Pyrosilicic acid

Pyrosilicic acid
Names
	IUPAC name Trihydroxysilyl trihydrogen orthosilicate
	Other names disilicic acid
Identifiers
CAS Number	20638-18-0 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:29292 ;
ChemSpider	55684 ;
Gmelin Reference	26937
PubChem CID	61804;
	InChI InChI=1S/H6O7Si2/c1-8(2,3)7-9(4,5)6/h1-6H Key: KDJOAYSYCXTQGG-UHFFFAOYSA-N ;
	SMILES O[Si](O)(O)O[Si](O)(O)O;
Properties
Chemical formula	H6O7Si2
Molar mass	174.211 g·mol−1
Conjugate base	Pyrosilicate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). (what is ?) Infobox references

Pyrosilicic acid is the chemical compound with formula H₆Si₂O₇ or (HO)₃SiOSi(OH)₃. It is one of the silicic acids and has pyrosilicate as its conjugate base.

It was synthesized, using nonaqueous solutions, in 2017.[1]

{\ce {H6Si2O7(aq) -> 2 SiO2(s) + 3 H2O}}

Pyrosilicic acid may be present in sea water and other natural waters at very low concentration.[2][3] Compounds formally derived from it, such as sodium pyrosilicate, are found in the sorosilicate minerals.

References

Igarashi, Masayasu; Matsumoto, Tomohiro; Yagahashi, Fujio; Yamashita, Hiroshi; Ohhara, Takashi; Hanashima, Takayasu; Nakao, Akiko; Moyosh, Taketo; Sato, Kazuhiko; Shimada, Shigeru (2017). "Non-aqueous selective synthesis of orthosilicic acid and its oligomers". Nature Communications. 8 (1): 140. Bibcode:2017NatCo...8..140I. doi:10.1038/s41467-017-00168-5. PMC 5529440. PMID 28747652.
Katsumi Goto (1956): "Effect of pH on Polymerization of Silicic Acid". Journal of Physical Chemistry, volume 60, issue 7, pages 1007–1008. doi:10.1021/j150541a046
M. F. Bechtold (1955): "Polymerization and Properties of Dilute Aqueous Silicic Acid from Cation Exchange". Journal of Physical Chemistry, volume 59, issue 6, pages 532–541. doi:10.1021/j150528a013

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[synthesis-1] Igarashi, Masayasu; Matsumoto, Tomohiro; Yagahashi, Fujio; Yamashita, Hiroshi; Ohhara, Takashi; Hanashima, Takayasu; Nakao, Akiko; Moyosh, Taketo; Sato, Kazuhiko; Shimada, Shigeru (2017). "Non-aqueous selective synthesis of orthosilicic acid and its oligomers". Nature Communications. 8 (1): 140. Bibcode:2017NatCo...8..140I. doi:10.1038/s41467-017-00168-5. PMC 5529440. PMID 28747652.

[goto-2] Katsumi Goto (1956): "Effect of pH on Polymerization of Silicic Acid". Journal of Physical Chemistry, volume 60, issue 7, pages 1007–1008. doi:10.1021/j150541a046

[bech-3] M. F. Bechtold (1955): "Polymerization and Properties of Dilute Aqueous Silicic Acid from Cation Exchange". Journal of Physical Chemistry, volume 59, issue 6, pages 532–541. doi:10.1021/j150528a013