Silver perrhenate

Silver perrhenate is a chemical compound with the formula AgReO4. This compound is isostructural with the mineral scheelite (CaWO4).[1] Silver perrhenate reacts with trimethylsilyl chloride to give the silyl "ester" (CH3)3SiOReO3.[2]

Silver perrhenate
Names
IUPAC name
Silver(1+) perrhenate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.153.139
EC Number
  • 232-042-2
  • InChI=1S/Ag.4O.Re/q+1;;;;-1;
    Key: JRISYOCHUNKJAV-UHFFFAOYSA-N
  • InChI=1/Ag.4O.Re/q+1;;;;-1;/rAg.O4Re/c;1-5(2,3)4/q+1;-1
    Key: JRISYOCHUNKJAV-HGQFXYHCAN
  • [Ag+].[O-][Re](=O)(=O)=O
Properties
AgReO4
Molar mass 358.073 g/mol
Density 7.05 g/cm3
Melting point 430 °C (806 °F; 703 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References

  1. Naumov, D. Yu.; Virovets, A. V.; Korenev, S. V.; Gubanov, A. I. (1999). "Silver perrhenate, AgReO4". Acta Crystallographica Section C. 55 (8): IUC9900097. doi:10.1107/S0108270199099138.
  2. US patent 2008262256, Wolfgang A. Herrmann, Fritz E. Kuhn, Richard Fischer, "Method for efficiently producing methyltrioxorhenium(vii) (mto) and organorhenium(vii) oxides", issued 2005-08-30


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