Isotopes of ruthenium

Isotopes of ruthenium (₄₄Ru)
γ	–
γ	–
Standard atomic weight Ar°(Ru)
	101.07±0.02; 101.07±0.02 (abridged)[2][3];

Naturally occurring ruthenium (₄₄Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are ¹⁰⁶Ru, with a half-life of 373.59 days; ¹⁰³Ru, with a half-life of 39.26 days and ⁹⁷Ru, with a half-life of 2.9 days.

Twenty-four other radioisotopes have been characterized with atomic weights ranging from 86.95 u (⁸⁷Ru) to 119.95 u (¹²⁰Ru). Most of these have half-lives that are less than five minutes, except ⁹⁴Ru (half-life: 51.8 minutes), ⁹⁵Ru (half-life: 1.643 hours), and ¹⁰⁵Ru (half-life: 4.44 hours).

The primary decay mode before the most abundant isotope, ¹⁰²Ru, is electron capture and the primary mode after is beta emission. The primary decay product before ¹⁰²Ru is technetium and the primary product after is rhodium.

Because of the very high volatility of ruthenium tetroxide (RuO
₄) ruthenium radioactive isotopes with their relative short half-life are considered as the second most hazardous gaseous isotopes after iodine-131 in case of release by a nuclear accident.[4][5][6] The two most important isotopes of ruthenium in case of nuclear accident are these with the longest half-life: ¹⁰³Ru (≥ 1 month) and ¹⁰⁶Ru (≥ 1 year).[5]

