paramagnetic
(adjective)
Exhibiting paramagnetism (the tendency of magnetic dipoles to align with an external magnetic field).
Examples of paramagnetic in the following topics:
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Diamagnetism and Paramagnetism
- Diamagnetic atoms have only paired electrons, whereas paramagnetic atoms, which can be made magnetic, have at least one unpaired electron.
- Electrons that are alone in an orbital are called paramagnetic electrons.
- Therefore, an atom is considered to be paramagnetic when it contains at least one paramagnetic electron.
- In other words, an atom could have 10 paired (diamagnetic) electrons, but as long as it also has one unpaired (paramagnetic) electron, it is still considered a paramagnetic atom.
- Paramagnetic properties are due to the realignment of the electron paths caused by the external magnetic field.
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Transition Metals
- The formation of many paramagnetic compounds due to the presence of unpaired d electrons.
- A few compounds of main group elements are also paramagnetic (e.g., nitric oxide, oxygen).
- Transition metal compounds are paramagnetic when they have one or more unpaired d electrons.
- Ferromagnetism occurs when individual atoms are paramagnetic and the spin vectors are aligned parallel to each other in a crystalline material.
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Physical Properties and Atomic Size
- These include the formation of compounds whose color is due to d–d electronic transitions and the formation of many paramagnetic compounds due to the presence of unpaired d electrons.
- Transition metal compounds are paramagnetic when they have one or more unpaired d electrons.
- Ferromagnetism occurs when individual atoms are paramagnetic and the spin vectors are aligned parallel to each other in a crystalline material.
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Detection and Observation of Radicals
- The same unpaired or odd electron that renders most radical intermediates unstable and highly reactive may be induced to leave a characteristic "calling card" by a magnetic resonance phenomenon called "electron spin resonance" (esr) or "electron paramagnetic resonance" (epr).
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Electron Configurations and Magnetic Properties of Ions
- Some are attracted to a magnetic field (paramagnetism); others are repulsed by it (diamagnetism); still others have a much more complex relationship with an applied magnetic field (e.g., spin-glass behavior and antiferromagnetism).
- If the ionization of an element yields an ion with unpaired electrons, these electrons may align the sign of their spins in the presence of a magnetic field, making the material paramagnetic.
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The Third Law of Thermodynamics and Absolute Energy
- Materials that remain paramagnetic at absolute zero, by contrast, may have many nearly-degenerate ground states, as in a spin glass, or may retain dynamic disorder, as is the case in a spin liquid.
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Manganese
- Manganese metal and its common ions are paramagnetic.
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Lanthanides and Actinides
- All actinides are radioactive, paramagnetic, and, with the exception of actinium, have several crystalline phases.
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Chromium
- Above 38 °C, it transforms into a paramagnetic state.
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Properties of Oxygen
- In normal triplet form, O2 molecules are paramagnetic.