Arsenidogermanate

Arsenidogermanates are chemical compounds that contain anions with arsenic bonded to germanium. They are in the category of tetrelarsenides, pnictidogermanates, or tetrelpnictides.

Germanium forms two arsenides: GeAs and GeAs₂.[1]

List

formula	formula weight	crystal system	space group	unit cell	volume	density	comments	ref
LiGe₃As₃		orthorhombic	Pbam	a=10.0862 b=15.7612 c=3.7403 Z=4	594.60	5.01		[2]
Li₅GeAs₃							black	[3]
NaGe₆As₆	908.05	monoclinic	C2/m	a = 22.063, b = 3.8032, c = 7.2020, β = 92.744°, Z = 2	603.64	5.00	needles	[4]
Na₁₀Ge₂As₆		monoclinic	P12₁/n1	a=13.531 b=7.544 c=8.298 β = 90.2° Z=2	847.0			[5]
K₂GeAs₂		orthorhombic	Ibam	a = 13.292, b = 7.028, c = 6.548 Z = 4			moisture sensitive needles	[6]
KGe₃As₃	481.53	orthorhombic	Pnma	a=9.993, b=3.7664, c=18.607 Z=4	700.34	4.568		[7]
K₂Ge₃As₃	520.73	orthorhombic	Pnnm	a=14.1466 b=16.300 c=3.7489 Z=4	864.47	4.001	fibrous metallic	[8]
K₂NaGaAs₂			Ibam	a=6.733 b=14.809 c=6.574 Z=4	655.5	3.250		[9]
KCdGeAs₂		triclinic	P1	a = 8.004, b = 8.402, c = 8.703, α = 71.019°, β = 75.257°, γ = 73.746°, Z=4			band gap 0.8 eV; Ge₂As₆ units	[10]
RbCdGeAs₂		triclinic	P1	a = 8.269, b = 8.452, c = 8.735, α = 71.163°, β = 75.601°, γ = 73.673°, Z=4			Ge₂As₆ units	[10]
Sr₃Ge₂As₄							red metallic; 1D As₃GeGeAs₃ units	[11]
K₅In₅Ge₅As₁₄		monoclinic	C2/m	a=40.00,b=3.925,c=10.299, β=99.97°, Z=8	1592	4.55	air sensitive; layered	[12]
K₈In₈Ge₅As₁₇		monoclinic	P2₁/c	a=18.394,b=19.087,c=25.360, β=105.71°, Z=4	8571	4.45	air sensitive; layered	[12]
RbGe₃As₃	528	orthorhombic	Pnma	a=10.166 b=3.7595 c=19.028 Z=4	727.2	4.823		[7]
Rb(Ge_1.5In_0.5)As₂(As_1.5Ge_0.5)		orthorhombic	Cmc2₁	a = 3.799, b = 16.50, c = 12.24, Z = 4	767	4.589		[13]
Rb_XGe_2−XIn_XAs₄								[13]
I₈As₂₁Ge₂₅	4403	cubic	Pm3n	a=10.5963 Z=1	1189.8	6.1431	colourless	[14]
Cs₅GeAs₃							metallic; unstable in air; GeAs₃ units	[15]
BaGe₂As₂		tetragonal	P4₂mc	a=7,786 c=8.664 Z=4	525.2	5.47	metallic	[16]
Ba₄GeAs₄							dark metallic; GeAs₄ units	[17]
Re₃Ge_0.6As_6.4								[18]
Re₃GeAs₆	1080.75	cubic	Im3m	a = 8.73202 Z=4	665.75	10.78	n-type semiconductor	[18]
AuGeAs		monoclinic	Cc	a 7.2729, b 6.2953, c 6.3067, β 119.209°				[19]
K_XGe_2−XTl_XAs₄								[13]

