Yang Shao-Horn

Yang Shao-Horn is a Chinese American scholar, Professor of Mechanical Engineering[1][3][4] and Materials Science and Engineering[5] and a member of Research Laboratory of Electronics at the Massachusetts Institute of Technology. She is known for research on understanding and controlling of processes for storing electrons in chemical bonds towards zero-carbon energy and chemicals.

Yang Shao-Horn
Born
Yang Shao
EducationSecond High School Attached to Beijing Normal University
Alma materBeijing University of Technology (BS)
Michigan Technological University (PhD)
Known forClean energy, electrochemistry, material chemistry and catalysis
AwardsFaraday Medal
Scientific career
FieldsChemistry
Materials
Computation
Spectroscopy
Catalysis[1]
InstitutionsMassachusetts Institute of Technology
Thesis (1998)
Doctoral studentsBetar Gallant[2]
Websitehttps://www.rle.mit.edu/eel/


Education

Shao-Horn was born in Beijing and was educated at Second High School Attached to Beijing Normal University. She obtained her B.S. in Metallurgical Engineering at Beijing University of Technology,[6] and moved to Michigan Technological University for graduate studies, where her Ph.D. research was focused on mechanistic investigations of Li-ion battery material failures using transmission electron microscopy, co-advised by Stephen A. Hackney[7] and M.M. Thackeray[8] at Argonne National Laboratory.

Research and career

Upon the completion of her Ph.D. in 1998, Shao-Horn joined the Eveready Battery Company in Westlake, Ohio as a Staff Scientist, during which she researched high-voltage spinel materials for Li-ion batteries,[9] iron disulfide for lithium primary batteries[10][11] and Alkaline Zn-MnO2 batteries.[12] Shao-Horn left Energizer in 2000 and obtained an NSF International Research Fellowship to work with Claude Delmas at the Institute of Condensed Matter Chemistry[13] in Bordeaux, France.

In 2002, she joined the MIT faculty. Shao-Horn's research is centered on exploiting physical/materials chemistry to understand and control the kinetics and dynamics for storing electrons in chemical bonds towards zero-carbon energy and chemicals. She is known for the use of surface electronic structure features and/or solvation environments to develop universal design principles of materials and electrode/electrolyte interface to enhance functions (activity, selectivity, and stability) spanning from making of sustainable chemicals and fuels,[14] via water splitting,[15] carbon dioxide,[16] to rechargeable Li-ion and Li-air batteries.[17]

She has pioneered the oxide electronic structure tuning to develop active catalysts to promote oxygen reduction and evolution kinetics. Shao-Horn and her collaborators have shown that the antibonding orbital filling of surface transition‑metal cations controls the catalytic activity of oxides for oxygen reduction[18] and oxygen evolution[19] in a volcano-shaped dependence over several orders of magnitude. Subsequently, Shao-Horn and her coworkers have shown that increasing the metal-oxygen covalency enhances activity for oxygen evolution but beyond an optimal value reduces oxide stability.[20][21] Exploiting this concept not only sets record catalytic activity but also establishes a new reaction mechanism, where both metal and oxygen sites can catalyze oxygen evolution[22] and deprotonation from oxide the surface can be rate-limiting.[23] Moreover, such concepts have been applied to elucidate that increasing metal-oxygen covalency of metal oxides can promote the dehydrogenation of organic molecules such as carbonate solvents and electrolyte degradation by late transition metal oxides, which decreases the cycle life of Li-ion batteries[24][25][26] and selective oxidation of hydrocarbon fuels.

Shao-horn has given a number of lectures in academia (e.g. Marvel Lecture, Stanford ENERGY and Storage X 2021), at industrial events (e.g., BASF Energy Symposium 2015[27]) and high-level strategic meetings (e.g., Ideaslab of World Economic Forum in Davos). She has advised ~90 students and postdoctoral associates at MIT, who are now pursuing successful careers in industry, national research laboratories, and in academia (~30) including faculty positions at University of Michigan, MIT and Cornell and academic positions in Europe and Asia.

