Lutetium phosphide

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP.[3][4] The compound forms dark crystals, does not dissolve in water.

Lutetium phosphide
Names
Other names
Phosphanylidynelutetium
Identifiers
3D model (JSmol)
ECHA InfoCard 100.031.588
EC Number
  • InChI=1S/Lu.P
    Key: PQFNNANPDJBCCR-UHFFFAOYSA-N
  • [Lu+3].[P-3]
Properties
LuP
Molar mass 205.94[2]
Appearance Dark crystals
Density 8,1
Insoluble
Structure
cubic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Synthesis

Heating powdered lutetium and red phosphorus in an inert atmosphere or vacuum:

It can also be formed in the reaction of lutetium and phosphine.

Physical properties

Lutetium phosphide forms dark cubic crystals, space group Fm3m, cell parameters a = 0.5533 nm, Z = 4.[5]

Stable in air, does not dissolve in water and reacts actively with nitric acid.

Uses

The compound is a semiconductor used in high power, high-frequency applications, and in laser diodes.[6]

Also used in gamma radiation detectors due to its ability to absorb radiation.

References
  1. EINECS: European Inventory of Existing Commercial Chemical Substances. Office for Official Publications of the European Communities. 1987. p. 591. ISBN 978-92-825-7507-9. Retrieved 12 December 2021.
  2. "Landolt-Börnstein Substance / Property Index". lb.chemie.uni-hamburg.de. Retrieved 12 December 2021.
  3. Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Cumulative Supplement to the Initial Inventory: User Guide and Indices. United States Environmental Protection Agency. Office of Toxic Substances. 1980. p. 176. Retrieved 12 December 2021.
  4. "Lutetium Phosphide". American Elements. Retrieved 12 December 2021.
  5. Singh, Sanjay Kumar (2019). High Pressure Properties of Lutetium Monopnictides (LuX, X = N, P, As) Theoretical Study at High Pressure : Phase Transition, Electronic and Thermal Properties of LuN, LuP and LuAs Compounds (1. Auflage ed.). Saarbrücken: Scholar's Press. ISBN 9786138913924. Archived from the original on 12 December 2021. Retrieved 12 December 2021.
  6. "CAS 12032-05-2 Lutetium Phosphide - Alfa Chemistry". alfa-chemistry.com. Retrieved 12 December 2021.
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