matrix reactions of magnesium atoms with ozone. Infrared spectra of MgO, MgO₂, and MgO₃ in solid nitrogen". The Journal of Chemical Physics. 69 (2): 556–563. Bibcode:1978JChPh..69..556A. doi:10.1063/1.436646. ISSN 0021-9606.
Vol’nov, Il’ya Ivanovich (1966). Petrocelli, A. W. (ed.). Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals. Boston, MA: Springer US. doi:10.1007/978-1-4684-8252-2. ISBN 978-1-4684-8254-6.
Wang, Guanjun; Gong, Yu; Zhang, Qingqing; Zhou, Mingfei (2010). "Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon". Journal of Physical Chemistry A. 114 (40): 10803–10809. Bibcode:2010JPCA..11410803W. doi:10.1021/jp107434f. PMID 20857987.

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[:0-1] Andrews, Lester; Prochaska, Eleanor S.; Ault, Bruce S. (1978-07-15). "Matrix reactions of magnesium atoms with ozone. Infrared spectra of MgO, MgO₂, and MgO₃ in solid nitrogen". The Journal of Chemical Physics. 69 (2): 556–563. Bibcode:1978JChPh..69..556A. doi:10.1063/1.436646. ISSN 0021-9606.

[2] Vol’nov, Il’ya Ivanovich (1966). Petrocelli, A. W. (ed.). Peroxides, Superoxides, and Ozonides of Alkali and Alkaline Earth Metals. Boston, MA: Springer US. doi:10.1007/978-1-4684-8252-2. ISBN 978-1-4684-8254-6.

[3] Wang, Guanjun; Gong, Yu; Zhang, Qingqing; Zhou, Mingfei (2010). "Formation and Characterization of Magnesium Bisozonide and Carbonyl Complexes in Solid Argon". Journal of Physical Chemistry A. 114 (40): 10803–10809. Bibcode:2010JPCA..11410803W. doi:10.1021/jp107434f. PMID 20857987.