Awards and honors

Shao-Horn was awarded the Charles W. Tobias Young Investigator Award 2008 for notable contributions to understanding the mechanism of Pt catalyst loss in fuel cells, which has contributed to prolonging the lifetime of fuel cells in consumer vehicles in collaboration with Hubert A. Gasteiger[28] and colleagues at GM,[29][30] and to enhance oxygen reduction activity for Pt alloy catalysts in fuel cells.[31][32][33]

In 2018, Shao-Horn was awarded the Faraday Medal of Royal Society of Chemistry for her contributions to electrochemistry research, and she is the first woman receiving this recognition since its inception in 1977.[34][35] In 2020, she was awarded the Dr. Karl Wamsler Innovation Award from the Technical University of Munich in appreciation of her visionary electrocatalysis research, developing universal guiding principles to understand and optimize charge transfer at the solid-gas and solid-liquid interface to store energy in chemical bonds. She is the first woman receiving this award since its inception in 2017.[36] She was selected to receive a Humbolt Prize in Chemistry from the Alexander von Humboldt Foundation for fundamental studies of interface at the Fritz Haber Institute.

Shao-Horn is a member of the U.S. National Academy of Engineering since 2018. She is a fellow of the American Association for the Advancement of Science, the Electrochemical Society, the National Academy of Inventors and the International Society of Electrochemistry. She serves as Senior Editor for Accounts of Materials Research of American Chemical Society (ACS), and on advisory/editorial boards of leading journals such as the Journal of Physical Chemistry in ACS, Energy and Environmental Science from Royal Society of Chemistry (RSC), Advanced Energy Materials and Advanced Functional Materials from Wiley, Materials Today, Chem, Cell Press Chem, and Joule from Elsevier, and the board of directors for International Meetings of Lithium batteries.

