Selenide iodide

The selenide iodides are chemical compounds that contain both selenide ions (Se2−) and iodide ions (I−) and one or metal atoms. They are in the class of mixed anion compounds or chalcogenide halides.[1]

Some related compounds do not actually contain a selenide ion, instead containing an iodoselenium cation. These cations include SeI3+, Se2I42+, Se6I22+, and polymeric Se6I+.[2]

List
name formula MW system space group unit cell cell

volume

 density properties ref
Ti4Se9I6 triclinic P1 a = 7.965 b = 10.339 c = 15.692; α = 79.116°, β = 75.861°, γ = 71.437°; Z = 2 black [3]
V4O(Se2)4I6·I2 1866.64 tetragonal P42/nbc a=11.8384 c=18.689 Z=4 2619.2 4.734 dark blue [4]
CuSe3I trigonal R3m a=9.601 V= 872.859 [5]
α AsSeI monoclinic P2s a=8.855 b=4.194 c=10.341 β=93.74 Z=4 5.14 melt 221 °C dark red metallic [6]
β AsSeI cubic F4132 a=11.05 Z=16 5.53 dark red metallic [6]
AsF6Se6I [2]
triniobium selenide heptaiodide Nb3SeI7 hexagonal P63mc [1]
(Nb4Se15I2)I2 monoclinic P21/c a=8.8807 b=25.8368 c=11.6222 β=103.437° 1D; band gap 0.6 eV [7]
[Mo3Se7(TeI3)I2]I 1729.54 P23/n a=10.4969 b=13.029 c=16.567 β =102.921° Z=4 2208.3 5.202 [1][8]
Pd2SeI3 orthorhombic metallic black [9]
heptasilver(I) tetraseleniogermanate(IV) selenide iodide Ag7GeISe5 cubic F43m a=10.9864 Z=4 1326.1 6.740 black; silver ion conductor [10]
CdBiSe2I monoclinic C2/m [1]
indium selenide iodide InSeI tetragonal I41/a [1]
Antimony selenide iodide SbSeI orthorhombic Pnma band gap 1.70 eV n-type semiconductor [1]
SbF6Se6I [2]
Cs3Mo6I6Se2I6 [1]
Cs3Mo6I7SeI6 [1]
tribarium tetraselenide diiodide Ba3Se4I2 monoclinic C2/c a = 15.080 Å, b = 10.400 Å, c = 8.383 Å, β = 103.206°, Z = 4 [11]
Ta2Se8I tetragonal a = 9.59 c = 12.64 Charge-density-wave Weyl semimetal [12][13]
tritantalum selenide heptaiodide Ta3SeI7 hexagonal P63mc [1]
Ta4Se9I8 [1]
WCl6Se6I [2]
Hg3Se2I2 orthorhombic Imma a= 9.7660 b=19.381 c=9.6332 Z=8 light red [1][14]
trimercury arsenic tetraselenide iodide Hg3AsSe4I 1119.43 hexagonal P63mc a = 7.6902 c = 9.968 Z = 2 510.50 7.283 dark red [15]
Tl6SeI4 tetragonal P4/mnc 7.4 band-gap 1.6 eV; semiconductor; melt 432 °C [1][16]
Bismuth selenide iodide BiSeI 414.84 orthorhombic Pnma a = 8.697 b = 4.2205 c = 10.574 388.1 7.100 band gap 1.3 eV; silver [1][17]
Bi2CuSe3I [1]
In2Bi3Se7I [1]
InBi2Se4I [1]

References
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  2. Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides". Angewandte Chemie International Edition in English. 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833.
  3. Poltarak, Pavel A.; Komarov, Vladislav Yu.; Kozlova, Svetlana G.; Sukhikh, Aleksandr S.; Artemkina, Sofya B.; Fedorov, Vladimir E. (March 2019). "First titanium square fragment {Ti4(μ4-Se)(μ2-Se2)4} in its selenoiodide: Synthesis and structure of Ti4Se9I6". Inorganica Chimica Acta. 488: 285–291. doi:10.1016/j.ica.2019.01.037. S2CID 104458193.
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  10. Aldon, L.; Belin, R.; Pontillon, Y. (2001-01-01). "Refinement of the crystal structure of heptasilver(I) tetraseleniogermanate(IV) selenide iodide, Ag7GeISe5". Zeitschrift für Kristallographie - New Crystal Structures. 216 (1–4): 191–192. doi:10.1524/ncrs.2001.216.14.191. ISSN 2197-4578. S2CID 98367111.
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