References

Stöhr, Herbert; Klemm, Wilhelm (1940-07-09). "Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut". Zeitschrift für anorganische und allgemeine Chemie. 244 (2): 205–223. doi:10.1002/zaac.19402440211.
Mark, Justin; Hanrahan, Michael P.; Woo, Katherine E.; Lee, Shannon; Rossini, Aaron J.; Kovnir, Kirill (2 May 2019). "Chemical and Electrochemical Lithiation of van der Waals Tetrel‐Arsenides". Chemistry – A European Journal. 25 (25): 6392–6401. doi:10.1002/chem.201900339. OSTI 1526289. PMID 30887569. S2CID 83463348.
Juza, Robert; Schulz, Werner (February 1954). "Ternäre Phosphide und Arsenide des Lithiums mit Elementen der 3. und 4. Gruppe". Zeitschrift für anorganische und allgemeine Chemie (in German). 275 (1–3): 65–78. doi:10.1002/zaac.19542750107. ISSN 0044-2313.
Khatun, Mansura; Mar, Arthur (2016-05-01). "NaGe₆As₆: Insertion of sodium into the layered semiconductor germanium arsenide GeAs". Zeitschrift für Naturforschung B. 71 (5): 375–380. doi:10.1515/znb-2015-0203. ISSN 1865-7117. S2CID 197298002.
Eisenmann, B.; Klein, J.; Somer, M. (1991-02-01). Eisenmann, B.; Klein, J.; Somer, M. (eds.). "Crystal structure of decasodium di-μ-arsenido-bis(diarsenidogermanate), Na₁₀Ge₂As₆". Zeitschrift für Kristallographie - Crystalline Materials. 197 (3–4): 265–266. Bibcode:1991ZK....197..265E. doi:10.1524/zkri.1991.197.3-4.265. ISSN 2194-4946.
Eisenmann, Brigitte; Klein, Jürgen (September 1991). "SiS₂-isostrukturelle Anionen [SiP₂²⁻], [GeAs₂²⁻] und [SnAs₂²⁻] in Alkaliverbindungen". Journal of the Less Common Metals (in German). 175 (1): 109–117. doi:10.1016/0022-5088(91)90355-8.
Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt₃As₃ (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry. 238: 229–235. Bibcode:2016JSSCh.238..229K. doi:10.1016/j.jssc.2016.03.035.
Eulenstein, Armin R.; Bogdanovski, Dimitri; Reinhardt, Hendrik; Miß, Vanessa; Roling, Bernhard; Hampp, Norbert; Dronskowski, Richard; Dehnen, Stefanie (12 November 2019). "K₂Ge₃As₃: Fiberlike Crystals of a Narrow-Band-Gap Zintl Phase with a One-Dimensional Substructure _∞¹{(Ge₃As₃)^2–}". Chemistry of Materials. 31 (21): 8839–8849. doi:10.1021/acs.chemmater.9b02827. S2CID 204116281.
Somer, Mehmet; Peters, Karl; von Schnering, Hans Georg (July 1992). "K₂NaGaP₂, Cs₂NaGaP₂, K₂NaGaAs₂, K₂NaInP₂ und K₂NaInAs₂, Verbindungen mit den SiS₂-isosteren Polyanionen ^∞
₁[MX_4/2]³⁻ (M=Ga, In; X=P, As)". Zeitschrift für anorganische und allgemeine Chemie (in German). 613 (7): 19–25. doi:10.1002/zaac.19926130103. ISSN 0044-2313.
Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (21 July 2014). "Quaternary Arsenides ACdGeAs₂ (A = K, Rb) Built of Ethane-Like Ge₂As₆ Units". Inorganic Chemistry. 53 (14): 7756–7762. doi:10.1021/ic5011264. PMID 24983676.