Selected bibliography
  1. T. Wang, Y. Zhang, B. Huang, B. Cai, R.R.  Rao, L. Giordano, S.G. Sun and Y. Shao-Horn, Enhancing the Catalysis of Oxygen Reduction Reaction via Tuning Interfacial Hydrogen Bonds, Nature Catalysis, 4, 753-762, September 2021.
  2. H. Iriawan, S.Z. Andersen, X. Zhang, B. M. Comer, J. Barrio, P. Chen, A.J. Medford, I.E.L. Stephens, I. Chorkendorff and Y. Shao-Horn, Methods for nitrogen activation by reduction and oxidation, Nature Reviews Methods Primers, 1, 56, August 2021.
  3. B. Huang, R.R. Rao, S. You, K. H. Myint, Y. Song, Y. Wang, W. Ding, L. Giordano, Y. Zhang, T. Wang, S. Muy, Y. Katayama, J. C. Grossman, A. P. Willard, K. Xu, Y. Jiang and Y. Shao-Horn, Cation- and pH-Dependent Hydrogen Evolution and Oxidation Reaction Kinetics, Journal of the American Chemical Society Au, 14, 6030-6040, August 2021.
  4. J. Hwang, R.R. Rao, L. Giordano, K. Akkiraju, X.R. Wang, E. Crumlin and Y. Shao-Horn, Regulating oxygen activity of perovskites to promote NOx oxidation, Nature Catalysis, 4, 663-673, July 2021.
  5. R.R. Rao, M.J. Kolb, L. Giordano, A. F. Pederson, Y. Katayama, J. Hwang, A. Mehta, H. You, J.R. Lunger, H. Zhou, N.B. Halck, T. Vegge, I. Chorkendorff, I.E.L. Stephens, and Y. Shao-Horn, Operando Identification of Site-Dependent Water Oxidation Activity on Ruthenium Dioxide Single-Crystal Surfaces, Nature Catalysis, 3, 516-525, May 2020.
  6. Y. Zhang, Y. Katayama, R. Tatara, L. Giordano, Y. Yu, D. Fraggedakis, J. Sun, F. Maglia, R. Jung, M.Z. Bazant and Y. Shao-Horn, Revealing Electrolyte Oxidation via Carbonate Dehydrogenation on Ni-based Oxides in Li-ion Batteries by in situ Fourier Transform Infrared Spectroscopy, Energy and Environmental Science, 13, 183-199, November 2019.
  7. B.J. Hopkins, Y. Shao-Horn, and D. P. Hart, Suppressing Corrosion In Primary Aluminum–Air Batteries Via Oil Displacement, Science, 362, 658-661, November 2018.
  8. J. Hwang, R.R. Rao, L. Giordano, Y. Katayama, Y. Yu, and Y. Shao-Horn, Perovskites in Catalysis and Electrocatalysis, Science, 358, 751-756, November 2017.
  9. W. Hong, K.A. Stoerzinger, Y-L. Lee, L. Giordano, A.J.L. Grimaud, A.M. Johnson, J. Hwang, E. Crumlin, W. Yang, Y. Shao-Horn, Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides, Energy & Environmental Science, 10, 2190-2200, October 2017.
  10. L. Giordano, P. Karayaylali, Y. Yu, Y. Katayama, F. Maglia, S. Lux, and Y. Shao-Horn, Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries, Journal of Physical Chemistry Letters, 8, 3881-3887, August 2017.
  11. W. Hong, K.A. Stoerzinger, Y-L. Lee, L. Giordano, A.J.L. Grimaud, A.M. Johnson, J. Hwang, E. Crumlin, W. Yang, Y. Shao-Horn, Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides, Energy & Environmental Science, 10, 2190-2200, October 2017.
  12. L. Giordano, P. Karayaylali, Y. Yu, Y. Katayama, F. Maglia, S. Lux, and Y. Shao-Horn, Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries, Journal of Physical Chemistry Letters, 8, 3881-3887, August 2017.
  13.  J. Bachman, S. Muy, Grimaud, A., H.H. Chang, N. Pour, S. Lux, O. Paschos, F. Maglia, S. Lupart, P. Lamp, L. Giordano and Y. Shao-Horn, Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction, Chemical Reviews, 116, 140-162, January 2016.
  14. D. Kwabi, V.S. Bryantsev, T.P. Batcho, D. Itkis, C.V. Thompson and Y. Shao-Horn, Experimental and Computational Analysis of the Solvent-Dependent O2/Li+-O2- Redox Couple: Standard Potentials, Coupling Strength and Implications for Lithium-Oxygen Batteries, Angewandte Chemie International Edition, 128, 3181-3186, February 2016.
  15. W.T. Hong, K.A. Stoerzinger, B. Mortiz, T.P. Devereaux, W.Yang, and Y. Shao-Horn, Probing LaMO3 Metal and Oxygen Partial Density of States Using X-ray Emission, Absorption, and Photoelectron Spectroscopy, Journal of Physical Chemistry C, 119, 2063-2072, 2015.
  16. B. Han, C.E. Carlton, A. Kongkanand, R.S. Kukreja, B.R.C. Theobald, L. Gan, R. O'Malley, P. Strasser, F.T. Wagner, and Y. Shao-Horn, Record Activity and Stability of Dealloyed Bimetallic Catalysts for Proton Exchange Membrane Fuel Cells, Energy & Environmental Science, 8, 258-266, 2015.
  17. J. Suntivich, K.J. May, H.A. Gasteiger, J.B. Goodenough and Y. Shao-Horn, A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles, Science, 334, 1383-1385, 2011.
  18. P.J. Ferreira, G.J. la O’, Y. Shao-Horn, D. Morgan, R. Makharia, S. Kocha and H. Gasteiger, Instability of Pt/C Electrocatalysts in Proton Exchange Membrane Fuel Cells: A Mechanistic Investigation, Journal of the Electrochemical Society, 152, A2256–A2271, 2005.

