Platinum(IV) bromide

Platinum(IV) bromide is the inorganic compound with the formula PtBr4. It is a brown solid. It is a little-used compound mainly of interest for academic research.[2] It is a component of a reagent used in qualitative inorganic analysis.[3]

Platinum(IV) bromide
Names
IUPAC name
Platinum(IV) bromide
Other names
Platinic bromide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.066.481
EC Number
  • 273-151-5
  • InChI=1S/4BrH.Pt/h4*1H;/q;;;;+4/p-4
    Key: SNPHNDVOPWUNON-UHFFFAOYSA-J
  • Br[Pt](Br)(Br)Br
Properties
PtBr4
Molar mass 514.694 g/mol
Appearance brownish-black crystals
Melting point decomposes at 180°C
0.41 g/100mL @ 20°C
Solubility slightly soluble in ethanol, diethyl ether[1]
Hazards
GHS labelling:
GHS05: Corrosive
Danger
H314
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond
2
0
1
Flash point non-flammable
Safety data sheet (SDS)
Related compounds
Other anions
 Platinum(IV) fluoride
Platinum(IV) chloride
Platinum(IV) iodide
Other cations
 Nickel(II) bromide
Palladium(II) bromide
Related compounds
 Platinum(II) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

In terms of structure, the compound is an inorganic polymer consisting of interconnected PtBr6 octahedra.

References
  1. Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, p. 481, ISBN 0-8493-0594-2, retrieved 2008-06-19
  2. Lagrow, Alec P.; Knudsen, Kristian Rahbek; Alyami, Noktan M.; Anjum, Dalaver H.; Bakr, Osman M. (2015). "Effect of Precursor Ligands and Oxidation State in the Synthesis of Bimetallic Nano-Alloys". Chemistry of Materials. 27 (11): 4134–4141. doi:10.1021/acs.chemmater.5b01247. hdl:10754/553018.
  3. Wenger, P. E. (2007), Reagents for Qualitative Inorganic Analysis, Read Country Books, p. 242, ISBN 978-1-4067-4847-5, retrieved 2008-06-18


This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.