Trimethylolpropane triacrylate

Trimethylolpropane triacrylate (TMPTA) is a trifunctional acrylate ester monomer derived from trimethylolpropane, used in the manufacture of plastics, adhesives, acrylic glue, anaerobic sealants, and ink. It is useful for its low volatility and fast cure response. It has the properties of weather, chemical and water resistance, as well as good abrasion resistance. End products include alkyd coatings,[1] compact discs, hardwood floors, concrete and cementitious applications,[2][3][4] Dental composites, photolithography, letterpress, screen printing, elastomers, automobile headlamps, acrylics and plastic components for the medical industry.

Trimethylolpropane triacrylate
Names
Preferred IUPAC name
2-Ethyl-2-{[(prop-2-enoyl)oxy]methyl}propane-1,3-diyl di(prop-2-enoate)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.077
UNII
  • InChI=1S/C15H20O6/c1-5-12(16)19-9-15(8-4,10-20-13(17)6-2)11-21-14(18)7-3/h5-7H,1-3,8-11H2,4H3
    Key: DAKWPKUUDNSNPN-UHFFFAOYSA-N
  • InChI=1/C15H20O6/c1-5-12(16)19-9-15(8-4,10-20-13(17)6-2)11-21-14(18)7-3/h5-7H,1-3,8-11H2,4H3
    Key: DAKWPKUUDNSNPN-UHFFFAOYAU
  • CCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C
Properties
C15H20O6
Molar mass 296.319 g·mol−1
Density 1.06
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Other uses

As the molecule has acrylic functionality, it is capable of doing the Michael reaction with an amine. This allows its use in epoxy chemistry where its use speeds up the cure time considerably[5][6]

See also

References
  1. Wang, Qianhe (January 2019). "PhD Dissertation Acrylated Alkyds". University of Akron.
  2. Rengaraju, Sripriya; Al-Tabbaa, Abir (2023). "Life Cycle Assessment (LCA) of Microcapsule based self-healing in concrete". MATEC Web of Conferences. 378: 06004. doi:10.1051/matecconf/202337806004. ISSN 2261-236X.
  3. Lin, Xiuju; Liao, Bing; Zhang, Jingfei; Li, Simin; Huang, Jianheng; Pang, Hao (2019-06-20). "Synthesis and characterization of high-performance cross-linked polycarboxylate superplasticizers". Construction and Building Materials. 210: 162–171. doi:10.1016/j.conbuildmat.2019.03.185. ISSN 0950-0618.
  4. Ma, Yihan; Lei, Lei; Sha, Shengnan; Liu, Yi; Shi, Caijun (2023-06-01). "Synthesis of a cross-linked polycarboxylate ether superplasticizer and its effects on the properties of cement paste containing montmorillonite". Cement and Concrete Research. 168: 107136. doi:10.1016/j.cemconres.2023.107136. ISSN 0008-8846.
  5. "Epoxy Polyacrylate Resins". www.hexion.com. Retrieved 2020-02-12.
  6. "Low Viscosity, Fast Curing Epoxy Acrylate Oligomers". www.pcimag.com. Retrieved 2020-02-12.
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