Paul Flory

Paul John Flory (June 19, 1910 – September 9, 1985) was an American chemist and Nobel laureate who was known for his work in the field of polymers, or macromolecules.[2] He was a leading pioneer in understanding the behavior of polymers in solution, and won the Nobel Prize in Chemistry in 1974 "for his fundamental achievements, both theoretical and experimental, in the physical chemistry of macromolecules".[3]

Paul Flory
Flory in 1973
Born
Paul John Flory

(1910-06-19)June 19, 1910
Sterling, Illinois, U.S.
DiedSeptember 9, 1985(1985-09-09) (aged 75)
Big Sur, California, U.S.
NationalityAmerica
Alma materManchester University (Indiana) and Ohio State University
Known forPolymer chemistry
Polymer physics
Flory convention
Flory–Fox equation
Flory–Huggins solution theory
Flory–Rehner equation
Flory–Schulz distribution
Flory–Stockmayer theory
Random sequential adsorption
Star-shaped polymer
Self-avoiding walk
AwardsNobel Prize for Chemistry (1974)
National Medal of Science (1974)
Priestley Medal (1974)
Perkin Medal (1977)[1]
Elliott Cresson Medal (1971)
Peter Debye Award (1969)
Charles Goodyear Medal (1968)
William H. Nichols Medal (1962)
Colwyn medal (1954)
Scientific career
FieldsPhysical chemistry of polymers
InstitutionsDuPont, Stanford University, Carnegie Mellon University, Cornell University
Doctoral advisorHerrick L. Johnston

Biography

Personal life

Flory was born in Sterling, Illinois, on June 19, 1910. He was raised by Ezra Flory and Nee Martha Brumbaugh. His father worked as a clergyman-educator, and his mother was a school teacher. He first gained his interest in science from Carl W Holl, who was a professor in chemistry. Holl was employed in Indiana at Manchester College as a chemistry professor. In 1936, he married Emily Catherine Tabor. He and Emily had three children together: Susan Springer, Melinda Groom and Paul John Flory, Jr. They also had five grandchildren. All of his children pursued careers in the field of science. His first position was at DuPont with Wallace Carothers.[4][5] He was posthumously inducted into the Alpha Chi Sigma Hall of Fame in 2002.[6] Flory died on September 9, 1985, due to a massive heart attack. His wife Emily died in 2006 aged 94.

Schooling

After graduating from Elgin High School in Elgin, Illinois in 1927, Flory received a bachelor's degree from Manchester College (Indiana) (now Manchester University) in 1931 and a Ph.D. from the Ohio State University in 1934. He completed a master's degree in organic chemistry under the supervision of Prof. Cecil E Boord.[7] Flory then pursued his doctorate thesis in physical chemistry studying the photochemistry of nitric oxide, supervised by Prof. Herrick L. Johnston.[8]

Work

In 1934, after receiving his Ph.D., he joined the Central Department of Dupont and Company working with Wallace H. Carothers.[9] After the death of Carothers in 1937, Flory was involved for two years at the Basic Research Laboratory located in the University of Cincinnati. During World War II, there was a need for research to develop synthetic rubber, so Flory joined the Esso Laboratories of the Standard Oil Development Company.[10] During 1943 to 1948 was the Research Laboratory of the Goodyear Tire and Rubber Company. In fact, he was the director of research at the Goodyear Tire and Rubber Company, leading the team for studies on polymers.

After working in the industry, Flory left to work at Cornell University for a lectureship. The lectureship was with the George Fisher Baker Non-Residents. During the lectureship, Flory was able to study and understand a way to treat the effect of the excluded volume. According the nobelprize.org polymers, "would be nonasymptotic with the length of the chain, that is the fear of the contribution by the exclusion of the segment of the chain from the space occupied would increase without a limit as the chain is lengthened. This was the volume on the configuration of polymer chains. In 1957, Flory and his family decided to make the move to Pittsburgh, Pennsylvania. The reason he and his family moved from New York to Pennsylvania was for him to be able to develop a program of basic research in chemistry at the Carnegie Mellon Institute. After his work at the Carnegie Mellon Institute, he accepted a professorship position at Stanford University in the department of chemistry. While he was at Stanford University, he changed his direction of research. The change of view in his studies has to do with the spatial configuration having to do with chain molecules. This have to do with configuration treatments having to do with chain molecules. The treatment is the dependent properties through mathematical methods. Not only is mathematical methods the only treatment but so is the thermodynamics of solutions. After his retirement he Flory remained still very active in the world of chemistry. He was a consultant for Dupont and IBM, not long after he retired. Flory also was involved with the study of the foundations in the Soviet Union started off by the professor MV Volkenstein and his collaborators. He also worked with the late professor of Kazuo Nagai in Japan. He felt the need to fight for scientists who were oppressed in various countries. In addition, he also spoke as the "Voice of America", during a broadcast in Eastern Europe as well as Soviet Union. Flory also worked for the "Committee on Human Rights" which is known as the National Academy of Sciences from 1979 to 1984. During 1980, he worked as a delegate at the scientific forum in Hamburg.