Eisenmann, Brigitte; Schäfer, Herbert (June 1980). "Zintl Phases with Complex Anions: Sr₃Si₂As₄ and Sr₃Ge₂As₄". Angewandte Chemie International Edition in English. 19 (6): 490–491. doi:10.1002/anie.198004901.
Shreeve-Keyer, Julie L; Haushalter, Robert C; Lee, Young-Sook; Li, Sichu; O'Connor, Charles J; Seo, Dong-Kyun; Whangbo, Myung-Hwan (May 1997). "New Layered Materials in the K–In–Ge–As System: K₈In₈Ge₅As₁₇ and K₅In₅Ge₅As₁₄". Journal of Solid State Chemistry. 130 (2): 234–249. Bibcode:1997JSSCh.130..234S. doi:10.1006/jssc.1996.7210.
Shreeve-Keyer, Julie L.; Haushalter, Robert C. (1996), Kajimura, Koji; Kuroda, Shin-ichi (eds.), "Synthesis and Structural Characterization of a Quaternary Zintl Phase Material from the Rb:Ge:In:As System: Rb(Ge1.5ln0.5)As2(As1.5Ge0.5)", Materials and Measurements in Molecular Electronics, Springer Proceedings in Physics, Tokyo: Springer Japan, vol. 81, pp. 139–150, doi:10.1007/978-4-431-68470-1_11, ISBN 978-4-431-68472-5, retrieved 2021-12-08
Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (15 March 2009). "I₈As₂₁Ge₂₅". Acta Crystallographica Section E. 65 (3): i15. doi:10.1107/S1600536809004991. PMC 2968696. PMID 21582033.
Eisenmann, Brigitte; Klein, Jürgen; Somer, Mehmet (January 1990). "Anions Isosteric with CO₃²⁻ in Cs₅SiP₃, Cs₅SiAs₃, Cs₅GeP₃, and Cs₅GeAs₃". Angewandte Chemie International Edition in English. 29 (1): 87–88. doi:10.1002/anie.199000871.
Eisenmann, Brigitte; Schäfer, Herbert (1981-04-01). "Zintlphasen mit binären Anionen: Zur Kenntnis von BaGe₂P₂ und BaGe₂As₂ / Zintl Phases with Binary Anions: BaGe₂P₂ and BaGe₂As₂". Zeitschrift für Naturforschung B. 36 (4): 415–419. doi:10.1515/znb-1981-0403. ISSN 1865-7117. S2CID 95993285.
Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (February 1981). "Ba₄SiAs₄, and Ba₄GeAs₄, Zintl Phases with Isolated SiAs₄⁸⁻ and GeAs₄⁸⁻ anions". Angewandte Chemie International Edition in English. 20 (2): 197–198. doi:10.1002/anie.198101972.
Soheilnia, Navid; Xu, Hong; Zhang, Huqin; Tritt, Terry M.; Swainson, Ian; Kleinke, Holger (1 August 2007). "Thermoelectric Properties of Re₃Ge_0.6As_6.4 and Re₃GeAs₆ in Comparison to Mo₃Sb_5.4Te_1.6". Chemistry of Materials. 19 (16): 4063–4068. doi:10.1021/cm0708517.
Lee, Shannon J.; Won, Juyeon; Wang, Lin‐Lin; Jing, Dapeng; Harmer, Colin P.; Mark, Justin; Akopov, Georgiy; Kovnir, Kirill (6 May 2021). "New Noncentrosymmetric Tetrel Pnictides Composed of Square‐Planar Gold(I) with Peculiar Bonding". Chemistry – A European Journal. 27 (26): 7383–7390. doi:10.1002/chem.202005312. PMC 8251799. PMID 33523500.