List of isotopes

Nuclide [n 1]	Z	N	Isotopic mass (Da) [n 2][n 3]	Half-life [n 4]	Decay mode [n 5]	Daughter isotope [n 6]	Spin and parity [n 7][n 4]	Natural abundance (mole fraction)
Nuclide [n 1]	Excitation energy[n 4]			Half-life [n 4]	Decay mode [n 5]	Daughter isotope [n 6]	Spin and parity [n 7][n 4]	Normal proportion	Range of variation
⁸⁷Ru	44	43	86.94918(64)#	50# ms [>1.5 µs]	β⁺	⁸⁷Tc	1/2−#
⁸⁸Ru	44	44	87.94026(43)#	1.3(3) s [1.2(+3−2) s]	β⁺	⁸⁸Tc	0+
⁸⁹Ru	44	45	88.93611(54)#	1.38(11) s	β⁺	⁸⁹Tc	(7/2)(+#)
⁹⁰Ru	44	46	89.92989(32)#	11.7(9) s	β⁺	⁹⁰Tc	0+
⁹¹Ru	44	47	90.92629(63)#	7.9(4) s	β⁺	⁹¹Tc	(9/2+)
^91mRu	80(300)# keV			7.6(8) s	β⁺ (>99.9%)	⁹¹Tc	(1/2−)
					IT (<.1%)	⁹¹Ru
					β⁺, p (<.1%)	⁹⁰Mo
⁹²Ru	44	48	91.92012(32)#	3.65(5) min	β⁺	⁹²Tc	0+
⁹³Ru	44	49	92.91705(9)	59.7(6) s	β⁺	⁹³Tc	(9/2)+
^93m1Ru	734.40(10) keV			10.8(3) s	β⁺ (78%)	⁹³Tc	(1/2)−
					IT (22%)	⁹³Ru
					β⁺, p (.027%)	⁹²Mo
^93m2Ru	2082.6(9) keV			2.20(17) µs			(21/2)+
⁹⁴Ru	44	50	93.911360(14)	51.8(6) min	β⁺	⁹⁴Tc	0+
^94mRu	2644.55(25) keV			71(4) µs			(8+)
⁹⁵Ru	44	51	94.910413(13)	1.643(14) h	β⁺	⁹⁵Tc	5/2+
⁹⁶Ru	44	52	95.907598(8)	Observationally Stable[n 8]			0+	0.0554(14)
⁹⁷Ru	44	53	96.907555(9)	2.791(4) d	β⁺	^97mTc	5/2+
⁹⁸Ru	44	54	97.905287(7)	Stable[n 9]			0+	0.0187(3)
⁹⁹Ru	44	55	98.9059393(22)	Stable[n 9]			5/2+	0.1276(14)
¹⁰⁰Ru	44	56	99.9042195(22)	Stable[n 9]			0+	0.1260(7)
¹⁰¹Ru[n 10]	44	57	100.9055821(22)	Stable[n 9]			5/2+	0.1706(2)
^101mRu	527.56(10) keV			17.5(4) µs			11/2−
¹⁰²Ru[n 10]	44	58	101.9043493(22)	Stable[n 9]			0+	0.3155(14)
¹⁰³Ru[n 10]	44	59	102.9063238(22)	39.26(2) d	β⁻	¹⁰³Rh	3/2+
^103mRu	238.2(7) keV			1.69(7) ms	IT	¹⁰³Ru	11/2−
¹⁰⁴Ru[n 10]	44	60	103.905433(3)	Observationally Stable[n 11]			0+	0.1862(27)
¹⁰⁵Ru[n 10]	44	61	104.907753(3)	4.44(2) h	β⁻	¹⁰⁵Rh	3/2+
¹⁰⁶Ru[n 10]	44	62	105.907329(8)	373.59(15) d	β⁻	¹⁰⁶Rh	0+
¹⁰⁷Ru	44	63	106.90991(13)	3.75(5) min	β⁻	¹⁰⁷Rh	(5/2)+
¹⁰⁸Ru	44	64	107.91017(12)	4.55(5) min	β⁻	¹⁰⁸Rh	0+
¹⁰⁹Ru	44	65	108.91320(7)	34.5(10) s	β⁻	¹⁰⁹Rh	(5/2+)#
¹¹⁰Ru	44	66	109.91414(6)	11.6(6) s	β⁻	¹¹⁰Rh	0+
¹¹¹Ru	44	67	110.91770(8)	2.12(7) s	β⁻	¹¹¹Rh	(5/2+)
¹¹²Ru	44	68	111.91897(8)	1.75(7) s	β⁻	¹¹²Rh	0+
¹¹³Ru	44	69	112.92249(8)	0.80(5) s	β⁻	¹¹³Rh	(5/2+)
^113mRu	130(18) keV			510(30) ms			(11/2−)
¹¹⁴Ru	44	70	113.92428(25)#	0.53(6) s	β⁻ (>99.9%)	¹¹⁴Rh	0+
¹¹⁴Ru	44	70	113.92428(25)#	0.53(6) s	β⁻, n (<.1%)	¹¹³Rh	0+
¹¹⁵Ru	44	71	114.92869(14)	740(80) ms	β⁻ (>99.9%)	¹¹⁵Rh
¹¹⁵Ru	44	71	114.92869(14)	740(80) ms	β⁻, n (<.1%)	¹¹⁴Rh
¹¹⁶Ru	44	72	115.93081(75)#	400# ms [>300 ns]	β⁻	¹¹⁶Rh	0+
¹¹⁷Ru	44	73	116.93558(75)#	300# ms [>300 ns]	β⁻	¹¹⁷Rh
¹¹⁸Ru	44	74	117.93782(86)#	200# ms [>300 ns]	β⁻	¹¹⁸Rh	0+
¹¹⁹Ru	44	75	118.94284(75)#	170# ms [>300 ns]
¹²⁰Ru	44	76	119.94531(86)#	80# ms [>300 ns]			0+
This table header & footer:

^mRu – Excited nuclear isomer.
( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
# – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
# – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
Modes of decay:

IT: Isomeric transition

n: Neutron emission

p: Proton emission
Bold symbol as daughter – Daughter product is stable.
( ) spin value – Indicates spin with weak assignment arguments.
Believed to undergo β⁺β⁺ decay to ⁹⁶Mo with a half-life over 6.7×10¹⁶ years
Theoretically capable of spontaneous fission
Fission product
Believed to undergo β⁻β⁻ decay to ¹⁰⁴Pd

Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
In September 2017 an estimated amount of 100 to 300 TBq (0.3 to 1 g) of ¹⁰⁶Ru was released in Russia, probably in the Ural region. It was, after ruling out release from a reentering satellite, concluded that the source is to be found either in nuclear fuel cycle facilities or radioactive source production. In France levels up to 0.036mBq/m³ of air were measured. It is estimated that over distances of the order of a few tens of kilometres around the location of the release levels may exceed the limits for non-dairy foodstuffs.[7]

Ruthenium-96

References

Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
"Standard Atomic Weights: Ruthenium". CIAAW. 1983.
Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; et al. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
Ronneau, C., Cara, J., & Rimski-Korsakov, A. (1995). Oxidation-enhanced emission of ruthenium from nuclear fuel. Journal of Environmental Radioactivity, 26(1), 63-70.
Backman, U., Lipponen, M., Auvinen, A., Jokiniemi, J., & Zilliacus, R. (2004). Ruthenium behaviour in severe nuclear accident conditions. Final report (No. NKS–100). Nordisk Kernesikkerhedsforskning.
Beuzet, E., Lamy, J. S., Perron, H., Simoni, E., & Ducros, G. (2012). Ruthenium release modelling in air and steam atmospheres under severe accident conditions using the MAAP4 code. Nuclear Engineering and Design, 246, 157-162.
Detection of ruthenium 106 in France and in Europe, IRSN France (9 Nov 2017)

Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
Isotopic compositions and standard atomic masses from:
- de Laeter, John Robert; Böhlke, John Karl; De Bièvre, Paul; Hidaka, Hiroshi; Peiser, H. Steffen; Rosman, Kevin J. R.; Taylor, Philip D. P. (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- Wieser, Michael E. (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.

"News & Notices: Standard Atomic Weights Revised". International Union of Pure and Applied Chemistry. 19 October 2005.
Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.

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[7] Ru – Excited nuclear isomer.

[8] ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.

[TMS-9] # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).

[TNN-10] # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).

[11] Modes of decay:

IT: Isomeric transition

n: Neutron emission

p: Proton emission

[12] Bold symbol as daughter – Daughter product is stable.

[13] ( ) spin value – Indicates spin with weak assignment arguments.

[14] Believed to undergo β⁺β⁺ decay to ⁹⁶Mo with a half-life over 6.7×10¹⁶ years

[SF-15] Theoretically capable of spontaneous fission

[FP-16] Fission product

[17] Believed to undergo β⁻β⁻ decay to ¹⁰⁴Pd

[NUBASE2020-1] Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.

[2] "Standard Atomic Weights: Ruthenium". CIAAW. 1983.

[CIAAW2021-3] Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; et al. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.

[Ronneau_1995-4] Ronneau, C., Cara, J., & Rimski-Korsakov, A. (1995). Oxidation-enhanced emission of ruthenium from nuclear fuel. Journal of Environmental Radioactivity, 26(1), 63-70.

[Backman_2004-5] Backman, U., Lipponen, M., Auvinen, A., Jokiniemi, J., & Zilliacus, R. (2004). Ruthenium behaviour in severe nuclear accident conditions. Final report (No. NKS–100). Nordisk Kernesikkerhedsforskning.

[Beuzet_2012-6] Beuzet, E., Lamy, J. S., Perron, H., Simoni, E., & Ducros, G. (2012). Ruthenium release modelling in air and steam atmospheres under severe accident conditions using the MAAP4 code. Nuclear Engineering and Design, 246, 157-162.

[18] Detection of ruthenium 106 in France and in Europe, IRSN France (9 Nov 2017)