Oxalate phosphite

The oxalate phosphites are chemical compounds containing oxalate and phosphite anions. They are also called oxalatophosphites or phosphite oxalates. Oxalate phosphates can form metal organic framework compounds.

Related compounds include the nitrite oxalates, arsenite oxalates,[1][2] phosphate oxalates and oxalatophosphonates.

The oxalate ion is rectangular and planar. The phosphite ion is shaped as a triangular pyramid. Because of high charge and stiff shape they will bridge across more than one cation, in particular those hard cations with a higher charge such as +3. Hydrogen can convert some of the oxygen on the anions to OH and reduce the charge. Many oxalate phosphite compounds have microporous structures where amines direct the structure formation.[3]

List
name chem mw crystal system space group unit cell Å volume density comment references
peha = pentaethylenehexamine [(H6peha)0.17(H2O)1.5][Al2(HPO3)2(C2O4)(HCOO)] +formate [4]
(H13C5NOH)0.5(H2C13H14N2)0.25[Al2(HPO3)2(C2O4)(OH)(H2O)]0.5H2O [4]
Li2(VOHPO3)2C2O4•6H2O triclinic P1 a=6.3592, b=8.0789, c=9.1692, α=64.390°, β=87.277°, γ=67.624° [5]
Li2(VOHPO3)2C2O4•4H2O monoclinic P21/a a=6.3555 b=12.6368 c=9.0242 β=105.167° [5]
Li2(VO)2(HPO3)2C2O4 [6]
diammonium (μ-oxalato)-bis(μ-phosphonato)-dioxo-di-vanadium hydrate (NH4)2(VOHPO3)2C2O4 2·9H2O triclinic P1 a = 6.3844, b = 7.2278, c = 9.2965, α = 67.260°, β = 72.927°, γ = 85.848° [7]
(μ6-Oxalato)-bis(μ4-hydrogen phosphonato)-bis(μ2-aqua)-bis(μ2-oxo)-di-sodium-di-vanadium Na2(VO)2(HPO3)2C2O4 463.87 triclinic P1 a 6.3255 b 6.7760 c 8.0759, α 104.992° β 101.679° γ 99.120° Z=1 319.20 2.413 blue [6]
K2(VO)2(HPO3)2C2O4 514.10 monoclinic C2/c a 17.75 b 6.370 c 13.977, β 115.42° Z=4 1427 2.393 blue [6]
K2MnII2(H2O)2C2O4(HPO3)2 472.09 hexagonal P63/m a=9.7371 c=22.4924 1846.8 2.547 pink [8]
(CN3H6)2·Mn2.5(HPO3)(C2O4)2.5(H2O)·H2O [9]
piperazine [C4N2H12][MnII2(HPO3)2(C2O4)] monoclinic P21/c a=6.0627 b=10.7122 c=10.387 β=97.956 Z=2 668.1 2.217 pale pink [10]
dab = 1,4-diaminobutane H2dab·Mn2(HPO3)2(C2O4)(H2O)2 monoclinic P21/n a = 5.616, b = 15.431, c = 9.445, β = 91.72(2)°, Z = 2 818.2 [11]
ethylenediammonium manganese phosphite-oxalate [C2N2H10][Mn2II(OH2)2(HPO3)2(C2O4)] monoclinic P21/c a 7.837 b 8.755 c 10.100, β 100.605° [12]
bis(1-(3-ammoniopropyl)imidazolium) tetrakis(μ-dihydrogen phosphato)-tetrakis(μ-oxalato)-tetra-manganes H2api·Mn2(H2PO4)2(C2O4)2 triclinic P1 a=7.6108 b=9.8476 c=15.2437, α=100.023° β=102.032° γ=110.612° [13]
(C6H14N2)0.5Mn(H2PO3)(C2O4) [14]
1,4-diazabicyclo[2.2.2]octane (DABCO) [C6N2H14]2[FeIII2F2(HPO3)2(C2O4)2]·2H2O monoclinic P21/n a=12.51 b=6.372 c=33.153 β=90.532 Z=4 2643.0 1.875 colourless; chains [15]
TREN [C6N4H21]2[FeII4(HPO3)2(C2O4)5]·5H2O triclinic P1 a=8.719 b=8.827 c=15.908 α=78.617 β=84.047 γ=68.241 Z=2 1114.1 1.770 brown; network [15]
[FeIII2(OH2)2(HPO3)2(C2O4)]·H2O monoclinic P21/c a=4.875 b=17.707 c=6.984 β=106.728 Z=4 577.46 2.368 colourless [15]
ethylenediammonium [C2N2H10][FeII2(OH2)2(HPO3)2(C2O4)] monoclinic P21/c a=7.684 b=8.651 c=10.053 β=100.821 Z=4 653.6 2.317 brown [15]
BAPEN [C8N4H26][FeIII6(HPO3)8(C2O4)3]·4H2O monoclinic P21/n a=8.493 b=16.685 c=16.215 β=95.919 Z=4 2280.35 2.157 colourless [15]
homopip [C5N2H14][FeII4(HPO3)2(C2O4)3] monoclinic P21/c a=7.682 b=7.726 c=18.092 β=94.443 Z=4 1070.8 2.004 brown [15]
Piperazinediium bis(μ4-phosphito)-(μ4-oxalato)-bis(μ3-oxalato)-tetra-iron(ii) [C4N2H12][FeII4(HPO3)2(C2O4)3] monoclinic P21/c a 7.7286 b 7.587 c 17.9816 β 98.214° [16]
dab = 1,4-diaminobutane (H2dab)0.5·Co(H2PO3)(C2O4) [17]
[C4N2H12][Co4(HPO3)2(C2O4)3] monoclinic P21/c a=7.614 b=7.51 c=17.750 β=97.351 Z=2 1007.3 2.466 [18]
CN3H6·Co(H2PO3)(C2O4) [8]
Co(H2PO3)(C2O4)·(C2H8N) triclinic P1 [19]
Co(H2PO3)(C2O4)·(C2H8N) monoclinic P21/n [19]
Co2(H2PO3)2(C2O4)3(C6N2H16)2 monoclinic P21/c a=5.8605 b=13.6144 c=19.361

