Perchloryl fluoride
Synonyms & Trade Names
Chlorine fluoride oxide, Chlorine oxyfluoride, TrioxychlorofluorideExposure Limits
NIOSH REL
TWA 3 ppm (14 mg/m3) ST 6 ppm (28 mg/m3)OSHA PEL
TWA 3 ppm (13.5 mg/m3) See Appendix GPhysical Description
Colorless gas with a characteristic, sweet odor. [Note: Shipped as a liquefied compressed gas.]Molecular Weight
102.5Boiling Point
-52°FFreezing Point
-234°FSolubility
0.06%Vapor Pressure
10.5 atmIonization Potential
13.60 eVFlash Point
NAUpper Exposive Limit
NALower Explosive Limit
NARelative Gas Density
3.64Incompatibilities & Reactivities
Combustibles, strong bases, amines, finely divided metals, reducing agents, alcoholsExposure Routes
inhalation, skin and/or eye contact (liquid)Symptoms
irritation respiratory system; liquid: frostbite; In Animals: methemoglobinemia; cyanosis; lassitude (weakness, exhaustion), dizziness, headache; pulmonary edema; pneumonitis; anoxiaTarget Organs
Skin, respiratory system, bloodPersonal Protection/Sanitation
(See protection codes)Skin:Frostbite
Eyes:Frostbite
Wash skin:No recommendation
Remove:No recommendation
Change:No recommendation
Provide:Frostbite wash
Respirator Recommendations
NIOSH/OSHA
Up to 30 ppm:
(APF = 10) Any supplied-air respirator
Up to 75 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode*
Up to 100 ppm:
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted canister providing protection against the compound of concern¿
Any appropriate escape-type, self-contained breathing apparatus
- Page last reviewed:April 11, 2016
- Page last updated:April 11, 2016
- Content source:
- National Institute for Occupational Safety and Health (NIOSH) Education and Information Division