Delphinidin 3',5'-O-glucosyltransferase

Delphinidin 3',5'-O-glucosyltransferase (EC 2.4.1.249, UDP-glucose:anthocyanin 3',5'-O-glucosyltransferase, UA3'5'GZ) is an enzyme with systematic name UDP-glucose:delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside 3'-O-glucosyltransferase.[1] This enzyme catalyses the following chemical reaction

2 UDP-glucose + delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside 2 UDP + delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside-3',5'-di-O-beta-D-glucoside (overall reaction)
(1a) UDP-glucose + delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside UDP + delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside-3'-O-beta-D-glucoside
(1b) UDP-glucose + delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside-3'-O-beta-D-glucoside UDP + delphinidin 3-O-(6-O-malonyl)-beta-D-glucoside-3',5'-di-O-beta-D-glucoside
Delphinidin 3',5'-O-glucosyltransferase
Identifiers
EC no.2.4.1.249
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
Search
PMCarticles
PubMedarticles
NCBIproteins

This enzyme catalyses two reactions in the biosynthesis of ternatin C5.

References

  1. Kogawa K, Kato N, Kazuma K, Noda N, Suzuki M (November 2007). "Purification and characterization of UDP-glucose: anthocyanin 3',5'-O-glucosyltransferase from Clitoria ternatea". Planta. 226 (6): 1501–9. doi:10.1007/s00425-007-0584-1. PMID 17668234.
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