Arsenide nitride

Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N³⁻) and arsenide (As³⁻). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.

Cubic Mg₃AsN, orthorhombic Ca₃AsN Sr₃AsN and Ba₃AsN showing increased distortion as alkaline earth metal increases in size.

Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.

List

name	formula	crystal system	space group	unit cell Å	volume	density	comment	ref
	Mg₃AsN	cubic	Pm3m	a =4.2148 Z=1	74.88	3.589	orange	[2]
	Ca₃AsN	orthorhombic	Pbnm	a=6.725 b=6.7198 c=9.5335 Z=4	430.8	3.237	red; moisture sensitive	[3]
	Ca₁₄As₆C_0.445N_1.135H_4.915		P4/mbm	a = 15.749 c = 9.1062			red; band gap 1.6 eV	[4]
	Cr₃AsN	tetragonal	I4/mcm	a=5.360 c=8.066				[5][6]
gallium arsenide nitride	Ga(As,N)
indium gallium arsenide nitride	(In,Ga)(As,N)
aluminium gallium arsenide nitride	(Al,Ga)(As,N)
	Sr₃AsN	orthorhombic	Pbnm	a=7.1856 b=10.1446 c=7.1464 Z=4	520.93	4.486	dark grey	[2]
	Ba₃AsN	orthorhombic	Pbnm	a=7.6741 b=10.7573 c=7.5387 Z=4	622.33	5.347	black	[2]
	LaFe₂AsN	orthorhombic	Cmcm	a =3.79932 b =11.11461 c =7.18656	303.474			[7]
	LaCo₂AsN	orthorhombic	Cmcm	a =3.75993 b =11.1674 c =7.0185	294699			[7]
	LaNi₂AsN	orthorhombic	Cmcm	a =3.71584 b =11.4147 c =6.9786	296.004			[7]
	Th₂ONAs		P3m1	a=4.041 c=6.979				[8]
	ThCrAsN						metallic	[9]
	ThMnAsN	tetragonal	P4/nmm	a =4.0818 b =4.0818 c =8.947			metallic	[10]
	ThFeAsN	tetragonal	P4/nmm	a = 4.0367 c = 8.5262			superconductor Tc 30 K	[11]
	ThFe_1-xCo_xAsN						superconductivity lost for x>0.05	[12]
	ThNiAsN	tetragonal	P4/nmm	a=4,0804 c=7.9888			superconductor at 4.3K	[13]
	BaTh₂Fe₄As₄(N_0.7O_0.3)₂			a=3.9886 c=29.853			Tc 22K	[14]
	U₂N₂As		P3m1	a=3.833 c=6.737				[8]

