Tritium radioluminescence

Tritium radioluminescence is the use of gaseous tritium, a radioactive isotope of hydrogen, to create visible light. Tritium emits electrons through beta decay and, when they interact with a phosphor material, light is emitted through the process of phosphorescence. The overall process of using a radioactive material to excite a phosphor and ultimately generate light is called radioluminescence. As tritium illumination requires no electrical energy, it has found wide use in applications such as emergency exit signs, illumination of wristwatches, and portable yet very reliable sources of low intensity light which won't degrade human night vision. Gun sights for night use and small lights (which need to be more reliable than battery powered lights, yet not interfere with night vision or be bright enough to easily give away one's location) used mostly by military personnel fall under the latter application.

Radioluminescent 1.8-curie (67 GBq) 6-by-0.2-inch (152.4 mm × 5.1 mm) tritium vials are tritium gas-filled, thin glass vials with inner surfaces coated with a phosphor.

History

Tritium was found to be an ideal energy source for self-luminous compounds in 1953 and the idea was patented by Edward Shapiro on 29 October 1953, in the US (2749251 – Source of Luminosity).[1]

Design
Radioluminescent keychains

Tritium lighting is made using glass tubes with a phosphor layer in them and tritium gas inside the tube. Such a tube is known as a "gaseous tritium light source" (GTLS), or beta light (since the tritium undergoes beta decay), or tritium lamp.

The tritium in a gaseous tritium light source undergoes beta decay, releasing electrons that cause the phosphor layer to phosphoresce.[2]

During manufacture, a length of borosilicate glass tube that has had the internal surface coated with a phosphor-containing material is filled with radioactive tritium. The tube is then sealed at the desired length using a carbon dioxide laser. Borosilicate is preferred for its strength and resistance to breakage. In the tube, the tritium gives off a steady stream of electrons due to beta decay. These particles excite the phosphor, causing it to emit a low, steady glow.

Tritium is not the only material that can be used for self-powered lighting. Radium was used to make self-luminous paint from the early years of the 20th century until approximately 1970. Promethium briefly replaced radium as a radiation source. Tritium is the only radiation source used in radioluminescent light sources today due to its low radiological toxicity and commercial availability.[3]

Various preparations of the phosphor compound can be used to produce different colors of light. For example, doping zinc sulfide phosphor with different metals can change the emission wavelength.[4] Some of the colors that have been manufactured in addition to the common phosphors are green, red, blue, yellow, purple, orange, and white.

The GTLSs used in watches give off a small amount of light: Not enough to be seen in daylight, but visible in the dark from a distance of several meters. The average such GTLS has a useful life of 10–20 years. Being an unstable isotope with a half-life of 12.32 years, the rate of beta emissions decreases by half in that period. Additionally, phosphor degradation will cause the brightness of a tritium tube to drop by more than half in that period. The more tritium that is initially placed in the tube, the brighter it is to begin with, and the longer its useful life. Tritium exit signs usually come in three brightness levels guaranteed for 10, 15, or 20 year useful life expectancies.[5] The difference between the signs is how much tritium the manufacturer installs.

The light produced by GTLSs varies in color and size. Green usually appears as the brightest color with a brightness as high as 2 cd/m2[6] and red appears the least bright. For comparison, most consumer desktop liquid crystal displays have luminances of 200 to 300 cd/m2.[7] Sizes range from tiny tubes small enough to fit on the hand of a watch to ones the size of a pencil. Large tubes (5 mm diameter and up to 100 mm long) are usually only found in green, and can surprisingly be not as bright as the standard 22.5 mm × 3 mm sized tritium, this is due to the lower concentration and high cost of tritium; this smaller size is usually the brightest and is used mainly in keychains available commercially.

Uses
A "permanent" illumination watch dial
Tritium-illuminated handgun night sights on an FN Five-seven

These light sources are most often seen as "permanent" illumination for the hands of wristwatches intended for diving, nighttime, or combat use. They are also used in glowing novelty keychains and in self-illuminated exit signs. They are favored by the military for applications where a power source may not be available, such as for instrument dials in aircraft, compasses, and sights for weapons. In the case of solid tritium light sources, the tritium replaces some of the hydrogen atoms in the paint, which also contains a phosphor such as zinc sulfide.

Tritium lights or beta lights were formerly used in fishing lures. Some flashlights have slots for tritium vials so that the flashlight can be easily located in the dark.

Tritium is used to illuminate the iron sights of some small arms. The reticle on the SA80's optical SUSAT sight as well as the LPS 4x6° TIP2 telescopic sight of a PSL rifle, contains a small amount of tritium for the same effect as an example of tritium use on a rifle sight. The electrons emitted by the radioactive decay of the tritium cause phosphor to glow, thus providing a long-lasting (several years) and non-battery-powered firearms sight that is visible in dim lighting conditions. The tritium glow is not noticeable in bright conditions such as during daylight, however; consequently some manufacturers have started to integrate fiber optic sights with tritium vials to provide bright, high-contrast firearms sights in both bright and dim conditions.

Safety
A self-luminous exit sign that contains tubes of tritium

While these devices contain a radioactive substance, it is currently believed that self-powered lighting does not pose a significant health concern. A 2007 report by the UK government's Health Protection Agency Advisory Group on Ionizing Radiation declared the health risks of tritium exposure to be double that previously set by the International Commission on Radiological Protection,[8] but encapsulated tritium lighting devices, typically taking the form of a luminous glass tube embedded in a thick block of clear plastic, prevent the user from being exposed to the tritium at all unless the device is broken apart.

