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CYCLOPENTANONE

ICSC: 0427

Ketocyclopentane
Adipic ketone
C5H8O
Molecular mass: 84.12
ICSC # 0427
CAS # 120-92-3
RTECS # GY4725000
UN # 2245
EC # 606-025-00-9
August 04, 1997 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Flammable. Heating will cause rise in pressure with risk of bursting.
NO open flames, NO sparks, and NO smoking.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Gas/air mixtures are explosive.

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


•INHALATION Cough. Sore throat.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Refer for medical attention.
•SKIN Redness. Pain.
Protective gloves.
Rinse and then wash skin with water and soap.
•EYES Redness. Pain.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION
Do not eat, drink, or smoke during work.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
Fireproof. Separated from acids. Cool. Keep in the dark. Keep in a well-ventilated room. Store only if stabilized.

Xi symbol
R: 10-36/38
S: 2-23
UN Hazard Class: 3
UN Packing Group: III
ICSC: 0427 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

CYCLOPENTANONE

ICSC: 0427

I

M

P

O

R

T

A

N

T


D

A

T

A

PHYSICAL STATE; APPEARANCE:
CLEAR, COLOURLESS LIQUID.

PHYSICAL DANGERS:
The vapour is heavier than air.

CHEMICAL DANGERS:
The substance easily polymerizes under the influence of acid(s).

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes, the skin, possibly the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point: 131°C
Melting point: -51°C
Relative density (water = 1): 0.95
Solubility in water:
poor
Relative vapour density (air = 1): 2.3
Flash point: 26°C

ENVIRONMENTAL
DATA


N O T E S

Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Card has been partly updated in October 2005. See section Emergency Response.
Transport Emergency Card: TEC (R)-30S2245 or 30GF1-III

NFPA Code: H2; F3; R0;

ADDITIONAL INFORMATION



ICSC: 0427 CYCLOPENTANONE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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