Titanium(IV) acetate

Titanium(IV) acetate or titanium tetraacetate is a hypothetical coordination complex with the formula Ti(C2H3O2)4. It is discussed in archaic literature,[1] well before the advent of X-ray crystallography and an appreciation of the structural trends in metal carboxylate complexes.

Titanium(IV) acetate
Names
Other names
  • Titanium tetraacetate
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 235-944-4
  • InChI=1S/4C2H4O2.Ti/c4*1-2(3)4;/h4*1H3,(H,3,4);
    Key: INNSZZHSFSFSGS-UHFFFAOYSA-N
  • CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Ti]
Properties
Ti(C2H3O2)4
Molar mass 288.07 g/mol
Melting point 117 °C (243 °F; 390 K)
Related compounds
Other cations
 Zirconium(IV) acetate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Evidence for the composition much less the structure as a tetraacetate has not been presented.[2] Instead a variety of titanium oxo acetates have been prepared by reactions of titanium alkoxides and acetic acid.[3]

Uses

Species claimed to be titanium(IV) acetate have been used in the production of bismuth titanate ferroelectric thin films. Titanium(IV) acetate is used in the step of making the acetate-derived solutions. The acetate derived solutions were created by blending acetic acid and bismuth acetate together and adding titanium(IV) acetate.[4] "Titanium(IV) acetate" is a substitute for antimony potassium tartrate(emetic tartar) when making red and brown dyes.[5]

References
  1. Frederick Pearson Treadwell (1916). Qualitative analysis. J.Wiley & sons, Incorporated. p. 538. Retrieved 26 March 2021.
  2. Pande, K. C.; Mehrotra, R. C. (1957). "Attempted Preparation of Titanium Tetra-Acetate". Journal für praktische Chemie. 5 (1–2): 101–104. doi:10.1002/prac.19570050112.
  3. Gautier-Luneau, I.; Mosset, A.; Galy, J. (1987). "Structural Characterization of a Hexanuclear Titanium Acetate Complex, Ti6(μ3–O)2(μ2–O)2(μ2–OC2H5)2-μ-CH3COO)8(OC2H5)6, Built Up of Two Trinuclear, oxo-Centered, Units". Zeitschrift für Kristallographie. 180 (1–4): 83–95. Bibcode:1987ZK....180...83G. doi:10.1524/zkri.1987.180.1-4.83.
  4. Scientific and Technical Aerospace Reports. NASA, Office of Scientific and Technical Information. 1995. p. 1198. Retrieved 26 March 2021.
  5. The Year-book for Colorists and Dyers. the New York Public Library. 1905. p. 413. Retrieved 26 March 2021.
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