This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.

[1] Stöhr, Herbert; Klemm, Wilhelm (1940-07-09). "Über Zweistoffsysteme mit Germanium. II. Germanium/Arsen, Germanium/Antimon, Germanium/Wismut". Zeitschrift für anorganische und allgemeine Chemie. 244 (2): 205–223. doi:10.1002/zaac.19402440211.

[2] Mark, Justin; Hanrahan, Michael P.; Woo, Katherine E.; Lee, Shannon; Rossini, Aaron J.; Kovnir, Kirill (2 May 2019). "Chemical and Electrochemical Lithiation of van der Waals Tetrel‐Arsenides". Chemistry – A European Journal. 25 (25): 6392–6401. doi:10.1002/chem.201900339. OSTI 1526289. PMID 30887569. S2CID 83463348.

[3] Juza, Robert; Schulz, Werner (February 1954). "Ternäre Phosphide und Arsenide des Lithiums mit Elementen der 3. und 4. Gruppe". Zeitschrift für anorganische und allgemeine Chemie (in German). 275 (1–3): 65–78. doi:10.1002/zaac.19542750107. ISSN 0044-2313.

[4] Khatun, Mansura; Mar, Arthur (2016-05-01). "NaGe₆As₆: Insertion of sodium into the layered semiconductor germanium arsenide GeAs". Zeitschrift für Naturforschung B. 71 (5): 375–380. doi:10.1515/znb-2015-0203. ISSN 1865-7117. S2CID 197298002.

[5] Eisenmann, B.; Klein, J.; Somer, M. (1991-02-01). Eisenmann, B.; Klein, J.; Somer, M. (eds.). "Crystal structure of decasodium di-μ-arsenido-bis(diarsenidogermanate), Na₁₀Ge₂As₆". Zeitschrift für Kristallographie - Crystalline Materials. 197 (3–4): 265–266. Bibcode:1991ZK....197..265E. doi:10.1524/zkri.1991.197.3-4.265. ISSN 2194-4946.

[6] Eisenmann, Brigitte; Klein, Jürgen (September 1991). "SiS₂-isostrukturelle Anionen [SiP₂²⁻], [GeAs₂²⁻] und [SnAs₂²⁻] in Alkaliverbindungen". Journal of the Less Common Metals (in German). 175 (1): 109–117. doi:10.1016/0022-5088(91)90355-8.

[:02-7] Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (June 2016). "Ternary arsenides ATt₃As₃ (A=K, Rb; Tt=Ge, Sn) with layered structures". Journal of Solid State Chemistry. 238: 229–235. Bibcode:2016JSSCh.238..229K. doi:10.1016/j.jssc.2016.03.035.

[8] Eulenstein, Armin R.; Bogdanovski, Dimitri; Reinhardt, Hendrik; Miß, Vanessa; Roling, Bernhard; Hampp, Norbert; Dronskowski, Richard; Dehnen, Stefanie (12 November 2019). "K₂Ge₃As₃: Fiberlike Crystals of a Narrow-Band-Gap Zintl Phase with a One-Dimensional Substructure _∞¹{(Ge₃As₃)^2–}". Chemistry of Materials. 31 (21): 8839–8849. doi:10.1021/acs.chemmater.9b02827. S2CID 204116281.

[9] Somer, Mehmet; Peters, Karl; von Schnering, Hans Georg (July 1992). "K₂NaGaP₂, Cs₂NaGaP₂, K₂NaGaAs₂, K₂NaInP₂ und K₂NaInAs₂, Verbindungen mit den SiS₂-isosteren Polyanionen ^∞
₁[MX_4/2]³⁻ (M=Ga, In; X=P, As)". Zeitschrift für anorganische und allgemeine Chemie (in German). 613 (7): 19–25. doi:10.1002/zaac.19926130103. ISSN 0044-2313.

[:0-10] Khatun, Mansura; Stoyko, Stanislav S.; Mar, Arthur (21 July 2014). "Quaternary Arsenides ACdGeAs₂ (A = K, Rb) Built of Ethane-Like Ge₂As₆ Units". Inorganic Chemistry. 53 (14): 7756–7762. doi:10.1021/ic5011264. PMID 24983676.

