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DINOCAP (ISOMER MIXTURE)

ICSC: 0881

2,4-Dinitro-6-(2-octyl)phenyl crotonate
2-Butenoic acid, 2(or 4)-isooctyl-4,6(or 2,6)dinitrophenyl ester
2,6(or 2,4)-Dinitro-4(or 6)octylphenyl crotonates in which octyl is a mixture of 1-methylheptyl, 1-ethylhexyl and 1-propylpentyl groups
DPC
C18H24N2O6
Molecular mass: 364.4
ICSC # 0881
CAS # 39300-45-3
RTECS # GQ5775000
EC # 609-023-00-6
August 10, 1997 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
STRICT HYGIENE! AVOID EXPOSURE OF (PREGNANT) WOMEN! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!

•INHALATION Laboured breathing. See Ingestion.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
•SKIN Pain. Redness.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
•EYES
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION Nausea. Vomiting.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment. Personal protection: A/P2 filter respirator for organic vapour and harmful dust.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs . See Chemical Dangers. Cool. Well closed.

Note: E
T symbol
N symbol
R: 61-20-22-38-43-48/22-50/53
S: 53-45-60-61
ICSC: 0881 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

DINOCAP (ISOMER MIXTURE)

ICSC: 0881

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A

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D

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PHYSICAL STATE; APPEARANCE:
DARK BROWN LIQUID

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes including nitrogen oxides . The substance is a weak acid. Reacts with strong oxidants causing fire and explosion hazard. May decompose when heated above 32°C.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the skin .

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization. Animal tests show that this substance possibly causes malformations in human babies.

PHYSICAL
PROPERTIES

Boiling point at 0.007kPa: 138-140°C
Relative density (water = 1): 1.10
Solubility in water:
none
Vapour pressure, Pa at 20°C: negligible

ENVIRONMENTAL
DATA

The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.

N O T E S

Incompatible with oil, oil based sprays and lime sulfur mixture. Carrier solvents used in commercial formulations may change physical and toxicological properties. Caprane, Crotothane and Karathane are trade names. Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.

ADDITIONAL INFORMATION



ICSC: 0881 DINOCAP (ISOMER MIXTURE)
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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