Research

After receiving his doctorate in 1934, he dealt with a variety of issues with physical chemistry. This having to do with the kinetics and mechanisms of polymeric substances. Having to do with the distribution of molar mass, solution of thermodynamics and hydrodynamics. In addition, during 1934, he also was able to discover that when polymeric chains will keep growing if they are mixed with other molecules when present. Flory also discovered the understanding of the term 'theta.' In other words, is the constant of hydrodynamic. With the theta point that is the neutral volumes interactions. In conclusion to the development of the theta point it has been confirmed and studied in a variety of laboratories by many scientists. Both natural and synthetic polymers have been studied throughout the theta point. Throughout this a better understanding of macromolecules was provided. It helped with the creation of basis under rational interpretations of physical measurements. The measurements have relations to both the solutions of polymers and quantitative characteristics. Some work completed by Paul Flory during his time includes the development in the quantitative correlations between the chain molecules and chemical structure of properties. This has to do with the way polymers are composed and what are composed of polymers. One piece of material formed through polymers is plastic. In the mid-1930s, Flory discovered how polymers are dissolved in a solvent. Leading to becoming outstretches which is caused by the forces of both polymers and solvent parts. He even had part finding a solution to polymers.

Career and polymer science

Flory's earliest work in polymer science was in the area of polymerization kinetics at the DuPont Experimental Station. In condensation polymerization, he challenged the assumption that the reactivity of the end group decreased as the macromolecule grew, and by arguing that the reactivity was independent of the size, he was able to derive the result that the number of chains present decreased with size exponentially. In addition polymerization, he introduced the important concept of chain transfer to improve the kinetic equations and remove difficulties in understanding the polymer size distribution.

In 1938, after Carothers' death, Flory moved to the Basic Science Research Laboratory at the University of Cincinnati. There he developed a mathematical theory for the polymerization of compounds with more than two functional groups and the theory of polymer networks or gels. This led to the Flory-Stockmayer theory of gelation, which equivalent to percolation on the Bethe lattice and in fact represents the first paper in the percolation field.

In 1940 he joined the Linden, NJ laboratory of the Standard Oil Development Company where he developed a statistical mechanical theory for polymer mixtures. In 1943 he left to join the research laboratories of Goodyear as head of a group on polymer fundamentals. In the Spring of 1948 Peter Debye, then chairman of the chemistry department at Cornell University, invited Flory to give the annual Baker Lectures. He then was offered a position with the faculty in the Fall of the same year. He was initiated into the Tau chapter of Alpha Chi Sigma at Cornell in 1949.[6] At Cornell he elaborated and refined his Baker Lectures into his magnum opus, Principles of Polymer Chemistry which was published in 1953 by Cornell University Press. This quickly became a standard text for all workers in the field of polymers, and is still widely used to this day.

Flory introduced the concept of excluded volume, coined by Werner Kuhn in 1934, to polymers. Excluded volume refers to the idea that one part of a long chain molecule can not occupy space that is already occupied by another part of the same molecule. Excluded volume causes the ends of a polymer chain in a solution to be further apart (on average) than they would be were there no excluded volume. The recognition that excluded volume was an important factor in analyzing long-chain molecules in solutions provided an important conceptual breakthrough, and led to the explanation of several puzzling experimental results of the day. It also led to the concept of the theta point, the set of conditions at which an experiment can be conducted that causes the excluded volume effect to be neutralized. At the theta point, the chain reverts to ideal chain characteristics – the long-range interactions arising from excluded volume are eliminated, allowing the experimenter to more easily measure short-range features such as structural geometry, bond rotation potentials, and steric interactions between near-neighboring groups. Flory correctly identified that the chain dimension in polymer melts would have the size computed for a chain in ideal solution if excluded volume interactions were neutralized by experimenting at the theta point.

Among his accomplishments are an original method for computing the probable size of a polymer in good solution, the Flory-Huggins Solution Theory, and the derivation of the Flory exponent, which helps characterize the movement of polymers in solution.

