Process heat

The required temperature of the process varies widely, with about half the industrial process heat having operating temperatures above 400 °C (752 °F). These higher-temperature processes can generally only be supplied by dedicated supplies like natural gas or coal, although pre-heating from other sources is also common in order to reduce fuel use. Those processes operating below the median can draw on a much wider variety of sources, including waste heat from other processes in the same industrial process. Resistive heating would in theory be a possible source of process heat but even as it converts nearly 100% of the supplied electricity to heat, it is obviously less efficient to burn a fuel in a thermal power plant to produce electricity only to use that electricity for process heat than to use the fuel directly. Thus this source of heat is only used where electricity from non-thermal sources (such as hydropower) is cheap and plentiful. Heat pumps which are commonly employed for home heating, warm water and other heat applications below 100 °C (212 °F) have too low a Carnot efficiency at high temperature differences between "hot" and "cold" end to be worthwhile. Some processes such as molten salt electrolysis provide the required process heat by the same electricity that is also needed to keep the endothermic reaction going. Heat is usually described by "grade" with higher temperatures having a higher "grade". This is because heat naturally flows from hot to cold and it is thus always possible to use a high temperature source of heat for lower temperature applications but not vice versa. As higher grade heat is more cumbersome and expensive to produce and as materials have limited heat resistance, there are efforts to reduce working temperatures wherever possible through the use of catalysts and fluxes. In equilibrium reactions where temperature is one of the factors influencing the equilibrium, temperature requirements can be reduced by removing the desired products in a continuous process. For example, if an equilibrium reaction between AB and CD produces AC and BD and the equilibrium can be shifted rightward by increasing temperature, continuously removing AC or BD from the reaction can serve to reduce the temperature requirements (c.f. principle of Le Chatelier). However, there are limits to this as the speed of reaction is also temperature-dependent. Catalysts can serve to increase the speed of reaction at any given temperature but they, by definition, do not shift the equilibrium.

Process heat accounts for approximately 30% of all the fuel use in the manufacturing sector, and is the target of significant efforts to introduce new forms of carbon neutral or at least lower carbon process heat supplies. Some wastes - including waste tires - are commonly used as replacement fuels or mixed into conventional fuel at appropriate ratios.[1] Biomass is already in widespread use in industry, while geothermal, concentrated solar power and nuclear power remain experimental and are not currently economically competitive. A problem with using nuclear power for process heat is that commonly used pressurized water reactors have an operating temperature well below 400°C[2] and boiling water reactors work at lower temperatures still (around 285 °C (545 °F)).[3] The Advanced Gas-cooled Reactor - whose high coolant outlet temperature was an explicit design goal - has proven a technological dead end and no other high temperature nuclear power plant has ever entered widespread commercial operation as of 2022.[4] Some Generation IV reactor proposals would change this, allowing higher grade heat to be produced. Likewise geothermal heat sources often have relatively low temperatures, sometimes even requiring binary cycles for electricity generation.[5][6]

A stopgap solution for decarbonization at the price of increased costs (ignoring carbon pricing) and lower round trip efficiency is the replacement of currently used fossil fuels by Power to X derived fuels. While this approach has the advantage of being usable with existing technology with minimal or no modification, it is less efficient than even resistive heating as the chemical processes required to turn electric energy into artificial fuels are less efficient than resistive heating. In processes where the fuel provides both heat and a chemical function (e.g. coke as a reducing agent in steelmaking) a power-to-x fuel may however be the only feasible low carbon alternative for some time to come. Hydrogen derived via processes such as electrolysis of water is often proposed as an alternative to current sources of process heat. Hydrogen is already in widespread use in industry today but is mostly derived from fossil fuels via processes such as steam reforming as of 2022. As some proposed processes for hydrogen production like the sulfur-iodine cycle themselves require high temperatures, their feasibility for generating hydrogen as a fuel for process heat as opposed to the direct use of the heat needed for the process seems questionable.

• Toledano, Ilan (16 May 2016). "Process heating for manufacturing 101". Processing.
• "Renewable Industrial Process Heat". Environmental Protection Agency. 28 October 2014.