Silver bromate

Silver bromate (AgBrO3), is a toxic, light and heat-sensitive, white powder.[2]

Silver bromate
Names
Systematic IUPAC name
Silver(I) bromate
Other names
Argentous bromate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.120
  • InChI=1S/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 checkY
    Key: XQLMNMQWVCXIKR-UHFFFAOYSA-M checkY
  • InChI=1/Ag.BrHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: XQLMNMQWVCXIKR-REWHXWOFAZ
  • [Ag+].[O-]Br(=O)=O
Properties
AgBrO3
Molar mass 235.770 g/mol
Appearance white powder
photosensitive
Density 5.206 g/cm3
Melting point 309 °C (588 °F; 582 K)
0.167 g/100 mL
5.38×10−5[1]
Solubility in ammonium hydroxide soluble
Hazards
GHS labelling:
GHS03: Oxidizing GHS07: Exclamation mark
Danger
H272, H315, H319, H335
P210, P220, P261, P264, P271, P280, P302+P352, P304+P340+P312, P305+P351+P338, P332+P313, P337+P313, P362+P364, P370+P378, P403+P233, P405, P501
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Silver bromide GIF

Uses

Silver bromate can be used as an oxidant for the transformation of tetrahydropyranyl ethers to carbonyl compounds.[3]

References
  1. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN 978-1138561632.
  2. Perry, Dale L. (2011). Handbook of inorganic compounds (2nd ed.). Boca Raton: Taylor & Francis. p. 365. ISBN 978-1-4398-1461-1. OCLC 587104373.
  3. Mohammadpoor-Baltork, Iraj; Nourozi, Ali Reza (1999). "Efficient and Selective Oxidative Deprotection of Tetrahydropyranyl Ethers, Ethylene Acetals and Ketals with Silver and Sodium Bromates in the Presence of Aluminum Chloride". Synthesis. 1999 (3): 487–490. doi:10.1055/s-1999-3410. S2CID 196725503.


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