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2,4,4-TRIMETHYL-2-PENTENE

ICSC: 0737

Diisobutene
Diisobutylene
C8H16 / CH3C(CH3)=CHC(CH3)3
Molecular mass: 112.2
ICSC # 0737
CAS # 107-40-4
UN # 2050
July 04, 1997 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Highly flammable.
NO open flames, NO sparks, and NO smoking.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Vapour/air mixtures are explosive.
Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT GENERATION OF MISTS!

•INHALATION Drowsiness. Headache. Nausea.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
•SKIN Redness.
Protective gloves.
First rinse with plenty of water, then remove contaminated clothes and rinse again.
•EYES
Safety spectacles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION Abdominal pain. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Evacuate danger area! Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours).
Fireproof. Separated from oxidants. Cool.

UN Hazard Class: 3
UN Packing Group: II
ICSC: 0737 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

2,4,4-TRIMETHYL-2-PENTENE

ICSC: 0737

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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID.

PHYSICAL DANGERS:
The vapour is heavier than air and may travel along the ground; distant ignition possible.

CHEMICAL DANGERS:
Reacts with oxidants.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the skin. The substance may cause effects on the central nervous system.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point: 104°C
Melting point: -106°C
Relative density (water = 1): 0.72
Solubility in water: none
Vapour pressure, kPa at 38°C: 11.02
Relative vapour density (air = 1): 3.9
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.31
Flash point: 1.7°C o.c.
Auto-ignition temperature: 305°C

ENVIRONMENTAL
DATA


N O T E S

Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.
NFPA Code: H2; F3; R0;

ADDITIONAL INFORMATION



ICSC: 0737 2,4,4-TRIMETHYL-2-PENTENE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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