Methyl hydroperoxide

Methyl hydroperoxide
Names
	IUPAC name Methaneperoxol
	Other names Hydroperoxide, methyl; Methane hydroperoxide; Methyl hydrogen peroxide; Hydroperoxymethane
Identifiers
CAS Number	3031-73-0 ;
3D model (JSmol)	Interactive image;
PubChem CID	18199;
CompTox Dashboard (EPA)	DTXSID10184401 ;
	InChI InChI=1S/CH4O2/c1-3-2/h2H,1H3 Key: MEUKEBNAABNAEX-UHFFFAOYSA-N;
	SMILES COO;
Properties
Chemical formula	CH4O2
Molar mass	48.041 g·mol−1
Appearance	colorless liquid
Density	0.9967 g/cm3 at 15°C
Melting point	<25 °C
Boiling point	46 °C (115 °F; 319 K)
Solubility in water	Miscible in water and diethyl ether
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	explosive
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Methyl hydroperoxide is the organic compound with the formula CH₃OOH. It is a volaltile colorless liquid. In addition to being of theoretical interest as the simplest organic hydroperoxide, methyl hydroperoxide is an intermediate in the oxidation of methane in the atmosphere.[1] When condensed or in concentrated form methyl hydroperoxide is rather explosive, unlike tertiary hydroperoxides such as tert-butylhydroperoxide.[2] Its laboratory preparation was first reported in 1929.[3]

References

Logan, Jennifer A.; Prather, Michael J.; Wofsy, Steven C.; McElroy, Michael B. (1981). "Tropospheric chemistry: A global perspective". Journal of Geophysical Research. 86 (C8): 7210. Bibcode:1981JGR....86.7210L. doi:10.1029/JC086iC08p07210.
Roger A. Sheldon (1983). Patai, Saul (ed.). Syntheses and Uses of Hydroperoxides and Dialkylperoxides. PATAI'S Chemistry of Functional Groups. John Wiley & Sons. doi:10.1002/9780470771730.ch6.
Rieche, Alfred; Hitz, Fritz (1929). "Über Monomethyl-hydroperoxyd)". Berichte der Deutschen Chemischen Gesellschaft. 62 (8): 2458–2474. doi:10.1002/cber.19290620888.

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[1] Logan, Jennifer A.; Prather, Michael J.; Wofsy, Steven C.; McElroy, Michael B. (1981). "Tropospheric chemistry: A global perspective". Journal of Geophysical Research. 86 (C8): 7210. Bibcode:1981JGR....86.7210L. doi:10.1029/JC086iC08p07210.

[Patai-2] Roger A. Sheldon (1983). Patai, Saul (ed.). Syntheses and Uses of Hydroperoxides and Dialkylperoxides. PATAI'S Chemistry of Functional Groups. John Wiley & Sons. doi:10.1002/9780470771730.ch6.

[3] Rieche, Alfred; Hitz, Fritz (1929). "Über Monomethyl-hydroperoxyd)". Berichte der Deutschen Chemischen Gesellschaft. 62 (8): 2458–2474. doi:10.1002/cber.19290620888.