References

Toivonen, J.; Oila, J.; Saarinen, K.; Hakkarainen, T.; Sopanen, M.; Lipsanen, H. (2002). "Vacancy-type defects in GaAsN grown by metalorganic vapor phase epitaxy". Conference Proceedings. 14th Indium Phosphide and Related Materials Conference (Cat. No.02CH37307). Stockholm, Sweden: IEEE. pp. 245–248. doi:10.1109/ICIPRM.2002.1014345. ISBN 978-0-7803-7320-4. S2CID 122733148.
Stoiber, Dominik; Niewa, Rainer (2019-02-15). "Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba)". Zeitschrift für anorganische und allgemeine Chemie. 645 (3): 329–334. doi:10.1002/zaac.201800295. S2CID 219878132.
Chern, Ming Y.; Disalvo, F.J.; Parise, J.B.; Goldstone, Joyce A. (February 1992). "The structural distortion of the anti-perovskite nitride Ca3AsN". Journal of Solid State Chemistry. 96 (2): 426–435. Bibcode:1992JSSCh..96..426C. doi:10.1016/S0022-4596(05)80277-4.
Blankenship, Trevor V.; Wang, Xiaoping; Hoffmann, Christina; Latturner, Susan E. (2014-10-06). "LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux". Inorganic Chemistry. 53 (19): 10620–10626. doi:10.1021/ic501722d. ISSN 0020-1669. PMID 25222291.
Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu; Ohta, Hiroto; Yajima, Takeshi; Hiroi, Zenji; Nakamura, Hiroyuki (15 October 2017). "Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan. 86 (10): 104706. Bibcode:2017JPSJ...86j4706W. doi:10.7566/JPSJ.86.104706.
Boller, H. (1968). "Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ". Monatshefte für Chemie. 99 (6): 2444–2449. doi:10.1007/BF01154362. S2CID 97266394.
Jeong, Sehoon; Matsuishi, Satoru; Bang, Joonho; Hosono, Hideo (2015-04-01). "Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN ( TM = Fe, Co, and Ni)". APL Materials. 3 (4): 041509. Bibcode:2015APLM....3d1509J. doi:10.1063/1.4913395. ISSN 2166-532X.
Benz, R.; Zachariasen, W. H. (1969-02-15). "Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 25 (2): 294–296. doi:10.1107/S0567740869002135.
Wang, Zhi-Cheng; Shao, Ye-Ting; Lin, Yi-Qiang; Song, Shi-Jie; Li, Bai-Zhuo; Cheng, Er-Jian; Li, Shi-Yan; Zhu, Qin-Qing; Ren, Zhi; Cao, Guang-Han (2023-08-09). "Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x". Physical Review B. 108 (6): 064503. arXiv:2308.05267. Bibcode:2023PhRvB.108f4503W. doi:10.1103/PhysRevB.108.064503. ISSN 2469-9950. S2CID 260775924.
Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong; Mao, Huican; Xia, Yuanhua; Hu, Bingfeng; Liu, Zichen; Wang, Zhicheng; Shao, Yeting; Feng, Zhifa; Tan, Shugang; Sun, Yuping; Ren, Zhi; Jing, Qiang; Liu, Bo (2020-03-02). "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects". Inorganic Chemistry. 59 (5): 2937–2944. doi:10.1021/acs.inorgchem.9b03294. ISSN 0020-1669. PMID 32064866. S2CID 211133783.
Wang, Cao; Wang, Zhi-Cheng; Mei, Yu-Xue; Li, Yu-Ke; Li, Lin; Tang, Zhang-Tu; Liu, Yi; Zhang, Pan; Zhai, Hui-Fei; Xu, Zhu-An; Cao, Guang-Han (2016-02-24). "A New ZrCuSiAs-Type Superconductor: ThFeAsN". Journal of the American Chemical Society. 138 (7): 2170–2173. arXiv:1603.01501. doi:10.1021/jacs.6b00236. ISSN 0002-7863. PMID 26853632. S2CID 5393656.
Wang, Jingfeng; Jiao, Fei; Wang, Xianyu; Zhu, Shu; Cai, Lingbo; Yang, Chunhui; Song, Pengwei; Zhang, Fuxiang; Li, Baizhuo; Li, Yunlong; Hu, Jiayuan; Li, Shubin; Li, Yuqiang; Tan, Shugang; Mei, Yuxue (2020-07-21). "The phase transition of ThFe 1-x Co x AsN from superconductor to metallic paramagnet". EPL (Europhysics Letters). 130 (6): 67003. Bibcode:2020EL....13067003W. doi:10.1209/0295-5075/130/67003. ISSN 1286-4854. S2CID 225558397.
Wang, Zhi-Cheng; Shao, Ye-Ting; Wang, Cao; Wang, Zhen; Xu, Zhu-An; Cao, Guang-Han (2017-06-01). "Enhanced superconductivity in ThNiAsN". EPL (Europhysics Letters). 118 (5): 57004. Bibcode:2017EL....11857004W. doi:10.1209/0295-5075/118/57004. ISSN 0295-5075. S2CID 125752599.
Shao, Ye-Ting; Wang, Zhi-Cheng; Li, Bai-Zhuo; Wu, Si-Qi; Wu, Ji-Feng; Ren, Zhi; Qiu, Su-Wen; Rao, Can; Wang, Cao; Cao, Guang-Han (September 2019). "BaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer". Science China Materials. 62 (9): 1357–1362. arXiv:1908.03992. doi:10.1007/s40843-019-9438-7. ISSN 2095-8226. S2CID 164224680.

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[1] Toivonen, J.; Oila, J.; Saarinen, K.; Hakkarainen, T.; Sopanen, M.; Lipsanen, H. (2002). "Vacancy-type defects in GaAsN grown by metalorganic vapor phase epitaxy". Conference Proceedings. 14th Indium Phosphide and Related Materials Conference (Cat. No.02CH37307). Stockholm, Sweden: IEEE. pp. 245–248. doi:10.1109/ICIPRM.2002.1014345. ISBN 978-0-7803-7320-4. S2CID 122733148.

[:2-2] Stoiber, Dominik; Niewa, Rainer (2019-02-15). "Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of ( A 3 N)As ( A = Mg, Ca, Sr, Ba)". Zeitschrift für anorganische und allgemeine Chemie. 645 (3): 329–334. doi:10.1002/zaac.201800295. S2CID 219878132.

[3] Chern, Ming Y.; Disalvo, F.J.; Parise, J.B.; Goldstone, Joyce A. (February 1992). "The structural distortion of the anti-perovskite nitride Ca3AsN". Journal of Solid State Chemistry. 96 (2): 426–435. Bibcode:1992JSSCh..96..426C. doi:10.1016/S0022-4596(05)80277-4.

