Monofluoride

A monofluoride is a chemical compound with one fluoride per formula unit. For a binary compound, this is the formula XF.

Organofluorine compounds

Common monofluoride are organofluorine compounds such as methyl fluoride and fluorobenzene.

Inorganic compounds

All the alkali metals form monofluorides. All have the sodium chloride (rock salt) structure and are soluble in water and even some alcohols.[1] Because the fluoride anion is highly basic, many alkali metal fluorides form bifluorides with the formula MHF2. Sodium and potassium bifluorides are significant to the chemical industry.[2] Among other monofluorides, only silver(I)[3] and thallium(I)[4] fluorides are well-characterized. Both are very soluble, unlike the other halides of those metals.

Selected inorganic monofluorides

Examples of the monofluorides include:

Metal monofluorides

Nonmetal monofluorides

References

  1. Aigueperse et al. 2005, "Fluorine Compounds, Inorganic," pp. 25–27.
  2. Aigueperse et al. 2005, "Fluorine Compounds, Inorganic," pp. 26–27.
  3. Milne, George W. A. (2005). Gardner's commercially important chemicals. John Wiley and Sons. p. 553. ISBN 978-0-471-73518-2.
  4. Arora, M. G. (2003). P-block Elements. Anmol Publications. p. 35. ISBN 81-7488-563-3.

Bibliography

  • Aigueperse, Jean; Mollard, Paul; Devilliers, Didier; Chemla, Marius; Faron, Robert; Romano, Renée; Cuer, Jean Pierre (2005). Ullmann (ed.). Encyclopedia of Industrial Chemistry. Wiley-VCH. p. 35. doi:10.1002/14356007. ISBN 978-3-527-30673-2.
  • Greenwood, N. N.; Earnshaw, A. (1998). Chemistry of the Elements (second ed.). Butterworth Heinemann. ISBN 0-7506-3365-4.
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