exergonic
Chemistry
(adjective)
Describing a reaction that releases energy to its surroundings.
Biology
(adjective)
Describing a reaction that releases energy (heat) into its environment.
Examples of exergonic in the following topics:
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Activation Energy
- Activation energy must be considered when analyzing both endergonic and exergonic reactions.
- Exergonic reactions have a net release of energy, but they still require a small amount of energy input before they can proceed with their energy-releasing steps.
- Cells will at times couple an exergonic reaction $(\Delta G<0)$ with endergonic reactions $(\Delta G>0)$, allowing them to proceed.
- The free energy released from the exergonic reaction is absorbed by the endergonic reaction.
- Important macromolecules, such as proteins, DNA, and RNA, store considerable energy, and their breakdown is exergonic.
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Free Energy
- Reactions that have a negative ∆G and, consequently, release free energy, are called exergonic reactions.
- Exergonic means energy is exiting the system.
- Exergonic and endergonic reactions result in changes in Gibbs free energy.
- Exergonic reactions release energy; endergonic reactions require energy to proceed.
- Shown are some examples of endergonic processes (ones that require energy) and exergonic processes (ones that release energy).
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ATP: Adenosine Triphosphate
- Cells couple the exergonic reaction of ATP hydrolysis with endergonic reactions to harness the energy within the bonds of ATP.
- ATP provides the energy for both energy-consuming endergonic reactions and energy-releasing exergonic reactions, which require a small input of activation energy.
- Cells couple the exergonic reaction of ATP hydrolysis with the endergonic reactions of cellular processes.
- In this example, the exergonic reaction of ATP hydrolysis is coupled with the endergonic reaction of converting glucose for use in the metabolic pathway.
- Sodium-potassium pumps use the energy derived from exergonic ATP hydrolysis to pump sodium and potassium ions across the cell membrane.
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Spontaneous and Nonspontaneous Processes
- Endergonic reactions can also be pushed by coupling them to another reaction, which is strongly exergonic, through a shared intermediate.Saul Steinberg from The New Yorker illustrates a nonspontaneous process here.
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Citric Acid Cycle
- This step is irreversible because it is highly exergonic.
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The Second Law of Thermodynamics
- In an exergonic chemical reaction where energy is released, entropy increases because the final products have less energy inside them holding their chemical bonds together.
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ATP in Metabolism
- In this way, ATP is a direct link between the limited set of exergonic pathways of glucose catabolism and the multitude of endergonic pathways that power living cells.
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Solvent Effects
- These different entropy changes are incorporated in the free energy of solution, which is exergonic for NaCl, but endergonic for CaF2.