Young–Laplace equation

If the pressure difference is zero, as in a soap film without gravity, the interface will assume the shape of a minimal surface.

The equation also explains the energy required to create an emulsion. To form the small, highly curved droplets of an emulsion, extra energy is required to overcome the large pressure that results from their small radius.

The Laplace pressure, which is greater for smaller droplets, causes the diffusion of molecules out of the smallest droplets in an emulsion and drives emulsion coarsening via Ostwald ripening.

Spherical meniscus with wetting angle less than 90°

In a sufficiently narrow (i.e., low Bond number) tube of circular cross-section (radius a), the interface between two fluids forms a meniscus that is a portion of the surface of a sphere with radius R. The pressure jump across this surface is related to the radius and the surface tension γ by

$${\displaystyle \Delta p={\frac {2\gamma }{R}}.}$$

This may be shown by writing the Young–Laplace equation in spherical form with a contact angle boundary condition and also a prescribed height boundary condition at, say, the bottom of the meniscus. The solution is a portion of a sphere, and the solution will exist only for the pressure difference shown above. This is significant because there isn't another equation or law to specify the pressure difference; existence of solution for one specific value of the pressure difference prescribes it.

The radius of the sphere will be a function only of the contact angle, θ, which in turn depends on the exact properties of the fluids and the container material with which the fluids in question are contacting/interfacing:

$${\displaystyle R={\frac {a}{\cos \theta }}}$$

so that the pressure difference may be written as:

$${\displaystyle \Delta p={\frac {2\gamma \cos \theta }{a}}.}$$

Illustration of capillary rise. Red=contact angle less than 90°; blue=contact angle greater than 90°

In order to maintain hydrostatic equilibrium, the induced capillary pressure is balanced by a change in height, h, which can be positive or negative, depending on whether the wetting angle is less than or greater than 90°. For a fluid of density ρ:

$${\displaystyle \rho gh={\frac {2\gamma \cos \theta }{a}}.}$$

where g is the gravitational acceleration. This is sometimes known as the Jurin's law or Jurin height[3] after James Jurin who studied the effect in 1718.[4]

For a water-filled glass tube in air at sea level:

• γ = 0.0728 J/m² at 20 °C
• θ = 20° (0.35 rad)
• ρ = 1000 kg/m³
• g = 9.8 m/s²

and so the height of the water column is given by:

$${\displaystyle h\approx {{1.4\times 10^{-5}}\mathrm {m} \over a}.}$$

Thus for a 2 mm wide (1 mm radius) tube, the water would rise 14 mm. However, for a capillary tube with radius 0.1 mm, the water would rise 14 cm (about 6 inches).

In the general case, for a free surface and where there is an applied "over-pressure", Δp, at the interface in equilibrium, there is a balance between the applied pressure, the hydrostatic pressure and the effects of surface tension. The Young–Laplace equation becomes:

$${\displaystyle \Delta p=\rho gh-\gamma \left({\frac {1}{R_{1}}}+{\frac {1}{R_{2}}}\right)}$$

The equation can be non-dimensionalised in terms of its characteristic length-scale, the capillary length:

$${\displaystyle L_{c}={\sqrt {\frac {\gamma }{\rho g}}},}$$

and characteristic pressure

$${\displaystyle p_{c}={\frac {\gamma }{L_{c}}}={\sqrt {\gamma \rho g}}.}$$

For clean water at standard temperature and pressure, the capillary length is ~2 mm.

The non-dimensional equation then becomes:

$${\displaystyle h^{*}-\Delta p^{*}=\left({\frac {1}{{R_{1}}^{*}}}+{\frac {1}{{R_{2}}^{*}}}\right).}$$

Thus, the surface shape is determined by only one parameter, the over pressure of the fluid, Δp^* and the scale of the surface is given by the capillary length. The solution of the equation requires an initial condition for position, and the gradient of the surface at the start point.

A pendant drop is produced for an over pressure of Δp^*=3 and initial condition r₀=10⁻⁴, z₀=0, dz/dr=0

A liquid bridge is produced for an over pressure of Δp^*=3.5 and initial condition r₀=0.25⁻⁴, z₀=0, dz/dr=0

Axisymmetric equations

The (nondimensional) shape, r(z) of an axisymmetric surface can be found by substituting general expressions for principal curvatures to give the hydrostatic Young–Laplace equations:[5]

$${\displaystyle {\frac {r''}{(1+r'^{2})^{{3}/{2}}}}-{\frac {1}{r(z){\sqrt {1+r'^{2}}}}}=z-\Delta p^{*}}$$

$${\displaystyle {\frac {z''}{(1+z'^{2})^{3/2}}}+{\frac {z'}{r(1+z'^{2})^{{1}/{2}}}}=\Delta p^{*}-z(r).}$$

In medicine it is often referred to as the Law of Laplace, used in the context of cardiovascular physiology,[6] and also respiratory physiology, though the latter use is often erroneous.[7]

Francis Hauksbee performed some of the earliest observations and experiments in 1709[8] and these were repeated in 1718 by James Jurin who observed that the height of fluid in a capillary column was a function only of the cross-sectional area at the surface, not of any other dimensions of the column.[4][9]

Thomas Young laid the foundations of the equation in his 1804 paper An Essay on the Cohesion of Fluids[10] where he set out in descriptive terms the principles governing contact between fluids (along with many other aspects of fluid behaviour). Pierre Simon Laplace followed this up in Mécanique Céleste[11] with the formal mathematical description given above, which reproduced in symbolic terms the relationship described earlier by Young.

Laplace accepted the idea propounded by Hauksbee in his book Physico-mechanical Experiments (1709), that the phenomenon was due to a force of attraction that was insensible at sensible distances.[12][13] The part which deals with the action of a solid on a liquid and the mutual action of two liquids was not worked out thoroughly, but ultimately was completed by Carl Friedrich Gauss.[14] Franz Ernst Neumann (1798-1895) later filled in a few details.[15][9][16]

• Maxwell, James Clerk; Strutt, John William (1911). "Capillary Action" . In Chisholm, Hugh (ed.). Encyclopædia Britannica. Vol. 5 (11th ed.). Cambridge University Press. pp. 256–275.
• Batchelor, G. K. (1967) An Introduction To Fluid Dynamics, Cambridge University Press
• Jurin, J. (1716). "An account of some experiments shown before the Royal Society; with an enquiry into the cause of the ascent and suspension of water in capillary tubes". Philosophical Transactions of the Royal Society. 30 (351–363): 739–747. doi:10.1098/rstl.1717.0026. S2CID 186211806.
• Tadros T. F. (1995) Surfactants in Agrochemicals, Surfactant Science series, vol.54, Dekker