Paul Fenter

Paul Fenter is a senior physicist and leader for Interfacial Processes Group, in the Chemical Sciences and Engineering Division at the U.S. Department of Energy’s (DOE) Argonne National Laboratory and the former director of the Center for Electrochemical Energy Science (CEES), a DOE Energy Frontier Research Center.

Paul Fenter
Alma materUniversity of Pennsylvania, Rensselaer Polytechnic Institute
EmployerArgonne National Laboratory
Known forinterfacial structure and dynamics, X-ray techniques
AwardsBertram E. Warren Diffraction Physics Award, UChicago Distinguished Performance Award
Websitehttps://www.anl.gov/profile/paul-a-fenter

Education and early career

Fenter holds a PhD from the University of Pennsylvania and a bachelor of science degree in physics from Rensselaer Polytechnic Institute.[1] He did his postdoctoral studies at Princeton University then joined Argonne in 1997 as a physicist.[1] Fenter has led the Interfacial Processes group since 2000 and was promoted to senior physicist in 2007.[2] Fenter became director of the Center for Electrochemical Energy Science in 2014.[2] While under his leadership (2014-2021), CEES contributed[3] several new insights on the behavior of cathodes in lithium ion batteries, and was recognized by the DOE for making a pivotal discovery in battery technology.[4] Fenter is also an adjunct professor at the University of Illinois at Chicago[2] and a Senior Scientist at Large in the UChicago Consortium for Advanced Science and Engineering.

Career

Fenter’s research has centered on understanding the structure and reactivity of solid-liquid interfaces through direct in-situ and operando studies. Such interfaces are pervasive in natural and engineered systems (e.g., geochemical interfaces of minerals in the natural environment, electrode-electrolyte interfaces in energy storage and catalytic systems, etc.) but are generally poorly understood due to the paucity of tools that can probe such interfaces at the conditions of interest.  His work has led to new advances in understanding of these systems including: the presence of interfacial hydration layers at solid-water interfaces,[5] the complex behavior of ions at charged solid-liquid interfaces (e.g., including the coexistence of multiple discrete ion adsorption states),[6][7] and  the role of interfacial reactivity in controlling lithium ion battery conversion reactions.[8] Fenter also specializes in development of novel X-ray-based techniques to understand the structure and reactivity at liquid-solid interfaces.

As the director of CEES, Fenter led a multi-institutional research program (with partners at Northwestern University,[9] University of Illinois and Purdue University) that studied the chemical reactions that limit the lifetime and safety of lithium ion batteries (LIBs). This included studies of the interface between electrodes and the electrolytes, and approaches to stabilize the electrode-electrolyte interface.[3] CEES also explored novel “beyond lithium ion insertion” chemistries that can lead to substantial increases in the energy storage capacity of LIBs.[3][4]

For his contributions, Fenter was awarded the 2012 Bertram E. Warren Diffraction Physics Award from the American Crystallographic Association[10] and The University of Chicago’s Board of Governors Distinguished Performance Award in 2018.[11] He was also named a fellow of the American Physical Society in 2008[12] and is a member of the American Chemical Society, and Geochemical Society.[1]

Research

Understanding mineral interactions with water

Fenter uses X-ray based approaches to understand the structure and reactivity of liquid-solid interfaces found in natural systems. The interactions between water, dissolved ions, and minerals are fundamental to many chemical processes, like ion exchange and environmental transport. Fenter has leveraged X-ray approaches to uncover new details about the structure of water at the interface,[13][14] and the arrangement of ions at charged mineral-water interfaces[15] known as the “electrical double layer”.

Advances in Lithium Ion Battery Systems

As the director of CEES, Fenter led a multi-institutional research program (with partners at Northwestern University, University of Illinois and Purdue University) that studied the chemical reactions that limit the lifetime and safety of lithium ion batteries (LIBs). This included studies of the interface between electrodes and the electrolytes, and approaches to stabilize the electrode-electrolyte interface. CEES also explored novel “beyond lithium ion insertion” chemistries that can lead to substantial increases in the energy storage capacity of LIBs.

Enhancing X-rays methods for interfacial studies

Fenter has extended the capabilities of X-ray scattering, spectroscopy, and microscopy techniques for analyzing interfacial processes. One example is the demonstration of “model-independent imaging” as a conceptual approach for visualizing the distribution of an element near interfaces through the use of phase-sensitive measurements (including resonant anomalous X-ray reflectivity[16] and X-ray standing waves[17]). These capabilities enabled new insights into ion adsorption structures, and been also applied to studies of mineral-water dynamics.[15] He also invented a novel X-ray microscope [18] that can image sub-nanometer high interfacial topography and dissolution dynamics.[19] Most recently, he has demonstrated a new general solution to the phase problem for the case of coherently illuminated atomistic structures.[20]