Tritium presents no external beta radiation threat when encapsulated in non-hydrogen-permeable containers due to its low penetration depth, which is insufficient to penetrate intact human skin. However, GTLS devices do emit low levels of X-rays due to bremsstrahlung.[9] According to a report by the Organisation for Economic Co-operation and Development,[10] any external radiation from a gaseous tritium light device is solely due to bremsstrahlung, usually in the range of 8–14 keV. The bremsstrahlung dose rate can not be calculated from the properties of tritium alone, as the dose rate and effective energy is dependent on the form of containment. A bare, cylindrical vial GTLS constructed of 0.1 mm thick glass that is 10 mm long and 0.5 mm in diameter will yield a surface dose rate of 100 millirads per hour per curie. If the same vial were instead constructed of 1 mm thick glass and enclosed in a plastic covering that is 2–3 mm thick, the GTLS will yield a surface dose rate of 1 millirad per hour per curie. The dose rate measured from 10 mm away will be two orders of magnitude lower than the measured surface dose rate. Given that the half-value thickness of 10 keV photon radiation in water is about 1.4 mm, the attenuation provided by tissue overlaying blood-forming organs is considerable.

The primary danger from tritium arises if it is inhaled, ingested, injected, or absorbed into the body. This results in the absorption of the emitted radiation in a relatively small region of the body, again due to the low penetration depth. The biological half-life of tritium – the time it takes for half of an ingested dose to be expelled from the body – is low, at only 12 days. Tritium excretion can be accelerated further by increasing water intake to 3–4 liters/day.[11] Direct, short-term exposure to small amounts of tritium is mostly harmless. If a tritium tube breaks, one should leave the area and allow the gas to diffuse into the air. Note that it is lighter than air and will float upwards like helium. Tritium exists naturally in the environment, but in very small quantities.

Legislation

Because tritium is used in boosted fission weapons and thermonuclear weapons (though in quantities several thousand times larger than that in a keychain), consumer and safety devices containing tritium for use in the United States are subject to certain possession, resale, disposal, and use restrictions. In the US, devices such as self-luminous exit signs, gauges, wristwatches, etc. that contain small amounts of tritium are under the jurisdiction of the Nuclear Regulatory Commission, and are subject to possession, distribution, and import and export regulations found in 10 CFR Parts, 30, 32, and 110. They are also subject to regulations for possession, use, and disposal in certain states. Luminous products containing more tritium than needed for a wristwatch are not widely available at retail outlets in the United States.

They are readily sold and used in the UK and US. They are regulated in England and Wales by environmental health departments of local councils. In Australia products containing tritium are licence exempt if they contain less than 1×106 becquerels per gram (2.7×10−5 Ci/g) tritium and have a total activity of less than 1×109 becquerels (0.027 Ci), except for in safety devices where the limit is 74×109 becquerels (2.0 Ci) total activity.[12]

See also

References
  1. Pereztroika, Jose (2019-11-30). "Luminor 2020: Debunking Panerai's fictional history of tritium-based lume". perezcope.com (blog).
  2. Jüstel, Thomas; Möller, Stephanie; Winkler, Holger; Adam, Waldemar (2012-04-15), "Luminescent Materials", in Wiley-VCH Verlag GmbH & Co. KGaA (ed.), Ullmann's Encyclopedia of Industrial Chemistry, Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, pp. a15_519.pub2, doi:10.1002/14356007.a15_519.pub2, ISBN 978-3-527-30673-2, retrieved 2022-02-26
  3. Zelenina, E. V.; Sychov, M. M.; Kostylev, A. I.; Ogurtsov, K. A. (2019-01-01). "Prospects for the Development of Tritium-Based Solid-State Radioluminescent Light Sources". Radiochemistry. 61 (1): 55–57. doi:10.1134/S1066362219010089. ISSN 1608-3288. S2CID 146018578.
  4. Fonda, Gorton R. (1946-07-01). "Preparation and Characteristics of Zinc Sulfide Phosphors Sensitive to Infra-Red*". JOSA. 36 (7): 382–389. doi:10.1364/JOSA.36.000382. PMID 20991937.
  5. "Self-illuminated signs" (PDF). U.S. Fire Administration. Techtalk. Vol. 1, no. 1. Federal Emergency Management Agency (FEMA). July 2009. Retrieved 2020-12-13.
  6. Zelenina, E. V.; Sychov, M. M.; Kostylev, A. I.; Ogurtsov, K. A. (2019-01-01). "Prospects for the Development of Tritium-Based Solid-State Radioluminescent Light Sources". Radiochemistry. 61 (1): 55–57. doi:10.1134/S1066362219010089. ISSN 1608-3288. S2CID 146018578.
  7. Hung, Jonathan (May 3, 2010). "Acer Ferrari One 200 Review – More than a Netbook". PC Perspective. Retrieved 2018-01-21.
  8. "Advice on risks from tritium" (Press release). HPA Press Statement. United Kingdom: Health Protection Agency. 29 November 2007. Archived from the original on 2 December 2007. Retrieved 5 February 2011.
  9. "Gaseous tritium light sources (GTLSs) and gaseous tritium light devices (GTLDs)" (PDF). Radiation Safety Handbook. Ministry of Defence (United Kingdom). May 2009. JSP 392.
  10. "Decisions on the Adoption of Radiation Protection Standards for Gaseous Tritium Light Devices" (PDF). OECD. OECD Legal Instruments: 15. 24 July 1973. Retrieved 19 February 2020.
  11. "Nuclide Safety Data Sheet Hydrogen-3" (PDF). www.ehso.emory.edu. Archived from the original (PDF) on 2006-09-08. Retrieved 2006-11-09.
  12. "www.legislation.gov.au". Australian Radiation Protection and Nuclear Safety Regulations 1999. Retrieved 2017-11-01.
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