electropositive
(adjective)
Tending to not attract electrons (repel) within a chemical bond.
Examples of electropositive in the following topics:
-
Binary Hydrides
- In such hydrides, hydrogen is bonded to a more electropositive element or group.
- Ionic, or saline, hydride is a hydrogen atom bound to an extremely electropositive metal, generally an alkali metal or an alkaline earth metal (for example, potassium hydride or KH).
-
Carbides
- Carbides are a class of compounds composed of carbon and an electropositive atom.
- Salt-like (saline) carbides are composed of the highly electropositive atoms, such as the alkali, alkali earth, and group-III metals, mixed with carbon.
-
Naming Molecular Compounds
- Generally, the more electropositive atom is written first, followed by the more electronegative atom with an appropriate suffix.
-
Periodic Trends in Metallic Properties
- In effect, the electropositive nature of the metallic atoms allows their valence electrons to exist as a mobile fluid.
-
Electronegativity and Oxidation Number
- The opposite of electronegativity is electropositivity, which is a measure of an element's ability to donate electrons.
- However, when hydrogen is bonded with a metal, its oxidation number reduces to -1 because the metal is a more electropositive, or less electronegative, element.
-
Properties of Hydrogen
- When participating in reactions, hydrogen can have a partial positive charge when reacting with more electronegative elements such as the halogens or oxygen, but it can have a partial negative charge when reacting with more electropositive elements such as the alkali metals.
-
Oxidation Numbers of Metals in Coordination Compounds
- Solution: The oxidation number of oxygen is assigned a charge of -2 when it reacts with a metal because the metal is more electropositive.
-
Variation of Physical Properties Across a Period
- A halide is a binary compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, or astatide compound.
-
Reactions of Simple Organometallic Compounds
- The electropositive nature of the metal atom or group is an important factor influencing the reactivity of these reagents.