Butane

The density of butane is highly dependent on temperature and pressure in the reservoir.[9] For example, the density of liquid phase is 571.8±1 kg/m³ (for pressures up to 2MPa and temperature 27±0.2 °C), while the density of liquid butane is 625.5±0.7 kg/m³ (for pressures up to 2MPa and temperature -13±0.2 °C).

Propane & butane density data [9]

Butane and Propane were simultaneously discovered in 1912 by an American chemist, Dr. Walter Snelling. Snelling identified these gases as components in gasoline and found that if they were cooled, they could be stored in a volume-reduced liquified state in pressurized containers.[10]

Common name	normal butane unbranched butane n-butane	isobutane i-butane
IUPAC name	butane	methylpropane
Molecular diagram
Skeletal diagram

Rotation about the central C−C bond produces two different conformations (trans and gauche) for n-butane.[11]

Spectrum of the blue flame from a butane torch showing CH molecular radical band emission and C₂ Swan bands

When oxygen is plentiful, butane burns to form carbon dioxide and water vapor; when oxygen is limited, carbon (soot) or carbon monoxide may also be formed. Butane is denser than air.

When there is sufficient oxygen:

2 C₄H₁₀ + 13 O₂ → 8 CO₂ + 10 H₂O

When oxygen is limited:

2 C₄H₁₀ + 9 O₂ → 8 CO + 10 H₂O

By weight, butane contains about 49.5 MJ/kg (13.8 kWh/kg; 22.5 MJ/lb; 21,300 Btu/lb) or by liquid volume 29.7 megajoules per liter (8.3 kWh/L; 112 MJ/U.S. gal; 107,000 Btu/U.S. gal).

The maximum adiabatic flame temperature of butane with air is 2,243 K (1,970 °C; 3,578 °F).

n-Butane is the feedstock for DuPont's catalytic process for the preparation of maleic anhydride:

2 CH₃CH₂CH₂CH₃ + 7 O₂ → 2 C₂H₂(CO)₂O + 8 H₂O

n-Butane, like all hydrocarbons, undergoes free radical chlorination providing both 1-chloro- and 2-chlorobutanes, as well as more highly chlorinated derivatives. The relative rates of the chlorination is partially explained by the differing bond dissociation energies, 425 and 411 kJ/mol for the two types of C-H bonds.

Normal butane can be used for gasoline blending, as a fuel gas, fragrance extraction solvent, either alone or in a mixture with propane, and as a feedstock for the manufacture of ethylene and butadiene, a key ingredient of synthetic rubber. Isobutane is primarily used by refineries to enhance (increase) the octane number of motor gasoline.[12][13][14][15]

For gasoline blending, n-butane is the main component used to manipulate the Reid vapor pressure (RVP). Since winter fuels require much higher vapor pressure for engines to start, refineries raise the RVP by blending more butane into the fuel.[16] n-Butane has a relatively high research octane number (RON) and motor octane number (MON), which are 93 and 92 respectively.[17]

When blended with propane and other hydrocarbons, the mixture may be referred to commercially as liquefied petroleum gas (LPG). It is used as a petrol component, as a feedstock for the production of base petrochemicals in steam cracking, as fuel for cigarette lighters and as a propellant in aerosol sprays such as deodorants.[18]

Pure forms of butane, especially isobutane, are used as refrigerants and have largely replaced the ozone-layer-depleting halomethanes in refrigerators, freezers, and air conditioning systems. The operating pressure for butane is lower than for the halomethanes such as Freon-12 (R-12), so R-12 systems such as those in automotive air conditioning systems, when converted to pure butane, will function poorly. A mixture of isobutane and propane is used instead to give cooling system performance comparable to use of R-12.

Butane is also used as lighter fuel for a common lighter or butane torch and is sold bottled as a fuel for cooking, barbecues and camping stoves. The global market for butane canisters is dominated by South Korean manufacturers.[19] In the 20th century the Braun (company) of Germany made a cordless hair styling device product that used butane as its heat source to produce steam.[20]

As fuel, it is often mixed with small amounts of mercaptans to give the unburned gas an offensive smell easily detected by the human nose. In this way, butane leaks can easily be identified. While hydrogen sulfide and mercaptans are toxic, they are present in levels so low that suffocation and fire hazard by the butane becomes a concern far before toxicity.[21][22] Most commercially available butane also contains some contaminant oil, which can be removed by filtration and will otherwise leave a deposit at the point of ignition and may eventually block the uniform flow of gas.[23]

The butane used as a solvent for fragrance extraction does not contain these contaminants[24] and butane gas can cause gas explosions in poorly ventilated areas if leaks go unnoticed and are ignited by spark or flame.[5] Purified butane is used as a solvent in the industrial extraction of cannabis oils.

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  Butane fuel canisters for use in camping stoves
• 
  Butane lighter, showing liquid butane reservoir
• 
  An aerosol spray can, which may be using butane as a propellant
• 
  Butane gas cylinder used for cooking

Inhalation of butane can cause euphoria, drowsiness, unconsciousness, asphyxia, cardiac arrhythmia, fluctuations in blood pressure and temporary memory loss, when abused directly from a highly pressurized container, and can result in death from asphyxiation and ventricular fibrillation. It enters the blood supply and within seconds produces intoxication.[25] Butane is the most commonly abused volatile substance in the UK, and was the cause of 52% of solvent related deaths in 2000.[26] By spraying butane directly into the throat, the jet of fluid can cool rapidly to −20 °C (−4 °F) by expansion, causing prolonged laryngospasm.[27] "Sudden sniffer's death" syndrome, first described by Bass in 1970,[28] is the most common single cause of solvent related death, resulting in 55% of known fatal cases.[27]

• Isobutane
• Cyclobutane
• Dimethyl ether
• Volatile substance abuse
• Butane (data page)
• Butanone
• n-Butanol
• Liquefied petroleum gas
• Industrial gas
• Butane torch
• Gas explosions

Wikimedia Commons has media related to Butane.

• International Chemical Safety Card 0232
• NIOSH Pocket Guide to Chemical Hazards