β=105.582

 1487.9 1.733 pink [20]
Co2(H2PO3)2(C2O4)2(C6N2H16) monoclinic P21/c a=15.3007 b=8.2832 c=16.2601 β=113.487 Z=2 1890 2.010 pink; proton conductor [20]
(C4H14N2)0.5Co(HPO3)(C2O4) [14]
bis(1,4-Diazoniabicyclo[2.2.2]octane) bis(μ3-hydrogen phosphito)-dihydroxy-bis(oxalato)-di-gallium(iii) dihydrate (C6N2H14)2[Ga2(OH)2(C2O4)2(HPO3)2]·2H2O monoclinic P21/n a 12.401 b 6.283 c 33.306 β 91.197° [21]
N,N,N',N'-Tetramethylethylenediammonium bis(μ3-hydrogen phosphito)-(μ2-oxalato)-dihydroxy-di-gallium(iii) (C6N2H18)0.5[Ga(OH)(C2O4)0.5(HPO3)] triclinic P1 a 6.257 b 8.558 c 9.253, α 93.219° β 108.265° γ 106.956° [21]
bis(μ3-Hydrogen phosphito)-(μ2-oxalato)-bis(1H-imidazole)-di-gallium(iii) Ga(C2O4)0.5(C3N2H4)(HPO3) monoclinic P21/c a 8.038 b 8.709 c 11.487, β 91.85° [21]
Ga(HPO3)(C2O4)(C3N2H4)·(C3N2H5) orthorhombic Pnma a=13.288, b=6.361, c=1.5364, Z=4 [22]
[bis(1,4-dimethylpiperazinediium) tetrakis(μ2-phosphito)-tetrakis(μ2-hydrogen phosphito)-bis(μ2-oxalato)-tetra-gallium] [Ga2(HPO3)2(H2PO3)2(C2O4)](C6N2H16) monoclinic P21/c a =10.183 b=12.525 c=16.295 β=98.218° [23]
[hemikis(1,4-dimethylpiperazinediium) bis(μ3-phosphito)-(μ2-hydrogen phosphito)-(μ2-oxalato)-di-gallium] [Ga2(HPO3)2(H2PO3)(C2O4)](C6N2H16)0.5 monoclinic C 2/c a =23.462 b= 8.1170 c =16.898, β 112.873° [23]
phen = 1,10-phenanthroline Cd2(phen)2(H2PO4)(H2PO3)(C2O4) chains [17]
Cd(C10H8N2)(HPO3)(C2O4)0.5 [14]
catena-(Piperazinedi-ium bis(μ3-hydrogen phosphito)-(μ2-oxalato)-(μ2-hydrogen phosphito)-di-indium) [C4H12N2][In2(HPO3)3(C2O4)] orthorhombic Cmcm a=6.555 b=15.384 c=18.135 [24]
[C4N2H12]3[In2(HPO3)2(C2O4)4].4H2O [25]
1,4-diazabicyclo[2.2.2]octane (dabco) C6H14N2[In2(HPO3)3(C2O4)] 671.79 orthorhombic Pna21 a = 12.414, b = 7.7166, c = 18.327, Z = 4 1755.6 2.542 [26]