References
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  8. "Michael M. Thackeray | Argonne National Laboratory". www.anl.gov. Retrieved 2021-03-24.
  9. Shao-Horn, Yang; Middaugh, Richard L. (2001-01-02). "Redox reactions of cobalt, aluminum and titanium substituted lithium manganese spinel compounds in lithium cells". Solid State Ionics. 139 (1): 13–25. doi:10.1016/S0167-2738(00)00817-1. ISSN 0167-2738.
  10. Shao-Horn, Yang; Osmialowski, Steve; Horn, Quinn C. (2002). "Nano-FeS[sub 2] for Commercial Li/FeS[sub 2] Primary Batteries". Journal of the Electrochemical Society. 149 (11): A1499. doi:10.1149/1.1513558. ISSN 0013-4651.
  11. Shao-Horn, Yang; Osmialowski, Steve; Horn, Quinn C. (2002). "Reinvestigation of Lithium Reaction Mechanisms in FeS[sub 2] Pyrite at Ambient Temperature". Journal of the Electrochemical Society. 149 (12): A1547. doi:10.1149/1.1516772. ISSN 0013-4651.
  12. Horn, Quinn C.; Shao-Horn, Yang (2003). "Morphology and Spatial Distribution of ZnO Formed in Discharged Alkaline Zn/MnO[sub 2] AA Cells". Journal of the Electrochemical Society. 150 (5): A652. doi:10.1149/1.1566014. ISSN 0013-4651.
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  16. Khan, Sami; Hwang, Jonathan; Horn, Yang-Shao; Varanasi, Kripa K. (February 2021). "Catalyst-proximal plastrons enhance activity and selectivity of carbon dioxide electroreduction". Cell Reports Physical Science. 2 (2): 100318. Bibcode:2021CRPS....200318K. doi:10.1016/j.xcrp.2020.100318.
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  18. Suntivich, Jin; Gasteiger, Hubert A.; Yabuuchi, Naoaki; Nakanishi, Haruyuki; Goodenough, John B.; Shao-Horn, Yang (July 2011). "Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries". Nature Chemistry. 3 (7): 546–550. Bibcode:2011NatCh...3..546S. doi:10.1038/nchem.1069. ISSN 1755-4330. PMID 21697876.
  19. Suntivich, J.; May, K. J.; Gasteiger, H. A.; Goodenough, J. B.; Shao-Horn, Y. (2011-12-09). "A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles". Science. 334 (6061): 1383–1385. Bibcode:2011Sci...334.1383S. doi:10.1126/science.1212858. ISSN 0036-8075. PMID 22033519. S2CID 206537028.
  20. May, Kevin J.; Carlton, Christopher E.; Stoerzinger, Kelsey A.; Risch, Marcel; Suntivich, Jin; Lee, Yueh-Lin; Grimaud, Alexis; Shao-Horn, Yang (2012-11-15). "Influence of Oxygen Evolution during Water Oxidation on the Surface of Perovskite Oxide Catalysts". The Journal of Physical Chemistry Letters. 3 (22): 3264–3270. doi:10.1021/jz301414z.
  21. Grimaud, Alexis; May, Kevin J.; Carlton, Christopher E.; Lee, Yueh-Lin; Risch, Marcel; Hong, Wesley T.; Zhou, Jigang; Shao-Horn, Yang (2013-09-17). "Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution". Nature Communications. 4 (1): 2439. Bibcode:2013NatCo...4.2439G. doi:10.1038/ncomms3439. ISSN 2041-1723. PMID 24042731.
  22. Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong; Hong, Wesley T.; Lee, Yueh-Lin; Giordano, Livia; Stoerzinger, Kelsey A.; Koper, Marc T. M.; Shao-Horn, Yang (May 2017). "Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution". Nature Chemistry. 9 (5): 457–465. Bibcode:2017NatCh...9..457G. doi:10.1038/nchem.2695. hdl:1887/3191990. ISSN 1755-4349. PMID 28430191. S2CID 31604130.