Honors

References
  1. "Paul A. Fenter | Argonne National Laboratory". www.anl.gov. Retrieved 2020-02-24.
  2. "Paul Venter CV Aug 2018" (PDF).
  3. "DOE CEES Selected Scientific Accomplishments" (PDF).
  4. "Argonne-led center receives award for pivotal discovery in battery technology | Argonne National Laboratory". www.anl.gov. Retrieved 2020-02-24.
  5. Fenter, Paul; Sturchio, Neil C. (2004). "Mineral–water interfacial structures revealed by synchrotron X-ray scattering". Progress in Surface Science. 77 (5–8): 171–258. doi:10.1016/j.progsurf.2004.12.001.
  6. Park, Changyong; Fenter, Paul A.; Nagy, Kathryn L.; Sturchio, Neil C. (2006-07-05). "Hydration and Distribution of Ions at the Mica-Water Interface". Physical Review Letters. 97 (1): 016101. doi:10.1103/PhysRevLett.97.016101. ISSN 0031-9007. PMID 16907385.
  7. Lee, Sang Soo; Fenter, Paul; Park, Changyong; Sturchio, Neil C.; Nagy, Kathryn L. (2010-11-16). "Hydrated Cation Speciation at the Muscovite (001)−Water Interface". Langmuir. 26 (22): 16647–16651. doi:10.1021/la1032866. ISSN 0743-7463. PMID 20932042.
  8. Evmenenko, Guennadi; Warburton, Robert E.; Yildirim, Handan; Greeley, Jeffrey P.; Chan, Maria K. Y.; Buchholz, D. Bruce; Fenter, Paul; Bedzyk, Michael J.; Fister, Timothy T. (2019-07-23). "Understanding the Role of Overpotentials in Lithium Ion Conversion Reactions: Visualizing the Interface". ACS Nano. 13 (7): 7825–7832. doi:10.1021/acsnano.9b02007. ISSN 1936-0851. OSTI 1566739. PMID 31117380. S2CID 162182530.
  9. "Supercharged. Better Batteries Ahead". Northwestern Engineering. Retrieved 2020-02-24.
  10. "Argonne physicist Fenter wins Warren Award for X-ray diffraction studies | Argonne National Laboratory". www.anl.gov. Retrieved 2020-02-24.
  11. "Awards & Recognition | Argonne National Laboratory". www.anl.gov. Retrieved 2020-02-24.
  12. "Six Argonne scientists elected American Physical Society fellows | Argonne National Laboratory". www.anl.gov. Retrieved 2020-02-24.
  13. Fenter, Paul; Sturchio, Neil C. (2004-01-01). "Mineral–water interfacial structures revealed by synchrotron X-ray scattering". Progress in Surface Science. 77 (5): 171–258. doi:10.1016/j.progsurf.2004.12.001. ISSN 0079-6816.
  14. Fenter, Paul; Lee, Sang Soo (December 2014). "Hydration layer structure at solid–water interfaces". MRS Bulletin. 39 (12): 1056–1061. doi:10.1557/mrs.2014.252. ISSN 0883-7694.
  15. "Mica provides clue to how water transports minerals | Argonne National Laboratory". www.anl.gov. Retrieved 2020-02-24.
  16. Ciccariello, S.; Riello, P. (2007-04-01). "Small-angle scattering from three-phase samples: application to coal undergoing an extraction process". Journal of Applied Crystallography. 40 (2): 282–289. doi:10.1107/S002188980700564X. ISSN 0021-8898.
  17. Bedzyk, M. J.; Fenter, P.; Zhang, Z.; Cheng, L.; Okasinski, J. S.; Sturchio, N. C. (2004-05-01). "X‐ray Standing Wave Imaging". Synchrotron Radiation News. 17 (3): 5–10. doi:10.1080/08940880408603088. ISSN 0894-0886. S2CID 121041399.
  18. Fenter, Paul; Park, Changyong; Zhang, Zhan; Wang, Steve (October 2006). "Observation of subnanometre-high surface topography with X-ray reflection phase-contrast microscopy". Nature Physics. 2 (10): 700–704. doi:10.1038/nphys419. ISSN 1745-2481.
  19. Laanait, Nouamane; Callagon, Erika B. R.; Zhang, Zhan; Sturchio, Neil C.; Lee, Sang Soo; Fenter, Paul (2015-09-18). "X-ray–driven reaction front dynamics at calcite-water interfaces". Science. 349 (6254): 1330–1334. doi:10.1126/science.aab3272. ISSN 0036-8075. PMID 26383950.
  20. Calvo-Almazán, Irene; Fenter, Paul (2021-07-01). "The Patterson function as auto-hologram and graph enables the direct solution to the phase problem for coherently illuminated atomistic structures". New Journal of Physics. 23 (7): 073018. doi:10.1088/1367-2630/ac0d2d. ISSN 1367-2630.
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