Examples of acidity in the following topics:
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- Polyprotic acids, also known as polybasic acids, are able to donate more than one proton per acid molecule.
- Common examples of monoprotic acids in mineral acids include hydrochloric acid (HCl) and nitric acid (HNO3).
- On the other hand, for organic acids the term mainly indicates the presence of one carboxylic acid group, and sometimes these acids are known as monocarboxylic acid.
- Polyprotic acid are able to donate more than one proton per acid molecule, in contrast to monoprotic acids that only donate one proton per molecule.
- An example of a triprotic acid is orthophosphoric acid (H3PO4), usually just called phosphoric acid.
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- Diprotic and polyprotic acids contain multiple acidic protons that dissociate in distinct, sequential steps.
- As their name suggests, polyprotic acids contain more than one acidic proton.
- Two common examples are carbonic acid (H2CO3, which has two acidic protons and is therefore a diprotic acid) and phosphoric acid (H3PO4, which has three acidic protons and is therefore a triprotic acid).
- With any polyprotic acid, the first amd most strongly acidic proton dissociates completely before the second-most acidic proton even begins to dissociate.
- Identify the key features that distinguish polyprotic acids from monoprotic acids.
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- The acid dissociation constant (Ka) is the measure of the strength of an acid in solution.
- The acid dissociation constant (Ka) is a quantitative measure of the strength of an acid in solution.
- Acid dissociation constants are most often associated with weak acids, or acids that do not completely dissociate in solution.
- Acids with a pKa value of less than about -2 are said to be strong acids.
- Acetic acid is a weak acid with an acid dissociation constant $K_a=1.8\times 10^{-5}$ .
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- The strength of an acid refers to the ease with which the acid loses a proton.
- where HA is a protonated acid, H+ is the free acidic proton, and A- is the conjugate base.
- Strong acids yield weak conjugate bases.
- For sulfuric acid, which is diprotic, the "strong acid" designation refers only to the dissociation of the first proton:
- p-Toluenesulfonic acid is an example of an organic soluble strong acid, with a pKa of -2.8.
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- The majority of acids are weak.
- Examples of weak acids include acetic acid (CH3COOH), which is found in vinegar, and oxalic acid (H2C2O4), which is found in some vegetables.
- Acids with a Ka less than 1.8×10−16 are weaker acids than water.
- The Ka of acetic acid is $1.8\times 10^{-5}$.
- Although it is only a weak acid, a concentrated enough solution of acetic acid can still be quite acidic.
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- Originally, acids and bases were defined by Svante Arrhenius.
- A wide range of compounds can be classified in the Brønsted-Lowry framework: mineral acids and derivatives such as sulfonates, carboxylic acids, amines, carbon acids, and many more.
- The conjugate acid is the species that is formed when the Brønsted base accepts a proton from the Brønsted acid.
- Here, acetic acid acts as a Brønsted-Lowry acid, donating a proton to water, which acts as the Brønsted-Lowry base.
- Chemistry 12.1 What are Acids and Bases?
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- Halogen oxoacids include hypochlorous acid (HOCl); chlorous acid(HOClO); chloric acid(HOClO2); oerchloric acid(HOClO3); oerbromic acid (HOBrO3)
- Consider the simple oxyacids HOI (hypoiodous acid), HOBr (hypobromous acid), and HOCl (hypochlorous acid).
- The strongest acid is perchloric acid on the left, and the weakest is hypochlorous acid on the far right.
- Carboxylic acids are the most common type of organic acid.
- Mellitic acid is an example of a hexacarboxylic acid.
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- Carboxylic acids are organic acids that contain a carbon atom that participates in both a hydroxyl and a carbonyl functional group.
- As proton donors, carboxylic acids are characterized as Brønsted-Lowry acids.
- Salts and esters of carboxylic acids are called carboxylates.
- Generally, in IUPAC nomenclature, carboxylic acids have an "-oic acid" suffix, although "-ic acid" is the suffix most commonly used.
- Carboxylic acids are characterized as weak acids, meaning that they do not fully dissociate to produce H+ cations in a neutral aqueous solution.
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- Simple acids, known as binary acids, have only one anion and one hydrogen.
- So, HNO3 will be nitric acid.
- Therefore, HClO4 is called perchloric acid.
- For example, chlorous acid is HClO2.
- For example, instead of bromic acid, HBrO3, we have hypobromous acid, HBrO.
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- Common examples of acids include acetic acid (in vinegar), sulfuric acid (used in car batteries), and tartaric acid (used in baking).
- A stronger acid more readily ionizes, or dissociates, in a solution than a weaker acid.
- sulfuric acid (H2SO4; only the first proton is considered strongly acidic)
- Stronger acids have a larger Ka and a more negative pKa than weaker acids.
- Acids + Bases Made Easy!