Energy operator

It is given by:[1]

$${\displaystyle {\hat {E}}=i\hbar {\frac {\partial }{\partial t}}}$$

It acts on the wave function (the probability amplitude for different configurations of the system)

$${\displaystyle \Psi \left(\mathbf {r} ,t\right)}$$

The energy operator corresponds to the full energy of a system. The Schrödinger equation describes the space- and time-dependence of the slow changing (non-relativistic) wave function of a quantum system. The solution of this equation for a bound system is discrete (a set of permitted states, each characterized by an energy level) which results in the concept of quanta.

Schrödinger equation

Using the energy operator to the Schrödinger equation:

$${\displaystyle i\hbar {\frac {\partial }{\partial t}}\Psi (\mathbf {r} ,\,t)={\hat {H}}\Psi (\mathbf {r} ,t)}$$

can be obtained:

$${\displaystyle {\hat {E}}\Psi (\mathbf {r} ,t)={\hat {H}}\Psi (\mathbf {r} ,t)}$$

where i is the imaginary unit, ħ is the reduced Planck constant, and ${\displaystyle {\hat {H}}}$ is the Hamiltonian operator.

Constant energy

Working from the definition, a partial solution for a wavefunction of a particle with a constant energy can be constructed. If the wavefunction is assumed to be separable, then the time dependence can be stated as ${\displaystyle e^{-iEt/\hbar }}$, where E is the constant energy. In full,[2]

$${\displaystyle \Psi (\mathbf {r} ,t)=\psi (\mathbf {r} )e^{-iEt/\hbar }}$$

where ${\displaystyle \psi (\mathbf {r} )}$ is the partial solution of the wavefunction dependent on position. Applying the energy operator, we have

$${\displaystyle {\hat {E}}\Psi (\mathbf {r} ,t)=i\hbar {\frac {\partial }{\partial t}}\psi (\mathbf {r} )e^{-iEt/\hbar }=i\hbar \left({\frac {-iE}{\hbar }}\right)\psi (\mathbf {r} )e^{-iEt/\hbar }=E\psi (\mathbf {r} )e^{-iEt/\hbar }=E\Psi (\mathbf {r} ,t).}$$

This is also known as the stationary state, and can be used to analyse the time-independent Schrödinger equation:

$${\displaystyle E\Psi (\mathbf {r} ,t)={\hat {H}}\Psi (\mathbf {r} ,t)}$$

where E is an eigenvalue of energy.

Klein–Gordon equation

The relativistic mass-energy relation:

$${\displaystyle E^{2}=(pc)^{2}+(mc^{2})^{2}}$$

where again E = total energy, p = total 3-momentum of the particle, m = invariant mass, and c = speed of light, can similarly yield the Klein–Gordon equation:

$${\displaystyle {\begin{aligned}&{\hat {E}}^{2}=c^{2}{\hat {p}}^{2}+(mc^{2})^{2}\\&{\hat {E}}^{2}\Psi =c^{2}{\hat {p}}^{2}\Psi +(mc^{2})^{2}\Psi \\\end{aligned}}}$$

where ${\displaystyle {\hat {p}}}$ is the momentum operator. That is:

$${\displaystyle {\frac {\partial ^{2}\Psi }{\partial t^{2}}}=c^{2}\nabla ^{2}\Psi -\left({\frac {mc^{2}}{\hbar }}\right)^{2}\Psi }$$

The energy operator is easily derived from using the free particle wave function (plane wave solution to Schrödinger's equation).[3] Starting in one dimension the wave function is

$${\displaystyle \Psi =e^{i(kx-\omega t)}}$$

The time derivative of Ψ is

$${\displaystyle {\frac {\partial \Psi }{\partial t}}=-i\omega e^{i(kx-\omega t)}=-i\omega \Psi .}$$

By the De Broglie relation:

$${\displaystyle E=\hbar \omega ,}$$

we have

$${\displaystyle {\frac {\partial \Psi }{\partial t}}=-i{\frac {E}{\hbar }}\Psi .}$$

Re-arranging the equation leads to

$${\displaystyle E\Psi =i\hbar {\frac {\partial \Psi }{\partial t}},}$$

where the energy factor E is a scalar value, the energy the particle has and the value that is measured. The partial derivative is a linear operator so this expression is the operator for energy:

$${\displaystyle {\hat {E}}=i\hbar {\frac {\partial }{\partial t}}.}$$

It can be concluded that the scalar E is the eigenvalue of the operator, while ${\displaystyle {\hat {E}}}$ is the operator. Summarizing these results:

$${\displaystyle {\hat {E}}\Psi =i\hbar {\frac {\partial }{\partial t}}\Psi =E\Psi }$$

For a 3-d plane wave

$${\displaystyle \Psi =e^{i(\mathbf {k} \cdot \mathbf {r} -\omega t)}}$$

the derivation is exactly identical, as no change is made to the term including time and therefore the time derivative. Since the operator is linear, they are valid for any linear combination of plane waves, and so they can act on any wave function without affecting the properties of the wave function or operators. Hence this must be true for any wave function. It turns out to work even in relativistic quantum mechanics, such as the Klein–Gordon equation above.

• Time translation symmetry
• Planck constant
• Schrödinger equation
• Momentum operator
• Hamiltonian (quantum mechanics)
• Conservation of energy
• Complex number
• Stationary state