  23. Hong, Wesley T.; Stoerzinger, Kelsey A.; Lee, Yueh-Lin; Giordano, Livia; Grimaud, Alexis; Johnson, Alyssa M.; Hwang, Jonathan; Crumlin, Ethan J.; Yang, Wanli; Shao-Horn, Yang (2017-10-11). "Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides". Energy & Environmental Science. 10 (10): 2190–2200. doi:10.1039/C7EE02052J. ISSN 1754-5706.
  24. Giordano, Livia; Karayaylali, Pinar; Yu, Yang; Katayama, Yu; Maglia, Filippo; Lux, Simon; Shao-Horn, Yang (2017-08-17). "Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries". The Journal of Physical Chemistry Letters. 8 (16): 3881–3887. doi:10.1021/acs.jpclett.7b01655. hdl:10281/299066. OSTI 1484008. PMID 28766340.
  25. Yu, Yang; Karayaylali, Pinar; Katayama, Yu; Giordano, Livia; Gauthier, Magali; Maglia, Filippo; Jung, Roland; Lund, Isaac; Shao-Horn, Yang (2018-12-06). "Coupled LiPF6 Decomposition and Carbonate Dehydrogenation Enhanced by Highly Covalent Metal Oxides in High-Energy Li-Ion Batteries". The Journal of Physical Chemistry C. 122 (48): 27368–27382. doi:10.1021/acs.jpcc.8b07848. ISSN 1932-7447. OSTI 1543653. S2CID 104574841.
  26. Zhang, Yirui; Katayama, Yu; Tatara, Ryoichi; Giordano, Livia; Yu, Yang; Fraggedakis, Dimitrios; Sun, Jame Guangwen; Maglia, Filippo; Jung, Roland; Bazant, Martin Z.; Shao-Horn, Yang (2020). "Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy". Energy & Environmental Science. 13 (1): 183–199. doi:10.1039/C9EE02543J. ISSN 1754-5692.
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  29. Ferreira, P. J.; la O', G. J.; Shao-Horn, Y.; Morgan, D.; Makharia, R.; Kocha, S.; Gasteiger, H. A. (2005). "Instability of Pt/C Electrocatalysts in Proton Exchange Membrane Fuel Cells". Journal of the Electrochemical Society. 152 (11): A2256. doi:10.1149/1.2050347. ISSN 0013-4651.
  30. Chen, Shuo; Gasteiger, Hubert A.; Hayakawa, Katsuichiro; Tada, Tomoyuki; Shao-Horn, Yang (2010). "Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes". Journal of the Electrochemical Society. 157 (1): A82. doi:10.1149/1.3258275. hdl:1721.1/79691. ISSN 0013-4651.
  31. Chen, Shuo; Ferreira, Paulo J.; Sheng, Wenchao; Yabuuchi, Naoaki; Allard, Lawrence F.; Shao-Horn, Yang (2008-10-22). "Enhanced Activity for Oxygen Reduction Reaction on "Pt3Co" Nanoparticles: Direct Evidence of Percolated and Sandwich-Segregation Structures". Journal of the American Chemical Society. 130 (42): 13818–13819. doi:10.1021/ja802513y. ISSN 0002-7863. PMID 18811156.
  32. Chen, Shuo; Sheng, Wenchao; Yabuuchi, Naoaki; Ferreira, Paulo J.; Allard, Lawrence F.; Shao-Horn, Yang (2009-01-22). "Origin of Oxygen Reduction Reaction Activity on "Pt3Co" Nanoparticles: Atomically Resolved Chemical Compositions and Structures". The Journal of Physical Chemistry C. 113 (3): 1109–1125. doi:10.1021/jp807143e. ISSN 1932-7447.
  33. Han, Binghong; Carlton, Christopher E.; Kongkanand, Anusorn; Kukreja, Ratandeep S.; Theobald, Brian R.; Gan, Lin; O'Malley, Rachel; Strasser, Peter; Wagner, Frederick T.; Shao-Horn, Yang (2015). "Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells". Energy & Environmental Science. 8 (1): 258–266. doi:10.1039/C4EE02144D. hdl:1721.1/97720. ISSN 1754-5692. S2CID 67836581.
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