Methane (data page)
This page provides supplementary chemical data on methane.
Material Safety Data Sheet
The handling of this chemical may incur notable safety precautions.[1]
Structure and properties
Structure and properties | |
---|---|
Index of refraction, nD | 1.000444[2] |
Dielectric constant, εr | 1.6761 ε0 at −182 °C[3] 1.0008181 ε0 at −20 °C[4] |
Bond strength | ? |
Bond length | 0.10870 nm [5] |
Bond angle | 109.5° |
Magnetic susceptibility | −17.4×10−6 cm3/mol[6] |
Thermodynamic properties
Phase behavior | |
---|---|
Triple point | 90.67 K (−182.48 °C), 0.117 bar[7] |
Critical point | 190.6 K (−82.6 °C), 46.0 bar[7] |
Std enthalpy change of fusion, ΔfusH |
1.1 kJ/mol |
Std entropy change of fusion, ΔfusS |
12.1 J/(mol·K) |
Std enthalpy change of vaporization, ΔvapH |
8.17 kJ/mol |
Std entropy change of vaporization, ΔvapS |
? J/(mol·K) |
Solid properties | |
Std enthalpy change of formation, ΔfH |
? kJ/mol |
Standard molar entropy, S |
? J/(mol K) |
Heat capacity, cp | ? J/(mol K) |
Liquid properties | |
Std enthalpy change of formation, ΔfH |
? kJ/mol |
Standard molar entropy, S |
? J/(mol K) |
Heat capacity, cp | ? J/(mol K) |
Gas properties | |
Std enthalpy change of formation, ΔfH |
−74.6 kJ/mol[8] |
Standard molar entropy, S |
186.3 J/(mol K)[8] |
Enthalpy of combustion ΔcH |
−891 kJ/mol[9] |
Heat capacity, cp | 35.7 J/(mol K)[8] |
van der Waals' constants[10] | a = 228.29 L2 kPa/mol2 b = 0.04278 L/mol |
Vapor pressure of liquid
P (mm Hg) | 1 | 10 | 40 | 100 | 400 | 760 | 1520 | 3800 | 7600 | 15200 | 30400 | 45600 | |
T (°C) | −205.9(s) | −195.5(s) | −187.7(s) | −181.4 | −168.8 | −161.5 | −152.3 | −138.3 | −124.8 | −108.5 | −86.3 | — |
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed. Annotation "(s)" indicates equilibrium temperature of vapor over solid. Otherwise temperature is equilibrium of vapor over liquid. Note that these are all negative temperature values.
![](../I/LogMethaneVaporPressure.png.webp)
Methane vapor pressure vs. temperature. Uses formula given in Lange's Handbook of Chemistry, 10th ed. Note that formula loses accuracy near Tcrit = −82.6 °C
Spectral data
![](../I/Methane-ir.png.webp)
Methane infrared spectrum
UV-Vis | |
---|---|
λmax | ? nm |
Extinction coefficient, ε | ? |
IR | |
Major absorption bands | 3019, 2917, 1534, 1306 cm−1[11] |
NMR | |
Proton NMR | |
Carbon-13 NMR | −2.3 ppm[12] |
Other NMR data | |
MS | |
Masses of main fragments |
|
This box:
- Except where noted otherwise, data relate to Standard temperature and pressure.
- Reliability of data general note.
References
- Material Safety Datasheet . Iowa State
- Haynes, p. 10.256
- Haynes, p. 6.212
- Haynes, p. 6.221
- Haynes, p. 9.45
- Haynes, p. 3.578
- Haynes, p. 6.175
- Haynes, p. 5.26
- Haynes, p. 5.67
- Lange's Handbook of Chemistry, 10th ed, pp. 1522–1524.
- Haynes, p. 9.106
- Haynes, p. 8.67
Cited sources
- Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. ISBN 9781498754293.
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