[4] Blankenship, Trevor V.; Wang, Xiaoping; Hoffmann, Christina; Latturner, Susan E. (2014-10-06). "LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux". Inorganic Chemistry. 53 (19): 10620–10626. doi:10.1021/ic501722d. ISSN 0020-1669. PMID 25222291.

[5] Waki, Takeshi; Takao, Kenta; Tabata, Yoshikazu; Ohta, Hiroto; Yajima, Takeshi; Hiroi, Zenji; Nakamura, Hiroyuki (15 October 2017). "Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN". Journal of the Physical Society of Japan. 86 (10): 104706. Bibcode:2017JPSJ...86j4706W. doi:10.7566/JPSJ.86.104706.

[6] Boller, H. (1968). "Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ". Monatshefte für Chemie. 99 (6): 2444–2449. doi:10.1007/BF01154362. S2CID 97266394.

[:1-7] Jeong, Sehoon; Matsuishi, Satoru; Bang, Joonho; Hosono, Hideo (2015-04-01). "Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN ( TM = Fe, Co, and Ni)". APL Materials. 3 (4): 041509. Bibcode:2015APLM....3d1509J. doi:10.1063/1.4913395. ISSN 2166-532X.

[:0-8] Benz, R.; Zachariasen, W. H. (1969-02-15). "Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se". Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 25 (2): 294–296. doi:10.1107/S0567740869002135.

[9] Wang, Zhi-Cheng; Shao, Ye-Ting; Lin, Yi-Qiang; Song, Shi-Jie; Li, Bai-Zhuo; Cheng, Er-Jian; Li, Shi-Yan; Zhu, Qin-Qing; Ren, Zhi; Cao, Guang-Han (2023-08-09). "Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x". Physical Review B. 108 (6): 064503. arXiv:2308.05267. Bibcode:2023PhRvB.108f4503W. doi:10.1103/PhysRevB.108.064503. ISSN 2469-9950. S2CID 260775924.

[10] Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong; Mao, Huican; Xia, Yuanhua; Hu, Bingfeng; Liu, Zichen; Wang, Zhicheng; Shao, Yeting; Feng, Zhifa; Tan, Shugang; Sun, Yuping; Ren, Zhi; Jing, Qiang; Liu, Bo (2020-03-02). "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects". Inorganic Chemistry. 59 (5): 2937–2944. doi:10.1021/acs.inorgchem.9b03294. ISSN 0020-1669. PMID 32064866. S2CID 211133783.

[11] Wang, Cao; Wang, Zhi-Cheng; Mei, Yu-Xue; Li, Yu-Ke; Li, Lin; Tang, Zhang-Tu; Liu, Yi; Zhang, Pan; Zhai, Hui-Fei; Xu, Zhu-An; Cao, Guang-Han (2016-02-24). "A New ZrCuSiAs-Type Superconductor: ThFeAsN". Journal of the American Chemical Society. 138 (7): 2170–2173. arXiv:1603.01501. doi:10.1021/jacs.6b00236. ISSN 0002-7863. PMID 26853632. S2CID 5393656.

[12] Wang, Jingfeng; Jiao, Fei; Wang, Xianyu; Zhu, Shu; Cai, Lingbo; Yang, Chunhui; Song, Pengwei; Zhang, Fuxiang; Li, Baizhuo; Li, Yunlong; Hu, Jiayuan; Li, Shubin; Li, Yuqiang; Tan, Shugang; Mei, Yuxue (2020-07-21). "The phase transition of ThFe 1-x Co x AsN from superconductor to metallic paramagnet". EPL (Europhysics Letters). 130 (6): 67003. Bibcode:2020EL....13067003W. doi:10.1209/0295-5075/130/67003. ISSN 1286-4854. S2CID 225558397.

[13] Wang, Zhi-Cheng; Shao, Ye-Ting; Wang, Cao; Wang, Zhen; Xu, Zhu-An; Cao, Guang-Han (2017-06-01). "Enhanced superconductivity in ThNiAsN". EPL (Europhysics Letters). 118 (5): 57004. Bibcode:2017EL....11857004W. doi:10.1209/0295-5075/118/57004. ISSN 0295-5075. S2CID 125752599.

[14] Shao, Ye-Ting; Wang, Zhi-Cheng; Li, Bai-Zhuo; Wu, Si-Qi; Wu, Ji-Feng; Ren, Zhi; Qiu, Su-Wen; Rao, Can; Wang, Cao; Cao, Guang-Han (September 2019). "BaTh$_2$Fe$_4$As$_4$(N$_{0.7}$O$_{0.3}$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer". Science China Materials. 62 (9): 1357–1362. arXiv:1908.03992. doi:10.1007/s40843-019-9438-7. ISSN 2095-8226. S2CID 164224680.