Arsenide bromide

Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

List
formula system space group unit cell Å volume density comment ref
(Ca2−x□x)(As1−xBr1+x) Ca2AsBr cubic a=6.05 3.47 yellow, or dark brown [1][2]
Ca3AsBr3 cubic Pm3 a=5.91 3.48 colourless or yellow [1][2]
Cu6AsS5Br cubic F43m a=9.8763 4.80 [3][4]
(Ge38As8)+8⋅8 I− cubic Pm3n a=10.625 5.71 semiconductor resistivity 1 Ω cm; band gap 0.9 eV; silvery grey [5]
I8As21Ge25 cubic Pm3n a=10.5963 Z=1 1189.77 6.143 colourless [6]
Cd2As3Br monoclinic C2/c a = 8.281, b = 9.411, c = 7.993, β = 101.49°, z = 4 5.76 black [7][8]
Cd4As2Br3 cubic Pa3 a=12.61 5.51 semiconductor band gap 1.8 eV [9]
Cd4PAsBr3 cubic Pa3 a=12.521 5.38 [10][4]
Cd4As2I1.5Br1.5 cubic Pa3 a=12.83 [11][4]
La3AsBr3 cubic I4132 a=12.09 5.50 [12]
Pr3AsBr3 cubic I4132 a=12.02 5.64 [12]
Hg2As3Br monoclinic C2/c a = 8.0914, b = 9.300, c = 8.1084, β = 99.323°, z = 4 7.79 black [7]
Hg4As2Br3 cubic Pa3 a=12.610 Z=8 2012.4 5.54 7.90 red; dark grey [13][14]
Hg19As10Br18 triclinic P1 a = 11.262, b = 11.352, c = 12.309, α = 105.724, β = 105.788, γ = 109.078° 1314.3 dark brown [15]
(HgBr2)3(As4S4)2 monoclinic P21/c a = 9.593, b = 11.395, c = 13.402, β = 107.27, Z = 2 1399 [16]
Hg3AsS4Br hexagonal P63mc a = 7.430, c = 9.364 Z=2 [17]
(Hg6As4)[TiBr6]Br cubic Pa3 a= 1230.9 [18]
[Hg6As4](CrBr6)Br cubic Pa a=12.275 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](FeBr6)Hg0.6 cubic Pa a=12.332 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](CuBr3)2 monoclinic I2/a a = 14.884, b = 9.358, c = 20.413, β=92.88°, Z = 6 dark red [20]
[Hg11As4](GaBr4)4 monoclinic C2/m [21]
Hg3AsSe4Br hexagonal P63mc a = 7.707, c = 9.47 Z=2 [17]
(Hg2Cd2As2Br)Br orthorhombic Pmma a = 8.791, b = 4.701, c = 9.779, Z=2 404.2 7.688 dark red [22]
(Hg6As4)(CdBr6) cubic Pa3 a=12.3738 Z=4 1894.6 7.345 red; air stable; band gap 1.94 [23]
[Hg6As4][InBr6]Br cubic Pa3 a=12.3511 Z=4 1884.2 dark red [24]
[Hg4As2](InBr3.5As0.5) Hexagonal P63/mmc a = 7.7408, c = 12.535, Z=2 650.47 [25]
[Hg6As4Br3](SnBr3) cubic P213 a=12.383 Z=4 [26]
[Hg6As4][YbBr6]Br cubic Pa3 a=12.362 Z=4 1889.1 7.860 dark red [27]
Hg9As4Bi2Br12 tetragonal P43 a=10.865 b=10.865 c=28.357 Z=4 3347.5 6.91 orange [28]

References
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