Stemar-13-ene synthase
Stemar-13-ene synthase (EC 4.2.3.33, OsDTC2, OsK8, OsKL8, OsKS8, stemarene synthase, syn-stemar-13-ene synthase) is an enzyme with systematic name 9α-copalyl-diphosphate diphosphate-lyase (stemar-13-ene-forming).[1][2] This enzyme catalyses the following chemical reaction
- 9α-copalyl diphosphate stemar-13-ene + diphosphate
| Stemar-13-ene synthase | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC no. | 4.2.3.33 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
| |||||||||
This diterpene cyclase produces stemar-13-ene, a putative precursor of the rice phytoalexin oryzalexin S.
References
- Mohan RS, Yee NK, Coates RM, Ren YY, Stamenkovic P, Mendez I, West CA (June 1996). "Biosynthesis of cyclic diterpene hydrocarbons in rice cell suspensions: conversion of 9,10-syn-labda-8(17),13-dienyl diphosphate to 9beta-pimara-7,15-diene and stemar-13-ene". Archives of Biochemistry and Biophysics. 330 (1): 33–47. doi:10.1006/abbi.1996.0223. PMID 8651702.
- Nemoto T, Cho EM, Okada A, Okada K, Otomo K, Kanno Y, Toyomasu T, Mitsuhashi W, Sassa T, Minami E, Shibuya N, Nishiyama M, Nojiri H, Yamane H (July 2004). "Stemar-13-ene synthase, a diterpene cyclase involved in the biosynthesis of the phytoalexin oryzalexin S in rice". FEBS Letters. 571 (1–3): 182–6. doi:10.1016/j.febslet.2004.07.002. PMID 15280039.
External links
- Stemar-13-ene+synthase at the U.S. National Library of Medicine Medical Subject Headings (MeSH)
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