The Flory convention
see Flory convention for details.

In modeling the position vectors of atoms in macromolecules it is often necessary to convert from Cartesian coordinates (x,y,z) to generalized coordinates. The Flory convention for defining the variables involved is usually employed. For an example, a peptide bond can be described by the x,y,z positions of every atom in this bond or the Flory convention can be used. Here one must know the bond lengths , bond angles , and the dihedral angles . Applying a vector conversion from the Cartesian coordinates to the generalized coordinates will describe the same three-dimensional structure using the Flory convention.

Awards and honors

Flory was elected to the United States National Academy of Sciences in 1953 and the American Academy of Arts and Sciences in 1957.[11][12] In 1968, he received the Charles Goodyear Medal. He also received the Priestley Medal and the Golden Plate Award of the American Academy of Achievement[13] in 1974. He received the Carl-Dietrich-Harries-Medal for commendable scientific achievements in 1977.[14] Flory received the Nobel Prize in Chemistry in 1974 "for his fundamental achievements both theoretical and experimental, in the physical chemistry of the macromolecules."[15] Additionally in 1974 Flory was awarded the National Medal of Science in Physical Sciences. The medal was presented to him by President Gerald Ford. This award was given to him because of his research on the "formation and structure of polymeric substances".[16]

Published books

With over 300 writings, both published and unpublished, throughout his lectureship at the university with the research and teaching led to his first published book. The book published by Cornell University was called the "Principles of Polymer Chemistry." The book was then the basis use of information for undergrad students. It was the standard principle for many decades, used by many professors. Another book which was published by Flory was "Statistical Mechanics of Chain Molecules." The book was published in 1969, worked to summarize different parts both molecules theories and applications. In 1985, the book written by Paul Flory called, "Selected Works of Paul Flory." This summarized much of his work and studies.

Bibliography
  • Flory, Paul. (1953) Principles of Polymer Chemistry. Cornell University Press. ISBN 0-8014-0134-8.
  • Flory, Paul. (1969) Statistical Mechanics of Chain Molecules. Interscience. ISBN 0-470-26495-0. Reissued 1989. ISBN 1-56990-019-1.
  • Flory, Paul. (1985) Selected Works of Paul J. Flory. Stanford Univ Press. ISBN 0-8047-1277-8.

References
  1. "SCI Perkin Medal". Science History Institute. May 31, 2016. Retrieved March 24, 2018.
  2. Pecora, Robert (November 1986). "Obituary: Paul John Flory". Physics Today. 39 (11): 116–117. Bibcode:1986PhT....39k.116P. doi:10.1063/1.2815221.
  3. "The Nobel Prize in Chemistry 1974". NobelPrize.org. Retrieved July 11, 2023.
  4. Mangravite, Andrew (2001). "Finding Aid to the Paul J. Flory papers, 1931–1985 bulk 1950–1978". Science History Institute. Retrieved March 27, 2018. Click on 'Paul J. Flory papers finding aid' for full finding aid.
  5. Morris, Peter J. T. (1986) Polymer Pioneers: A Popular History of the Science and Technology of Large Molecules Center for History of Chemistry, Philadelphia. pp. 70–73. ISBN 0941901033
  6. Fraternity – Awards – Hall of Fame. Alpha Chi Sigma (May 23, 2018). Retrieved on 2018-07-17.
  7. "Paul John Flory: A Biographical Memoir" (PDF).
  8. "Paul J. Flory | Nobel Prize-Winning American Chemist | Britannica". www.britannica.com. June 15, 2023. Retrieved July 11, 2023.
  9. "Paul J. Flory | Nobel Prize-Winning American Chemist | Britannica". www.britannica.com. June 15, 2023. Retrieved July 11, 2023.
  10. "Paul John Flory: A Biographical Memoir" (PDF).
  11. "Paul J. Flory". www.nasonline.org. Retrieved August 15, 2022.
  12. "Paul John Flory". American Academy of Arts & Sciences. Retrieved August 15, 2022.
  13. "Golden Plate Awardees of the American Academy of Achievement". www.achievement.org. American Academy of Achievement.
  14. "Carl-Dietrich-Harries-Medal for commendable scientific achievements". dkg-rubber.de. DKG. Retrieved July 2, 2022.
  15. "The Nobel Prize in Chemistry 1974". The Nobel Prize. Nobel media. Retrieved July 24, 2019.
  16. "The President's National Medal of Science: Recipient Details". National Medal of Science. National Science Foundation. Retrieved July 24, 2019.
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