[C4N2H12]2[In2(HPO3)3(C2O4)2].3H2O [25]
[C4N2H12]3[In4(HPO3)6(C2O4)3] [25]
[C4N2H14][In4(H2O)(HPO3)5(C2O4)2].2H2O [25]
H[In5(HPO3)6(H2PO3)2(C2O4)2]·(C4N2H11)2·H2O triclinic P1 a =7.822 b =10.626 c =13.156, α =94.720° β =92.336° γ =110.181° [27]
1-methylpiperazine In5(HPO3)6(H1.5PO3)2(C2O4)2·(H2C5N2H12)2 triclinic P1 a 10.1574 b 10.4440 c 10.6857, α 70.006° β 76.100° γ 79.337° [28]
1-ethylpiperazine In5(HPO3)6(H1.5PO3)2(C2O4)2·(H2C6N2H14)2 triclinic P1 a 10.1904 b 10.4327 c 10.7158, α 69.373° β 77.185° γ 79.268° [28]
dbu = 1,8-diazabicyclo[5.4.0]undec-7-ene Hdbu·In2(HPO3)2(C2O4)1.5 [17]
Ba2(C2O4)(H2PO3)2 531.38 monoclinic C2/c a = 12.3829, b = 7.9124, c = 11.0858, β=114.788 (2)°, Z = 4 986.10 3.534 colourless [29]
[Pr(H2O)(C2O4)0.5(HPO3)]·H2O 300.93 triclinic P1 a=6.6764 b=7.0684 c=7.8103 α=111.141° β=95.415° γ=90.457° Z=2 2.923 [30]
[Nd(H2O)(C2O4)0.5(HPO3)]·H2O 304.26 triclinic P1 a=6.6544 b=7.0684 c=7.8103 α=111.160° β=95.307° γ=90.590° Z=2 2.985 [30]
[Sm(H2O)(C2O4)0.5(HPO3)]·H2O [30]
[Eu(H2O)(C2O4)0.5(HPO3)]·H2O 311.98 triclinic P1 a=6.5619 b=6.9442 c=7.7412 α=111.369° β=95.495° γ=90.824° Z=2 3.173 [30]
[Gd(H2O)(C2O4)0.5(HPO3)]·H2O 317.27 triclinic P1 a=6.5434 b=6.9311 c=7.7465 α=111.487° β=95.645° γ=90.833° Z=2 3.244 [30]
[Ho(H2O)(C2O4)0.5(HPO3)]·H2O 324.95 triclinic P1 a=6.4628 b=6.8519 c=7.6936 α=111.646° β=95.779° γ=91.028° Z=2 3.421 [30]
[Er(H2O)(C2O4)0.5(HPO3)]·H2O 327.28 triclinic P1 a=6.4400 b=6.8326 c=7.6747 α=111.654° β=95.757° γ=91.096° Z=2 3.487 [30]
[Tm(H2O)(C2O4)0.5(HPO3)]·H2O triclinic P1 [30]
[Yb(H2O)(C2O4)0.5(HPO3)]·H2O 333.06 triclinic P1 a=6.4075 b=6.8050 c=7.6647 α=111.753° β=95.858° γ=91.204° Z=2 3.589 [30]
[Lu(H2O)(C2O4)0.5(HPO3)]·H2O triclinic P1 [30]

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