amphoteric
(adjective)
Having the characteristics of both an acid and a base, and capable of reacting as either; amphiprotic.
Examples of amphoteric in the following topics:
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The Solubility of Amphoteric Metal Hydroxides
- Amphoteric metal hydroxides behave as bases and acids, dissolving in excess alkali.
- The oxides and hydroxides of the metals in Group 3 and higher tend to be weakly basic and mostly display an amphoteric nature.
- An amphoteric substance is one that can act as either an acid or a base.
- An example of an amphoteric compound that is not amphiprotic is ZnO, which can act as an acid even though it has no protons to donate.
- An example of an amphoteric and amphiprotic substance is beryllium hydroxide (Be(OH)2):
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Basic and Amphoteric Hydroxides
- Some metal hydroxides are amphoteric, or capable of acting as either an acid or base.
- Now we will examine amphoteric hydroxides—that is, hydroxide salts that can act as either an acid or a base, depending on reaction conditions.
- One of the most common and familiar examples of an amphoteric hydroxide is aluminum hydroxide, Al(OH)3.
- Metal hydroxides with a highly-charged central metal atom can be amphoteric.
- In addition to aluminum, metals such as zinc, tin, lead, and beryllium can also form amphoteric oxides or hydroxides.
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Brønsted Acids and Bases
- Water is amphoteric, which means it can act as either an acid or a base.
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Acid-Base Properties of Water
- This is an example of autoprotolysis (meaning "self-protonating") and it exemplifies the amphoteric nature of water (ability to act as both an acid and a base).
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Oxides
- Oxides that react with both acids and bases are amphoteric.
- Metals tend to form basic oxides, non-metals tend to form acidic oxides, and amphoteric oxides are formed by elements near the boundary between metals and non-metals (metalloids).
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The Brønsted-Lowry Definition of Acids and Bases
- Note that water is amphoteric; depending on the circumstances, it can act as either an acid or a base, either donating or accepting a proton.
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Chromium
- Chromium(III) hydroxide (Cr(OH)3) is amphoteric, dissolving in acidic solutions to form [Cr(H2O)6]3+ and in basic solutions to form [Cr(OH)6]3−.
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Oxidation States of Nitrogen
- If one of the alkyl substituents consists of a long chain, such as C12H25, the resulting amine oxide is an amphoteric surfactant and finds use in shampoos and other mild cleaning agents.
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Synthesis of Amino Acids
- Since amino acids are amphoteric, resolution could also be achieved by using the basic character of the amine function.
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The Structure and Properties of Water
- Water can be described as an amphoteric molecule, meaning that it can react as both a Brønsted-Lowry acid or base.