[11] Eisenmann, Brigitte; Schäfer, Herbert (June 1980). "Zintl Phases with Complex Anions: Sr₃Si₂As₄ and Sr₃Ge₂As₄". Angewandte Chemie International Edition in English. 19 (6): 490–491. doi:10.1002/anie.198004901.

[:1-12] Shreeve-Keyer, Julie L; Haushalter, Robert C; Lee, Young-Sook; Li, Sichu; O'Connor, Charles J; Seo, Dong-Kyun; Whangbo, Myung-Hwan (May 1997). "New Layered Materials in the K–In–Ge–As System: K₈In₈Ge₅As₁₇ and K₅In₅Ge₅As₁₄". Journal of Solid State Chemistry. 130 (2): 234–249. Bibcode:1997JSSCh.130..234S. doi:10.1006/jssc.1996.7210.

[:3-13] Shreeve-Keyer, Julie L.; Haushalter, Robert C. (1996), Kajimura, Koji; Kuroda, Shin-ichi (eds.), "Synthesis and Structural Characterization of a Quaternary Zintl Phase Material from the Rb:Ge:In:As System: Rb(Ge1.5ln0.5)As2(As1.5Ge0.5)", Materials and Measurements in Molecular Electronics, Springer Proceedings in Physics, Tokyo: Springer Japan, vol. 81, pp. 139–150, doi:10.1007/978-4-431-68470-1_11, ISBN 978-4-431-68472-5, retrieved 2021-12-08

[14] Ayouz, Katia; Kars, Mohammed; Rebbah, Allaoua; Rebbah, Houria (15 March 2009). "I₈As₂₁Ge₂₅". Acta Crystallographica Section E. 65 (3): i15. doi:10.1107/S1600536809004991. PMC 2968696. PMID 21582033.

[15] Eisenmann, Brigitte; Klein, Jürgen; Somer, Mehmet (January 1990). "Anions Isosteric with CO₃²⁻ in Cs₅SiP₃, Cs₅SiAs₃, Cs₅GeP₃, and Cs₅GeAs₃". Angewandte Chemie International Edition in English. 29 (1): 87–88. doi:10.1002/anie.199000871.

[16] Eisenmann, Brigitte; Schäfer, Herbert (1981-04-01). "Zintlphasen mit binären Anionen: Zur Kenntnis von BaGe₂P₂ und BaGe₂As₂ / Zintl Phases with Binary Anions: BaGe₂P₂ and BaGe₂As₂". Zeitschrift für Naturforschung B. 36 (4): 415–419. doi:10.1515/znb-1981-0403. ISSN 1865-7117. S2CID 95993285.

[17] Eisenmann, Brigitte; Jordan, Hanna; Schäfer, Herbert (February 1981). "Ba₄SiAs₄, and Ba₄GeAs₄, Zintl Phases with Isolated SiAs₄⁸⁻ and GeAs₄⁸⁻ anions". Angewandte Chemie International Edition in English. 20 (2): 197–198. doi:10.1002/anie.198101972.

[:2-18] Soheilnia, Navid; Xu, Hong; Zhang, Huqin; Tritt, Terry M.; Swainson, Ian; Kleinke, Holger (1 August 2007). "Thermoelectric Properties of Re₃Ge_0.6As_6.4 and Re₃GeAs₆ in Comparison to Mo₃Sb_5.4Te_1.6". Chemistry of Materials. 19 (16): 4063–4068. doi:10.1021/cm0708517.

[19] Lee, Shannon J.; Won, Juyeon; Wang, Lin‐Lin; Jing, Dapeng; Harmer, Colin P.; Mark, Justin; Akopov, Georgiy; Kovnir, Kirill (6 May 2021). "New Noncentrosymmetric Tetrel Pnictides Composed of Square‐Planar Gold(I) with Peculiar Bonding". Chemistry – A European Journal. 27 (26): 7383–7390. doi:10.1002/chem.202005312. PMC 8251799. PMID 33523500.